Structure elucidation of a main heptachloro congener of toxaphene in marine organisms after isolation from Melipax®

Chemosphere

Volumn 33, Issue 6, 1996, Pages 1005-1019

  Krock, Bernd ^a   Vetter, Walter ^a   Luckas, Bernd ^a   Scherer, Gerd ^b  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

^b MAX PLANCK RESEARCH UNIT FOR ENZYMOLOGY OF PROTEIN FOLDING   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BORNANE DERIVATIVE; CAMPHECLOR;

ARTICLE; FISH; GAS CHROMATOGRAPHY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MARINE ENVIRONMENT; MASS SPECTROMETRY;

EID: 0029742895     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/0045-6535(96)00242-1     Document Type: Article

References (28)

1. Saleh, M. A. (1991) Toxaphene: chemistry, biochemistry, toxicity and environmental fate, Rev. Environ. Cont. Toxicol. 118, 1-85.
2. Voldner, E.C., Li, Y.F. (1995) Global usage of selected persistent organochlorines, Sci. Total Environ. 160/161, 201 - 210.
3. Heinisch, E., Klein, S. (1994) Zur Anwendung von Chlorkohlenwasserstoff-Pestiziden in der ehemaligen DDR - Folgewirkungen für Mensch und Umwelt- Produktions- und Anwendungsdaten, Gesunde Pflanzen 46, 20 - 24.
4. Akademie der Landwirtschaftswissenschaften der Deutschen Demokratischen Republik (Ed.) (1986) Pflanzenschutzmitterverzeichnis der DDR 1987/88, VEB Deutscher Landwirtschaftsverlag Berlin, pp 25ff.
5. Bidleman, T.F., Zaranski, M.T., Walla, M.D. (1988) Toxaphene: usage, aerial transport and deposition. In: N.W.Schmidtke (Ed.), Toxic Contamination in Large Lakes,Vol.I, Lewis Publishers, Chelsea, pp 257-284.
6. Jansson, B., Wideqvist, U. (1983) Analysis of toxaphene (PCC) and chlordane in biological samples by NCI mass spectrometry, Intern. J. Environ. Anal. Chem. 13, 309 - 321.
7. Saleh, M.A. (1983) Capillary gas chromatography-electron impact and chemical ionization mass spectrometry of toxaphene, J. Agric. Food Chem. 31, 748 - 751.
8. Casida, J.E., Holmstead, R.L., Khalifa, S., Knox, J.R., Ohsawa, T., Palmer, K.J., Wong, R.Y. (1974) Toxaphene insecticide: a complex biodegradable mixture, Science 183, 520 - 521.
9. Luckas, B., Vetter, W.. Fischer, P., Heidemann, G., Plötz, J. (1990) Characteristic chlorinated hydrocarbon patterns in the blubber of seals from different marine regions, Chemosphere 21, 13 - 19.
10. Stern, G.A., Muir, D.C.G., Ford, C.A., Grift, N.P., Dewaffly, E., Bidleman, T.F., Walla, M.D. (1992) Isolation and identification of two major recalcitrant toxaphene congeners in aquatic biota, Environ. Sci. Technol. 26, 1838-1840
11. Vetter, W., Krock, B., Luckas, B. (1996) Congener specific determination of compounds of technical toxaphene (CTTs) in different Antarctic seal species, Chromatographia, submitted.
12. Musial, C.J., Uthe, H.F. (1983) Widespread occurrence of the pesticide toxaphene in Canadian east coast marine fish, Intern. J. Environ. Anal. Chem. 14, 117 - 124.
13. Parlar, H. (1991) Chlorierte Bornan-Derivate - eine neue Klasse umweltrelevanter Chemikalien Nachr. Chem. Tech. Lab. 39, 26-37.
14. Parlar, H., Angerhöfer, D., Coelhan, M., Kimmel, L. (1995) HRGC and HRGC-ECNI determination of toxaphene residues in fish with a new 22 components standard, Organohalogen Compounds 26, 357 - 362, ISBN 3-928379-46-1.
15. Vetter, W., Luckas, B., Oehme, M. (1992) Isolation and purification of the two main toxaphene congeners in marine organisms, Chemosphere 25, 1643 - 1652.
16. Alawi, M., Barlas, H., Hainzl, D., Burhenne, J., Coelhan, M., Parlar, H. (1994) A contribution to the HRGC-MS and HRGC-ECD response factors of the environmental relevant toxaphene congeners, Fresenius Environ. Bull. 3, 350 - 357.
17. Vetter, W., Natzeck, C., Luckas, B., Heidemann, G., Kiabi, B., Karami, M. (1995) Chlorinated hydrocarbons in the blubber of a seal (Phoca caspica) from the Caspian Sea, Chemosphere 30, 1685-1696.
18. Swackhamer, D.L., Charles, M.J., Hites, R.A. (1987) Quantification of toxaphene in environmental samples using negative ion chemical ionization mass spectrometry, Anal. Chem. 59, 913 - 917.
19. Vaz, R., Blomkvist, G. (1985) Traces of toxaphene components in Swedish breast milk analyzed by capillary GC using ECD, electron impact and negative ion chemical ionization MS, Chemosphere 14, 223-231.
20. Parlar, H., Backer, F., Müller, R., Lach, G. (1988) Elimination of interfering compounds during GC determination of toxaphene residues by photodechlorination reactions, Fresenius Z. Anal. Chem. 331, 804 - 810.
21. Buser, H.-R., Oehme, M., Vetter, W., Luckas, B. (1993) Partial structure elucidation of the most abundant octa and nonachlorotoxaphene congeners in marine mammals by using conventional electron ionisation mass spectrometry and mass spectrometry/mass spectrometry, Fresenius J. Anal. Chem. 347, 502-512.
22. 1H-NMR structural assignment of TOX8 and TOX9, the two most abundant toxaphene congeners in marine mammals, Fresenius J. Anal. Chem. 349, 552 - 558.
23. Burhenne, J., Hainzl, D., Xu, L., Vieth, B., Alder, L., Parlar, H. (1993) Preperation and structure of high-chlorinated bornane derivatives for the quantification of toxaphene residues in environmental samples Fresenius J. Anal. Chem. 346, 779-785.
24. Nikifbrov, V. A., Tribulovich, V. G., Karavan, V. S. (1995) Experience in isolation of toxaphene congeners and prospects of congener-specific analysis of environmental samples, Organohalogen Compounds 26, 379 - 382, ISBN 3-928379-46-1.
25. Richards, S.A. (1988) Laboratory guide to proton NMR spectroscopy, Blackwell Scientific Publications, Oxford-London-Edinburgh-Boston-Palo Alto-Melbourne.
26. Rigaudy, J., Klesney, S.P. (1979) Nomenclature of organic chemistry. Sections A,B,C,D,E,F,H, 1979 edition. International Union of Pure and Applied Chemistry Organic Chemistry Division Commission on nomenclature of organic chemistry, Pergamon Press, Oxford.
27. Andrews, P., Vetter W. (1995) A systematic nomenclature system for toxaphene congeners. Part 1: chlorinated bornanes, Chemosphere 31, 3879 - 3886.
28. Vetter, W. (1993) Toxaphene. Theoretical aspects of the distribution of chlorinated bornanes including symmetrical aspects, Chemosphere 26, 1079 - 1084.