White phosphors from a silicate-carboxylate sol-gel precursor that lack metal activator ions

Science

Volumn 276, Issue 5320, 1997, Pages 1826-1828

  Green, Will H ^a   Le, Khoa P ^a   Grey, Jonathan ^a   Au, Tiffany T ^a   Sailor, Michael J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLIC ACID; PHOSPHORUS; SILICATE;

ARTICLE; BIOPHYSICS; ILLUMINATION; LUMINESCENCE; PRIORITY JOURNAL; ULTRAVIOLET RADIATION;

EID: 0030750454     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.276.5320.1826     Document Type: Article

References (48)

1. R. C. Ropp, in Luminescence and the Solid State (Elsevier, Amsterdam, Netherlands, 1991), vol. 12, pp. 283-352.
2. H. W. Leverenz, An Introduction to Luminescence of Solids (Dover, New York, 1968), pp. 407-420.
3. I. P. Benderskaya, I. F. Golubev, E. G. Morozov, Inorg. Mater. 29, 1279 (1993).
4. W. Xu, S. Dai, L. M. Toth, G. D. Del Cul, J. R. Peterson, J. Non-Cryst. Solids 194, 235 (1996).
5. F. Suzuki, K. Nakane, J. Piao, J. Mater. Sci. 31, 1335 (1996).
6. M. Pauthe, F. Despetis, J. Phalippou, J. Non-Cryst. Solids 155, 110 (1993).
7. K. Kamiya, T. Yoko, T. Sano, K. Tanaka, ibid. 119, 14 (1990).
8. L. Murawski et al., J. Mater. Sci. 25, 2569 (1990).
9. L. Bois, J. Maquet, F. Babonneau, H. Mutin, D. Bahloul, Chem. Mater. 6, 796 (1994).
10. E. Chomski, O. Dag, A. Kuperman, N. Coombs, G. A. Ozin, Chem. Vapor Deposition 2, 8 (1996).
11. M. P. Vinod and K. Vijayamohanan, Appl. Phys. Lett. 68, 81 (1996).
12. V. C. Costa, M. J. Lochhead, K. L. Bray, Chem. Mater. 8, 783 (1996).
13. J. M. McKierman et al., J. Inorg. Organomet. Polym. 1, 87 (1991).
14. C. J. Brinker and G. W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, San Diego, CA, 1990).
15. R. Reisfeld, in Sol-Gel Science and Technology, M. A. Aegerter, J. M. Jafelicci, D. F. Souza, E. D. Zanotto, Eds. (World Scientific, Singapore, 1989), pp. 323-345.
16. B. Luther-Davies, M. Samoc, M. Woodruff, Chem. Mater. 8, 2586 (1996).
17. S. A. Yamanaka, B. Dunn, J. S. Valentine, J. I. Zink, J. Am. Chem. Soc. 117, 9095 (1995).
18. -1 ramp, followed by a 4-hour isothermal hold. This procedure resulted in a transparent orange-colored glass with bright PL.
19. M. S. Wrighton, D. S. Ginley, D. L. Morse, J. Phys. Chem. 78, 2229 (1974).
20. M. A. Tamor and W. C. Vassel, J. Appl. Phys. 76, 3823 (1994).
21. F. Schwertfeger and U. Schubert, Chem. Mater. 7, 1909 (1995).
22. G. M. Renlund, S. Prochazka, R. H. Doremus, J. Mater. Res. 6, 2716 (1991).
23. _, ibid., p. 2723.
24. P. Robinson and D. Perlmutter, J. Non-Cryst. Solids 169, 183 (1994).
25. D. Ruter, S. Rolf, W. Bauhofer, Appl. Phys. Lett. 67, 149 (1995).
26. S. Hayashi, M. Kataoka, K. Yamamoto, Jpn. J. Appl. Phys. 32, L274 (1993).
27. T. Kitamura, Y. Takahashi, T. Yamanaka, K. Uchida, J. Lumin. 48-49, 373 (1991).
28. M. Sendova-Vassileva, N. Tzenov, D. Dimova-Malinovska, T. Marinova, V. Krastev, Thin Solid Films 276, 318 (1996).
29. N. Yamata, M. Sano, S. Yoshimura, Chem. Lett. 1, 21 (1996).
30. S. Liedtke, K. Lips, M. Bort, K. Jahn, W. Fuhs, J. Non-Cryst. Solids 114, 522 (1989).
31. T. Fujita, M. I. Abd-Elrahman, K. Takiyama, T. Oda, Philos. Mag. B74, 359 (1996).
32. F. Gaspari, R. V. Kruzelecky, P. K. Lim, L. S. Sidhu, S. Zukotynski, J. Appl. Phys. 79, 2684 (1996).
33. S. R. P. Silva, J. Robertson, Rusuli, G. A. J. Amaratunga, J. Schwan, Philos. Mag. B74, 369 (1996).
34. B. Arkles, "Silicon esters - alkoxy and acyloxysilanes" (product catalog, Gelest Inc., Tullytown, PA, 1995).
35. L. T. Canham et al., Thin Solid Films 276, 112 (1996).
36. S. Tajima, K. Shimizu, N. Baba, H. Sakai, Electrocompon. Sci. Technol. 3, 127 (1976).
37. A. O. Konstantinov, A. Henry, C. I. Harris, E. Janzen, Appl. Phys. Lett. 66, 2250 (1995).
38. D. R. Anderson, in Analysis of Silicones, A. L. Smith, ed. (Wiley, New York, 1974), vol. 1, pp. 247-286.
39. J. N. Demas and G. A. Crosby, J. Phys. Chem. 75, 991 (1971).
40. N. Auner and J. Weis, Eds., Organosilicon Chemistry II: From Molecules to Materials (VCH, New York, 1996).
41. Y. Charbouillot, D. Ravaine, M. Armand, C. Poinsignon, J. Non-Cryst. Solids 103, 325 (1988).
42. D. Levy and D. Avinir, J. Photochem. Photobiol. A Chem. 57, 41 (1991).
43. V. R. Kaufman, D. Levy, D. Avinir, J. Non-Cryst. Solids 82, 103 (1986).
44. J. Wen and G. L. Wilkes, Chem. Mater. 8, 1667 (1996).
45. E. Z. Faraggi et al., Adv. Mater. 8, 833 (1996).
46. D. Ravaine, A. Seminel, Y. Charbouillot, M. Vincens, J. Non-Cryst. Solids 82, 210 (1986).
47. H. Schmidt, ibid. 73, 681 (1985).
48. The authors wish to thank L. T. Canham, J. H. Golden, and M. Mariano for helpful discussions.