Tropospheric air pollution: Ozone, airborne toxics, polycyclic aromatic hydrocarbons, and particles

Science

Volumn 276, Issue 5315, 1997, Pages 1045-1052

  Finlayson Pitts, Barbara J ^a   Pitts Jr , James N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HALOGEN; HYDROXYL RADICAL; NITRATE; NITROGEN OXIDE; OZONE; POLYCYCLIC AROMATIC HYDROCARBON; VOLATILE ORGANIC COMPOUND;

AIR POLLUTANT; AIR POLLUTION; AIRBORNE PARTICLE; AMBIENT AIR; ARTICLE; EXHAUST GAS; MUTAGENICITY; OXIDATION; PRIORITY JOURNAL; RISK ASSESSMENT; TROPOSPHERE;

ATMOSPHERIC POLLUTION; HYDROXYL RADICAL; NITROGEN OXIDES; OXIDATION; OZONE; PAH; PARTICULATE MATTER; TROPOSPHERE; VOC;

EID: 0030618076     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.276.5315.1045     Document Type: Article

References (194)

1. P. Brimblecombe, Notes Rec. R. Soc. 32, 123 (1978).
2. V. Goodhill, Trans. Am. Acad. Opthalmol. Oto-laryngol. 463 (1971).
3. M. O. Andreae and P. J. Crutzen, Science 1052 (1997).
4. A. R. Ravishankara, ibid., p. 1058.
5. J. Fishman and P. J. Crutzen, Nature 274, 855 (1978).
6. J. Logan, J. Geophys. Res. 90, 10463 (1985).
7. R. D. Bojkov, J. Am. Meteorol. Soc. 25, 343 (1986).
8. A. Volz and D. Kley, Nature 332, 240 (1988).
9. D. Anfossi, S. Sandroni, S. Viarengo, J. Geophys. Res. 96, 17349 (1991).
10. A. P. Altshuller, J. Air Pollut. Control Assoc. 37, 1409 (1987).
11. P. J. Crutzen, Faraday Discuss. 100, 1 (1995).
12. J. N. Pitts Jr., Res. Chem. Intermed. 19, 251 (1993).
13. _, in Occupational Medicine: State of the Art Reviews (Hanley & Belfus, Philadelphia, PA, 1993), pp. 621-662.
14. J. R. Holton et al., Rev. Geophys. 33, 403 (1995).
15. M. Lenner, Atmos. Environ. 21, 37 (1987).
16. B. J. Finlayson-Pitts and J. N. Pitts Jr., Atmospheric Chemistry: Fundamentals and Experimental Techniques (Wiley, New York, 1986), and references therein.
17. R. Atkinson, A. M. Winer, J. N. Pitts Jr., Atmos. Environ. 20, 331 (1986).
18. U. Platt, in Air Monitoring by Spectroscopic Techniques, J. D. Winefordner, Ed. (Wiley, New York, 1994), pp. 27-85.
19. J. P. Smith et al., J. Geophys. Res. 98, 8983 (1993).
20. A. G. Russell, G. J. McRae, G. R. Cass, Atmos. Environ. 19, 893 (1985).
21. F. J. Dentener and P. J. Crutzen, J. Geophys. Res. 98, 7149 (1993).
22. A. M. Winer, in Handbook of Air Pollution Analysis, R. M. Harrison and R. Perry, Eds. (Chapman and Hall, London, ed. 2, 1985), chap. 3.
23. _ and H. W. Biermann, Res. Chem. Intermed. 20, 423 (1994).
24. J. N. Pitts Jr., H. W. Biermann, A. M. Winer, E. C. Tuazon, Atmos. Environ. 18, 847 (1984).
25. T. W. Kirchstetter, R. A. Harley, D. Littlejohn, Environ. Sci. Technol. 30, 2843 (1996).
26. A. Febo and C. Perrino, Atmos. Environ. 29, 345 (1995).
27. J. N. Pitts Jr., T. J. Wallington, H. W. Biermann, A. M. Winer, ibid. 19, 763 (1985).
28. J. N. Pitts Jr. et al., J. Air Pollut. Control Assoc. 39, 1344 (1989).
29. J. D. Spengler, M. Brauer, J. M. Samet, W. E. Lambert, Environ. Sci. Technol. 27, 841 (1993).
30. A. Febo and C. Perrino, Atmos. Environ. 25, 1055 (1991).
31. C. W. Spicer, D. V. Kenny, G. F. Ward, I. H. Billick, J. Air Waste Manage. Assoc. 43, 1479 (1993).
32. Z. Vecera and P. K. Dasgupta, Int. J. Environ. Anal. Chem. 56, 311 (1994).
33. F. Sakamaki, S. Hatakeyama, H. Akimoto, Int. J. Chem. Kinet. 15, 1013 (1983).
34. J. N. Pitts Jr. etal., ibid. 16, 919 (1984).
35. R. Svensson, E. Ljungström, O. Lindqvist, Atmos. Environ. 21, 1529 (1987).
36. M. E. Jenkin, R. A. Cox, D. J. Williams, ibid. 22, 487 (1988).
37. A. Bambauer, B. Brantner, M. Paige, T. Novakov, ibid. 28, 3225 (1994).
38. S. Mertes and A. Wahner, J. Phys. Chem. 99, 14000 (1995).
39. G. Lammel and J. N. Cape, Chem. Rev. 25, 361 (1996).
40. R. Atkinson, S. M. Aschmann, J. Arey, B. Shorees, J. Geophys. Res. 97, 6065 (1992).
41. R. Atkinson and S. M. Aschmann, Environ. Sci. Technol. 27, 1357(1993).
42. D. Grosjean, E. Grosjean, E. L. Williams, ibid. 28, 186 (1994).
43. S. E. Paulson and J. J. Orlando, Geophys. Res. Lett. 23, 3727 (1996).
44. B. J. Finlayson-Pitts, Res. Chem. Int. 19, 235 (1993).
45. T. E. Graedel and W. C. Keene, Global Biogeochem. Cyc. 9, 47 (1995).
46. R. J. Cicerone, Rev. Geophys. Space Phys. 19, 123 (1981).
47. J. W. Fitzgerald, Atmos. Environ. 25A, 533 (1991).
48. C. D. O'Dowd, M. H. Smith, I. E. Consterdine, J. A. Lowe, ibid. 31, 73 (1997).
49. B. J. Finlayson-Pitts, M. J. Ezell, J. N. Pitts Jr., Nature 337, 241 (1989).
50. W. Behnke, C. George, V. Scheer, C. Zetzsch, J. Geophys. Res. 102, 3795 (1997).
51. W. B. DeMore et al., JPL Publ. No. 97-4 (1997).
52. L. A. Barrie, J. W. Bottenheim, R. C. Schnell, P. J. Crutzen, R. A. Rasmussen, Nature 334, 138 (1988).
53. R. Vogt, P. J. Crutzen, R. Sander, ibid. 383, 327 (1996).
54. B. J. Finlayson-Pitts, F. E. Livingston, H. N. Berko, ibid. 343, 622 (1990).
55. J. C. McConnell et al., ibid. 355, 150 (1992).
56. S.-M. Fan and D. J. Jacob, ibid. 359, 522 (1992).
57. H. Niki and K. H. Becker, The Tropospheric Chemistry of Ozone in the Polar Regions (Springer-Verlag, Berlin, 1992).
58. G. LeBras and U. Platt, Geophys. Res. Lett. 22, 599 (1995).
59. G. A. Impey, P. B. Shepson, D. R. Hastie, L. A. Barrie, K. Anlauf, J. Geophys. Res., in press.
60. B. T. Jobson et al., ibid. 99, 25355 (1994).
61. S. McKeen and S. C. Liu, Geophys. Res. Lett. 20, 2363 (1993).
62. O. W. Wingenter et al., J. Geophys. Res. 101, 4331 (1996).
63. H. B. Singh et al., ibid., p. 1907.
64. H. B Singh, A. N. Thakur, Y. E. Chen, M. Kanakidou, Geophys. Res. Lett. 23, 1529 (1996).
65. J. Rudolph, R. Koppmann, C. H. Plass-Dülmer, Atmos. Environ. 30, 1887 (1996).
66. W. C. Keene, D. J. Jacob, S.-M. Fan, ibid., p. i.
67. W. C. Keene, J. R. Maben, A. A. P. Pszenny, J. N. Galloway, Environ. Sci. Technol. 27, 866 (1993).
68. A. A. P. Pszenny et al., Geophys. Res. Lett. 20, 699 (1993).
69. C. W. Spicer et al., in preparation.
70. P. Beichert and B. J. Finlayson-Pitts, J. Phys. Chem. 100, 15218 (1996).
71. S. Langer, R. S. Pemberton, B. J. Finlayson-Pitts, ibid. 101, 1277 (1997).
72. R. Vogt et al., Atmos. Environ. 30, 1729 (1996).
73. H. C. Allen, J. M. Laux, R. Vogt, B. J. Finlayson-Pitts, J. C. Hemminger, J. Phys. Chem. 100, 6371 (1996).
74. J. M. Laux, T. F. Fister, B. J. Finlayson-Pitts, J. C. Hemminger, ibid., p. 19891.
75. National Academy of Sciences, Rethinking the Ozone Problem in Urban and Regional Air Pollution (National Academy Press, Washington, DC, 1991).
76. J. G. Calvert, J. B. Heywood, R. F. Sawyer, J. H. Seinfeld, Science 261, 37 (1993).
77. B. J. Finlayson-Pitts and J. N. Pitts, J. Air Waste Manag. Assoc. 43, 1091 (1993).
78. A. J. Haagen-Smit and M. M. Fox, Ind. Eng. Chem. 48, 1484 (1956).
79. W. P. L. Carter and R. Atkinson, Environ. Sci. Technol. 21, 670 (1987).
80. _, ibid. 23, 864 (1989).
81. Y. Andersson-Sköld, P. Grennfelt, K. Pleijel, J. Air Waste Manage. Assoc. 42, 1152 (1992).
82. B. E. Croes, J. R. Holmes, A. C. Lloyd, ibid., p. 657.
83. F. M. Bowman and J. H. Seinfeld, J. Geophys. Res. 99, 5309 (1994).
84. W. P. L. Carter, J. Air Waste Manage. Assoc. 44, 881 (1994).
85. _, Atmos. Environ. 29, 2513 (1995).
86. _, J. A. Pierce, D. Luo, I. L. Malkina, ibid., p. 2499.
87. F. M. Bowman, C. Pilinis, J. H. Seinfeld, ibid., p. 579.
88. R. G. Derwent, M. E. Jenkin, S. M. Saunders, ibid. 30, 181 (1996).
89. J. N. Seiber, ibid., p. 751.
90. T. J. Kelly, R. Mukund, C. W. Spicer, A. J. Pollack, Environ. Sci. Technol. 28, 378A (1994).
91. D. R. Lawson et al., Aerosol Sci. Technol. 12, 64 (1990).
92. L. G. Anderson et al., Atmos. Environ. 30, 2113 (1996).
93. E. Grosjean, D. Grosjean, M. P. Fraser, G. R. Cass, Environ. Sci. Technol. 30, 2687 (1996).
94. M. F. Wolfe and J. N. Seiber, in Occupational Medicine: State of the Art Reviews, D. J. Shusterman and J. E. Peterson, Eds. (Hanley & Belfus, Philadelphia, PA, 1993), pp. 561-573.
95. J. N. Seiber and J. E. Woodrow, in Proceedings, Eighth International Congress of Pesticide Chemistry, Washington, DC, 4 to 9 July 1994 (American Chemical Society, Washington, DC, 1995).
96. E. C. Tuazon, R. Atkinson, A. M. Winer, J. N. Pitts Jr., Arch. Environ. Contam. Toxicol. 13, 691 (1984).
97. A. M. Winer and R. Atkinson, in Long Range Transport of Pesticides, D. A. Kurtz, Ed. (Lewis, Chelsea, MI, 1990), pp. 115-126.
98. M. A. Brown, M. X. Petreas, H. S. Okamoto, T. M. Mischke, R. D. Stephens, Environ. Sci. Technol. 27, 388 (1993).
99. National Academy of Sciences, Particulate Polycyclic Organic Matter (National Academy Press, Washington, DC, 1972).
100. A. Bjørseth, Ed., Handbook of Polycyclic Aromatic Hydrocarbons (Dekker, New York, 1983).
101. National Academy of Sciences, Polycyclic Aromatic Hydrocarbons: Evaluation of Sources and Effects (National Academy Press, Washington, DC, 1983).
102. G. Grimmer, Ed., Environmental Carcinogens: Polycyclic Aromatic Hydrocarbons: Chemistry, Occurrence, Biochemistry, Carcinogenicity (CRC Press, Boca Raton, FL, 1983).
103. A. Bjørseth and T. Ramdahl, Eds., Handbook of Polycyclic Aromatic Hydrocarbons, Vol. 2, Emission Sources and Recent Advances in Analytical Chemistry (Dekker, New York, 1985).
104. K. E. Thrane and A. Mikalsen, Atmos. Environ. 15, 909 (1981).
105. J. O. Allen et al., Environ. Sci. Technol. 30, 1023 (1996).
106. C. Venkataraman and S. K. Friedlander, ibid. 28, 563 (1994).
107. International Agency for Research on Cancer (IARC), "Diesel and Gasoline Engine Exhausts and Some Nitroarenes," in Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 46 (IARC, Lyon, France, 1989).
108. R. N. Westerholm et al., Environ. Sci. Technol. 25, 332 (1991).
109. W. F. Rogge, L. M. Hildemann, M. A. Mazurek, G. R. Cass, B. R. T. Simoneit, ibid. 27, 636 (1993).
110. R. Hammerle, D. Schuetzle, W. Adams, Environ. Health Perspect. 102, 25 (1994).
111. J. H. Johnson, S. T. Bagley, L. D. Gratz, D. G. Leddy. Soc. Automot. Eng. Trans. 103, 210 (1994).
112. D. H. Lowenthal et al., Atmos. Environ. 28, 731 (1994).
113. K. J. Baumgard and J. H. Johnson, Soc. Automot. Eng. 960131 (Spec. Publ. 1140, 1996, p. 37).
114. T. Nielsen, Atmos. Environ. 30, 3481 (1996).
115. L. A. Gundel, V. C. Lee, K. R. R. Mahanama, R. K. Stevens, J. M. Daisey, ibid. 29, 1719 (1995).
116. G. Löfroth, Chemosphere 7, 791 (1978).
117. T. Ramdahl, Nature 306, 580 (1983).
118. J. Leiter, M. B. Shimkin, M. J. Shear, J. Natl. Cancer Inst. 3, 155 (1942).
119. D. H. Phillips, Nature 303, 468 (1983).
120. T. Nielsen, H. E. Jørgensen, J. Chr. Larsen, M. Poulsen, Sci. Total. Environ. 190, 41 (1996).
121. California Air Resources Board, Benzo[a]pyrene as a Toxic Air Contaminant (July 1994). For information, contact J. Denton, Air Resources Board, Stationary Source Division, Air Quality Measures Branch, P.O. Box 2815, Sacramento, CA 95812-2815.
122. J. N. Pitts Jr., D. Grosjean, T. M. Mischke, V. F. Simmon, D. Poole, Toxicol. Lett. 1, 65 (1977).
123. R. E. Talcott and E. T. Wei, J. Natl. Cancer Inst. 58, 449 (1977).
124. H. Tokiwa, K. Morita, H. Takeyoshi, K. Takahashi, Y. Ohnishi, Mutat. Res. 48, 237 (1977).
125. W. Dehnen, N. Pitz and R. Tomingas, Cancer Lett. 4, 5 (1977).
126. I. Alfheim, G. Löfroth, M. Møller, Environ. Health Perspect. 47, 227 (1983).
127. I. Alfheim, G. Becher, J. K. Hongslo, T. Ramdahl, Environ. Mutagen. 6, 91 (1984).
128. I. Alfheim, A. Bjørseth, M. Møller, Crit. Rev. Environ. Control 14, 91 (1984).
129. B. N. Ames, J. McCann, E. Yamasaki, Mutat. Res. 31, 347 (1975).
130. D. M. Maron and B. N. Ames. ibid. 113, 173 (1983).
131. W. L. Belser Jr. et al., Environ. Mutagen. 3, 123 (1981).
132. L. D. Claxton et al., Mutat. Res. 276, 61 (1992).
133. J. Tuominen et al., Environ. Sci. Technol. 22, 1228 (1988).
134. R. Villalobos-Pietrini, S. Blanco, S. Gomez-Arroyo, Atmos. Environ. 29, 517 (1995).
135. L. G. Viras, K. Athanasiou, P. A. Siskos, ibid. 24B, 267 (1990).
136. A. G. Miguel, J. M. Daisey, J. A. Sousa, Environ. Mol. Mutagen. 15, 36 (1990).
137. R. Barale et al., Environ. Health Perspect. 102 67 (1994).
138. T. R. Skopek, H. L. Liber, D. A. Kaden, W. G. Thilly, Proc. Natl. Acad. Sci. U.S.A. 75, 4465 (1978).
139. M. P. Hannigan, G. R. Cass, A. L. Lafleur, J. P. Longwell, W. G. Thilly, Environ. Sci. Technol. 28 2014 (1994).
140. M. P. Hannigan, G. R. Cass, A. L. Lafleur, W. F. Busby Jr., W. G. Thilly, Environ. Health Perspect. 104, 428 (1996).
141. M. P. Hannigan et al., Environ. Sci. Technol. 31, 438 (1997).
142. J. Lewtas, Environ. Health Perspect. 100, 211 (1993).
143. W. F. Busby Jr., H. Smith, W. W. Bishop, W. G. Thilly, Mutat. Res. 322, 221 (1994).
144. W. F. Busby Jr., B. W. Penman, C. L. Crespi, ibid., p. 233.
145. W. F. Busby Jr., H. Smith, C. L. Crespi, B. W. Penman, Mutat. Res. Genet. Toxicol. 342, 9 (1995).
146. T. Nielsen, T. Ramdahl, A. Bjørseth, Environ. Health Perspect. 47, 103 (1983).
147. J. N. Pitts Jr., ibid., p. 115.
148. _, Atmos. Environ. 21, 2531 (1987).
149. J. Arey, W. P. Harger, D. Helmig, R. Atkinson, Mutat. Res. 281, 67 (1992).
150. R. Atkinson and J. Arey, Environ. Health Perspect. 102 (suppl. 4), 117 (1994).
151. J. Huisingh et al., in Applications of Short-Term Bioassay in the Fractionation and Analysis of Complex Environmental Mixtures, M. D. Waters, S. Nesnow, J. L. Huisingh, S. Sandhu, L. Claxton, Eds. (Plenum, New York, 1979), pp. 383-418.
152. N. Y. Kado, D. Langley, E. Eisenstadt, Mutat. Res. 121, 25 (1983).
153. D. Schuetzle and J. Lewtas, Anal. Chem. 58, 1060A (1986).
154. YY. Wang, S. M. Rappaport, R. F. Sawyer, R. E. Talcott, E. T. Wei, Cancer Lett. 5, 39 (1978).
155. C. E. Chnsp, G. L. Fisher, J. E. Lammert, Science 199, 73 (1978).
156. J. Jäger, J. Chromatogr. 152, 575 (1978).
157. H. S. Rosenkranz and R. Mermelstein, J. Environ, Sci. Health C3, 221 (1985).
158. H. Tokiwa and Y. Ohnishi, CRC Crit. Rev. Toxicol. 17, 23 (1986).
159. C. Y. Wang, M.-S. Lee, C. M. King, P. O. Warner, Chemosphere 9, 83 (1980).
160. C. M. White, Ed., Nitrated Polycyclic Aromatic Hydrocarbons (Hüethig, Heidelberg, Germany, 1985).
161. J. Lewtas and M. G. Nishioka, in Nitroarenes: Occurrence, Metabolism, and Biological Impact (Plenum, New York, 1990), pp. 61-72.
162. T. Nielsen, Environ. Sci. Technol. 18, 157 (1984).
163. _ and T. Ramdahl, Atmos. Environ. 20, 1507 (1986).
164. T. Ramdahl et al., Nature 321, 425 (1986).
165. J. N. Pitts Jr., J. A. Sweetman, B. Zielinska, A. M. Winer, R. Atkinson, Atmos. Environ. 19, 1601 (1985).
166. T. Nielsen, B. Seitz, T. Ramdahl, ibid. 18, 2159 (1984).
167. P. Ciccioli et al., J. Geophys. Res. 101, 19567 (1996) and references therein.
168. J. Arey et al., Atmos. Environ. 20, 2339 (1986).
169. R. Knispel, R. Koch, M. Siese, C. Zetzsch, Ber. Bunsen-Ges. Phys. Chem. 94, 1375 (1990).
170. E. Bjergbakke, A. Sillesen, P. Pagsberg, J. Phys. Chem. 100, 5729 (1996).
171. R. Atkinson, J. Arey, B. Zielinska, S. M. Aschmann, Environ. Sci. Technol. 21, 1014 (1987).
172. B. Zielinska, J. Arey, R. Atkinson, P. A. McElroy, ibid. 23, 723 (1989).
173. J. N. Pitts Jr. et al., ibid. 19, 1115 (1985).
174. D. Helmig, J, Arey, W. P. Harger, R. Atkinson, J. López-Cancio, ibid. 26, 622 (1992).
175. D. Helmig, J. López-Cancio, J. Arey, W. P. Harger, R. Atkinson, ibid., p. 2207.
176. E. S. C. Kwok, W. P. Harger, J. Arey, R. Atkinson, ibid. 28, 521 (1994).
177. P. Gupta, W. P. Harger, J. Arey, Atmos. Environ. 30, 3157 (1996).
178. W. P. Harger, J. Arey, R. Atkinson, ibid. 26A, 2463 (1992).
179. L. A. Gundel, J. M. Daisey, L. R. F. de Carvalho, N. Y. Kado, D. Schuetzle, Environ. Sci. Technol. 27, 2112 (1993).
180. J. N. Pitts Jr. et al., Science 202, 515 (1978).
181. K. Nikolaou, P. Masclet, G. Mouvier, Sci. Total Environ. 32, 103 (1984).
182. K. A. Van Cauwenberghe, in Handbook of Polycyclic Aromatic Hydrocarbons (Dekker, New York, 1985), pp. 351-384.
183. Z. Fan, D. Chen, P. Birla, R. M. Kamens, Atmos. Environ. 29, 1171 (1995).
184. Z. Fan, R. M. Kamens, J. Zhang, J. Hu, Environ. Sci. Technol. 30, 2821 (1996).
185. D. W. Dockery et al., W. Engl. J. Med. 329, 1753 (1993).
186. R. F. Phalen and D. V. Bates, Inhalation Toxicol. 7, 1 (1995).
187. J. Schwartz, D. W. Dockery, L. M. Neas, Air Waste Manage. Assoc. 46, 927 (1996).
188. R. F. Phalen, Inhalation Studies: Foundation and Techniques (CRC Press, Boca Raton, FL, 1984).
189. A. S. Kao and S. K. Friedlander, Inhalation Toxicol. 7, 149 (1995).
190. W. F. Rogge, M. A. Mazurek, L. M. Hildemann, G. R. Cass, B. R. T. Simoneit, Atmos. Environ. 27A, 1309 (1993).
191. S. N. Pandis, A. S. Wexler, J. H. Seinfeld, J. Phys. Chem. 99, 9646 (1995).
192. B. J. Turpin, J. J. Huntzicker, S. M. Larson, G. R. Cass, Environ. Sci. Technol. 25, 1788 (1991).
193. K. T. Whitby and G. M. Sverdrup, Adv. Environ. Sci. Technol. 10, 477 (1980).
194. The authors are grateful to a number of granting agencies and individuals who have provided leadership and support to the atmospheric chemistry community, including NSF; the U.S. Department of Energy; the U.S. Environmental Protection Agency; the California Air Resources Board; the National Institute of Environmental Health Sciences; The Research Corporation; and especially J. Moyers, J. Hales, R. Patterson, J. Holmes, G. Malindzak and the late R. Carrigan. We are also grateful to many colleagues at the Statewide Air Pollution Research Center at the University of California, Riverside; the Departments of Chemistry and Earth System Science at the University of California. Irvine; and the California Air Resources Board. We thank T. Nielsen, J. Johnson, J. Seiber, A. R. Ravishankara, M. O. Andreae, and P. J. Crutzen for helpful discussions; B. T. Jobson and D. Kley for permission to reproduce figures from their papers; J. Arey and R. Atkinson for helpful comments on the manuscript; and M. Minnich for assistance in its preparation.