PCB/Toxaphene group separation on silica prior to congener specific determination of toxaphene residues in fish and other samples by GC/ECD

Chemosphere

Volumn 35, Issue 7, 1997, Pages 1519-1530

  Krock, Bernd ^a   Vetter, Walter ^a   Luckas, Bernd ^a  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CAMPHECLOR; HEXANE; POLYCHLORINATED BIPHENYL; SILICON DIOXIDE;

ANALYTICAL TECHNIQUES; GROUP SEPARATION; ORGANIC POLLUTANTS; PESTICIDES; TOXAPHENE;

ANIMAL TISSUE; ARTICLE; BIOLOGICAL MONITORING; ELECTRON CAPTURE DETECTION; FEMALE; FISH; GAS CHROMATOGRAPHY; LIVER; MALE; NONHUMAN; SEAL; WATER POLLUTION; WHALE;

ANIMALS; ENVIRONMENTAL POLLUTANTS; FEMALE; FISHES; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; INSECTICIDES; LIVER; MALE; POLYCHLORINATED BIPHENYLS; REPRODUCIBILITY OF RESULTS; SILICON DIOXIDE; TOXAPHENE;

ANIMALIA; CETACEA; GADUS MORHUA; PHOCIDAE;

EID: 0030773445     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0045-6535(97)00222-1     Document Type: Article

References (32)

1. M. A. Saleh, Toxaphene: chemistry, biochemistry, toxicity and environmental fate, Rev. Environ. Cont. Toxicol. 118, 1-85 (1991).
2. E. C. Voldner, Y.-F. Li, Global usage of selected persistent organochlorines, Sci. Total Environ. 160/161, 201-210 (1995).
3. T. F. Bidleman, M. T. Zaranski, M. D. Walla, Toxaphene: usage, aerial transport and deposition. In: Toxic Contamination in Large Lakes, Vol.I (Edited by N. W. Schmidtke). Lewis Publishers, Chelsea, pp. 257-284 (1988).
4. B. Jansson, U. Wideqvist, Analysis of toxaphene (PCC) and chlordane in biological samples by NCI mass spectrometry, Intern. J. Environ. Anal. Chem. 13, 309-321 (1983).
5. M. A. Saleh, Capillary gas chromatography-electron impact and chemical ionization mass spectrometry of toxaphene, J. Agric. Food Chem. 31, 748-751 (1983).
6. J. E. Casida, R. L. Holmstead, S. Khalifa, J. R. Knox, T. Ohsawa, K. J. Palmer, R. Y. Wong, Toxaphene insecticide: a complex biodegradable mixture, Science 183, 520-521 (1974).
7. B. Luckas, W. Vetter, P. Fischer, G. Heidemann, J. Plötz, Characteristic chlorinated hydrocarbon patterns in the blubber of seals from different marine regions, Chemosphere 21, 13-19 (1990).
8. G. A. Stern, D. C. G. Muir, C. A. Ford, N. P. Grift, E. Dewailly, T. F. Bidleman, M. D. Walla, Isolation and identification of two major recalcitrant toxaphene congeners in aquatic biota, Environ. Sci. Technol. 26, 1838-1840 (1992).
9. W. Vetter, B. Krock, B. Luckas, Congener specific determination of compounds of technical toxaphene (CTTs) in different Antarctic seal species, Chromatographia 44, 65-73 (1997).
10. C. J. Musial, H. F. Uthe, Widespread occurrence of the pesticide toxaphene in Canadian east coast marine fish, Intern. J. Environ. Anal. Chem. 14, 117-124 (1983).
11. H. Parlar, Chlorierte Bornan-Derivate - eine neue Klasse umweltrelevanter Chemikalien. Nachr. Chem. Tech. Lab. 39, 26-37 (1991).
12. J. Burhenne, D. Hainzl, L. Xu, B. Vieth, L. Alder, H. Parlar, Preparation and structure of high-chlorinated bornane derivatives for the quantification of toxaphene residues in environmental samples, Fresenius J. Anal. Chem. 346, 779-785 (1993).
13. P. Andrews, W. Vetter, A systematic nomenclature system for toxaphene congeners. Part 1: chlorinated bornanes, Chemosphere 31, 3879-3886 (1995).
14. H. Parlar, D. Angerhöfer, M. Coelhan, L. Kimmel, HRGC and HRGC-ECNI determination of toxaphene residues in fish with a new 22 components standard. Organohal. Compounds 26, 357-362 (1995).
15. L. Alder, B. Vieth, A congener-specific method for the quantification of camphechlor (toxaphene) residues in fish and other foodstuffs, Fresenius J. Anal. Chem. 354, 81-92 (1996).
16. W. Specht, M. Tillkes, Gaschromatographische Bestimmung von Rückständen an Pflanzenbehandlungsmitteln nach Clean-up über Gel-Chromatographie und Mini-Kieselgel-Säulen-Chromatographie. Fresenius Z. Anal. Chem. 322, 443-455 (1985).
17. B. Krock, W. Vetter, B. Luckas, G. Scherer, Structure elucidation of a main heptachloro congener of toxaphene in marine organisms after isolation from Melipax®. Chemosphere 33, 1005-1019 (1996).
18. W. Vetter, C. Natzeck, B. Luckas, G. Heidemann, B. Kiabi, M. Karami, Chlorinated hydrocarbons in the blubber of a seal (Phoca caspica) from the Caspian Sea. Chemosphere 30, 1685-1696 (1995).
19. W. Vetter, B. Luckas, Synthesis, isolation, and chromatography of perdeuterated α-1,2,3,4,5,6-hexachlorocyclohexane. J. High Resol. Chromatogr. 18, 643-646 (1995).
20. 1H NMR structural assignment of TOX8 and TOX9, the two most abundant toxaphene congeners in marine mammals. Fresenius J. Anal. Chem. 349, 552-558 (1993).
21. W. V. Turner, S. Khalifa, J. E. Casida, Toxaphene Toxicant A. Mixture of 2,2,5-endo,6-exo,8,8,9,10-octachlorobornane and 2,2,5-endo,6-exo,8,9,9,10-octachlorobornane. J. Agric. Food Chem. 23, 991-995 (1975).
22. F. Matsumura, R. W. Howard, J. O. Nelson, Structure of the toxic fraction A of toxaphene. Chemosphere 5, 271-276 (1975).
23. W. Vetter, U. Klobes, B. Krock, B. Luckas, Congener specific separation of compounds of technical toxaphene on a non-polar CP-Sil 2 phase. J. Microcol. Sep., in press (1997).
24. C. Natzeck, W. Vetter, B. Luckas, G. Moskopp, J. Buijten, Quantitative determination of toxic mono- and non-ortho polychlorinated biphenyls in cod liver oil after selective liquid chromatographic separation. Chromatographia 41, 585-593 (1995).
25. B. Jansson, U. Wideqvist, Analysis of toxaphene (PCC) and chlordane in biological samples by NCI mass spectrometry. Intern. J. Environ. Anal. Chem. 13, 309-321 (1983).
26. E. Schulte, R. Malisch, Berechnung der wahren PCB-Gehalte in Umweltproben. 1. Ermittlung der Zusammensetzung zweier technischer PCB-Gemische. Fresenius Z. Anal. Chem. 314, 545-551 (1983).
27. W. Zoller, W. Schäfer, T. Class, K. Ballschmiter, Quantitation of polychlorodibenzodioxin and polychlorobiphenyl standards by gas-chromatography - flame ionisation detector. Fresenius Z. Anal Chem. 321, 247-251 (1985).
28. W. Vetter, B. Luckas, M. Oehme, Isolation and purification of the two main toxaphene congeners in marine organisms. Chemosphere 25, 1643-1652 (1992).
29. J. de Boer, H.-J. de Geus, U. A. Th. Brinkman, Multidimensional gas chromatographic analysis of toxaphene - test of different column combinations. Organohal. Compounds 28, 363-368 (1996).
30. H. Karlsson, M. Oehme, Comparison of retention time overlaps of toxaphene congeners on three different stationary phases in cod liver samples and consequences for quantification, Organohal. Compounds 28, 369-374 (1996).
31. W. Vetter, B. Luckas, G. Heidemann, K. Skírnisson, Organochlorine residues in marine mammals from the northern hemisphere - a consideration of the composition of organochlorine residues in the blubber of marine mammals, Sci. Total Environ. 186, 29-39 (1996).
32. W. Vetter, B. Luckas, Ratios of PCB 138, PCB 163, and PCB 164 in Aroclor mixtures. Fresenius J. Anal. Chem. 352, 512-513 (1995).