Organic-Soluble Neutral and Ionic Indium Siloxane Cages: Potential Precursors for Indium-Containing Silicates

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 20, 1997, Pages 2203-2205

  Voigt, Andreas ^a   Walawalkar, Mrinalini G ^a   Murugavel, Ramaswamy ^a   Roesky, Herbert W ^a   Parisini, Emilio ^a   Lubini, Paolo ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Alkali metals; Cage compounds; Indium; Silicon

Indexed keywords

EID: 0030693118     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199722031     Document Type: Article

References (29)

1. G. Giannetto, R. Monque, R. Galiasso, Catal. Rev. Sci. Eng. 1994, 36, 271.
2. M. Estermann, L. B. McCusker, C. Baerlocher, A. Merrouche, H. Kessler, Nature 1991, 352, 320.
3. a) M. Guisnet, N. S. Gnep, F. Alario, Appl. Catal. A 1992, 89, 1;
4. b) Y. Ono, Catal. Rev. Sci. Eng. 1992, 34, 179;
5. c) L. S. Marchenko, D. Z. Levin, V. A. Plakhotnik, E. S. Mortikov, Bull. Acad. Sci. USSR Div. Chem. Sci. Engl. Transl. 1986, 35, 81.
6. a) E. Kikuchi, M. Ogura, I. Terasaki, Y. Goto, J. Catal. 1996, 161, 465;
7. b) E. Kikuchi, K. Yogo, Catal. Today 1994, 22, 73.
8. a) R. Murugavel, A. Voigt, M. G. Walawalkar, H. W. Roesky, Chem. Rev. 1996, 96, 2205;
9. b) M. G. Voronkov, E. A. Maletina, V. K. Roman, Heterosiloxanes, (Soviet Scientific Review Supplement, Series Chemistry, Vol. 1), Academic Press, London, 1988;
10. c) F. J. Feher, T. A. Budzichowski, Polyhedron 1995, 14, 3239.
11. R. Murugavel, V. Chandrasekhar, H. W. Roesky, Acc. Chem. Res. 1996, 29, 183.
12. A. Voigt, R. Murugavel, M. Montero, H. Wessel, F.-Q. Liu, H. W. Roesky, I. Usón, T. Albers, E. Parisini, Angew. Chem. 1997, 109, 1020-1022; Angew. Chem. Int. Ed. Engl. 1997, 36, 1001-1003, and references therein.
13. A. Voigt, R. Murugavel, M. Montero, H. Wessel, F.-Q. Liu, H. W. Roesky, I. Usón, T. Albers, E. Parisini, Angew. Chem. 1997, 109, 1020-1022; Angew. Chem. Int. Ed. Engl. 1997, 36, 1001-1003, and references therein.
14. a) M. Montero, I. Usón, H. W. Roesky, Angew. Chem. 1994, 106, 2198; Angew. Chem. Int. Ed. Engl. 1994, 33, 2103;
15. a) M. Montero, I. Usón, H. W. Roesky, Angew. Chem. 1994, 106, 2198; Angew. Chem. Int. Ed. Engl. 1994, 33, 2103;
16. b) M. Montero, A. Voigt, M. Teichert, I. Usón, H. W. Roesky, ibid. 1995, 107, 2761 and 1995, 34, 2504;
17. b) M. Montero, A. Voigt, M. Teichert, I. Usón, H. W. Roesky, ibid. 1995, 107, 2761 and 1995, 34, 2504;
18. c) A. Voigt, R. Murugavel, E. Parisini, H. W. Roesky, ibid. 1996, 108, 823 and 1996, 35, 748;
19. c) A. Voigt, R. Murugavel, E. Parisini, H. W. Roesky, ibid. 1996, 108, 823 and 1996, 35, 748;
20. d) V. Chandrasekhar, R. Murugavel, A. Voigt, H. W. Roesky. H.-G. Schmidt, M. Noltemeyer, Organometallics 1996, 15, 918.
21. R. Murugavel, P. Böttcher, A. Voigt, M. G. Walawalkar, H. W. Roesky, E. Parisini, M. Teichert, M. Noltemeyer, Chem. Commun 1996, 2417.
22. Self-condensation of silanols in the presence of ionic acidic or basic impurities is well known, see ref. [9].
23. 2 [16]. All non-hydrogen atoms were refined anisotropically. Hydrogen atoms were added in idealized positions and included in the refinement. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100353. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: int. code + (1223)336-033; e-mail: deposit@chemcrys.cam.ac.uk).
24. a) S. S. Al-Juaid, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, A. T. L. Roberts, J. D. Smith, A. C. Sullivan, J. Chem. Soc. Chem. Commun. 1986, 908;
25. b) A. M. Arif, A. R. Barron, Polyhedron 1988, 7, 2091.
26. K. Hoffmann, E. Weiss, J. Organomet. Chem. 1972, 37, 1.
27. W. Clegg, Acta Crystallogr. Sect. A 1981, 37, 22.
28. G. M. Sheldrick, SHELXS-90/96, Program for Structure Solution: Acta Crystallogr. Sect. A 1990, 46, 467.
29. G. M. Sheldrick, SHELXL-93/96, Program for Crystal Structure Refinement, Universität Göttingen, 1993.