Some new laboratory approaches to studying tropospheric heterogeneous reactions

Atmospheric Environment

Volumn 30, Issue 10-11, 1996, Pages 1729-1737

  Vogt, R ^a   Elliott, C ^a   Allen, H C ^a   Laux, J M ^a   Hemminger, J C ^a   Finlayson Pitts, B J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Heterogeneous reactions; Marine atmosphere; Sea salt; Sodium chloride; Troposphere

Indexed keywords

CLIMATE CHANGE; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAS EMISSIONS; MATHEMATICAL MODELS; NITRIC ACID; NITROGEN OXIDES; PARTICLES (PARTICULATE MATTER); SODIUM COMPOUNDS; TRANSMISSION ELECTRON MICROSCOPY; TROPOSPHERE; X RAY PHOTOELECTRON SPECTROSCOPY; X RAY SPECTROSCOPY;

ENERGY DISPERSIVE X RAY SPECTROSCOPY; MICROCRYSTALLITES; SODIUM NITRATES;

ATMOSPHERIC CHEMISTRY;

NITRIC ACID; NITROGEN DIOXIDE; NITROGEN OXIDE; SODIUM BROMIDE; SODIUM CHLORIDE;

CONFERENCE PAPER; GLOBAL CLIMATE; INFRARED SPECTROSCOPY; LABORATORY; MARINE ENVIRONMENT; PRIORITY JOURNAL; REACTION ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; TROPOSPHERE; X RAY SPECTROMETRY;

ANALYTICAL TECHNIQUES; ATMOSPHERIC CHEMISTRY;

EID: 0030131760     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/1352-2310(95)00392-4     Document Type: Conference Paper

References (40)

1. Abbatt J. P. D., Beyer K. D., Fucaloro A. F., McMahon J.R., Wooldridge P. J., Zhang R. and Molina M. R. (1992) Interaction of HCl with water-ice: implications for the stratosphere. J. geophys. Res. 97, 15,819-15,826.
2. Baldwin A. C. and Golden D. M. (1979) Heterogeneous atmospheric reactions: sulfuric acid aerosols as tropospheric sinks. Science 206, 562-563.
3. Barrie L. A., Bottenheim J. W., Schnell R. C., Crutzen P. J. and Rasmussen R. A. (1988) Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere. Nature 334, 138-141.
4. 3 and wet NaCl. J. Aerosol Sci. 23, S933-S936.
5. 4-Aerosol. J. Aerosol Sci. 24, S115-S116.
6. Briggs S. and Seah M. P. (1990) Practical Surface Analysis, pp. 210-211. Wiley, New York.
7. Busek P. R. and Bradley J. P. (1992) Electron beam studies of individual natural and anthropogenic microparticles: composition, structures, and surface reactions. In Heterogeneous Atmospheric Chemistry (edited by Schryer D. R.) Geophysical Monograph Vol. 26, pp. 57-76. American Geophysical Union, Washington, District of Columbia.
8. DeMore W. B., Sander S. P., Golden D.M., Hampson R. F., Kurylo M. J., Howard C. J., Ravishankara A. R., Kolb C. E. and Molina M. J. (1994) Chemical kinetics and photochemical data for use in stratospheric modeling, JPL Publ. No. 94-26, December 15, 1994.
9. 3, and OH. J. geophys. Res. 98, 7149-7163.
10. Dwyer V. M. (1994) Extraction of inelastic mean free path data from elastic electron backscattering data. J. Vac. Sci. Technol. A 12, 2680-2684.
11. Fenter F. F., Caloz F. and Rossi M. J. (1994) Kinetics of nitric acid uptake by salt. J. phys. Chem. 98, 9801-9810.
12. 2 with NaCl and atmospheric implications of NOCl Formation. Nature 306, 676-677.
13. Finlayson-Pitts B. J. and Pitts J. N. Jr. (1986) Atmospheric Chemistry: Fundamentals and Experimental Techniques. Wiley, New York.
14. 2 with NaBr: Possible source of BrNO in polluted marine atmospheres. Atmospheric Environment. 22, 1107-1112.
15. 2. J. phys. Chem. 93, 4397-4400.
16. 2. Nature 337, 241-244.
17. Finlayson-Pitts B. J. (1993) Chlorine atoms as a potential tropospheric oxidant in the marine boundary layer. Res. Chem. Int. 19, 235-249.
18. 5 by water and NaCl solutions. J. phys. Chem. 98, 8780-8784.
19. Graedel T. E. and Keene W. C. (1995) The tropospheric budget of reactive chlorine. Global Biogeochem. Cycles 9, 47-77.
20. Greenberg A., Trussel R. R., Clesceri L. S. and Franson M. A. H., Eds. (1985) Standard methods for the examination of water and waste water. American Public Health Association, American Water Works Association and Water Pollution Control Federation; American Public Health Association, Washington District of Columbia.
21. 5 on Polar Stratospheric Cloud materials. J. geophys. Res. 96 D3, 5081-5090.
22. 6 hydrocarbon during the polar sunrise 1992 experiment: evidence for Cl atom and Br atom chemistry. J. geophys. Res. 99, 25,355-25,368.
23. 2 production. Atmospheric Environment, 26A, 3099-3103.
24. Karlsson R. and Ljungström E. (1995) Nitrogen dioxide and sea salt particles-a laboratory study. J. Aerosol Sci. 26, 39-50.
25. Laux J. M., Hemminger J. C. and Finlayson-Pitts B. J. (1994) X-ray photoelectron spectroscopic studies of the heterogeneous reaction of gaseous nitric acid with sodium chloride: Kinetics and contribution to the chemistry of the marine troposphere. Geophys. Res. Lett. 21, 1623-1626.
26. 3(s). J. phys. Chem. 99, 13,203-13,212.
27. 5 with solid NaCl at 298 K: estimated lower limit to the reaction probability and its potential role in tropospheric and stratospheric chemistry. Geophys. Res. Lett. 18, 17-20.
28. Moulder J. F., Stickle W. F., Sobol P. E. and Bomben K. D. (1992) Handbook of X-ray Photoelectron Spectroscopy. Perkin Elmer Corporation, Physical Electronics Division Eden Prarie, Minnesota.
29. Mouri H. and Okada H. (1993) Shattering and modification of sea-salt particles in the marine atmosphere. Geophys. Res. Lett. 20, 49-52.
30. 5 on aqueous aerosols. J. geophys. Res. 93, 15,889-15,896.
31. Posfai M., Anderson J. R., Busek P. R. and Sievering H. (1993) Compositional variations of sea-salt mode aerosol particles from the north atlantic. Paper presented at the AGU Fall Meeting, San Francisco.
32. Posfai M., Anderson J. R., Busek P. R., Shattuck T. W., Tindale N. W. (1994) Constituents of a remote pacific marine aerosol: a TEM study. Atmospheric Environment 28, 1747-1756.
33. 5 on ice and nitric acid trihydrate. J. phys. Chem. 94, 3255-3260.
34. Rossi M. J., Malhotra R. and Golden D. M. (1987) Heterogeneous chemical reaction of chlorine nitrate and water on sulfuric-acid surfaces at room temperature. Geophys. Res. Lett. 14, 127-130.
35. 3(s). J. phys. Chem. 98, 9509-9517.
36. 3. J. phys. Chem. 98, 3747-3755; (1995) J. phys. Chem. 99, 13,052.
37. 3. J. phys. Chem. 98, 3747-3755; (1995) J. phys. Chem. 99, 13,052.
38. Winkler T., Goschnick J. and Ache H. J. (1991) Reactions of nitrogen oxides with NaCl as model of sea salt aerosol. J. Aerosol Sci. 22, S605-S608.
39. 2 on aqueous surfaces. J. phys. Chem. 93, 1159-1172.
40. Zetzsch C. and Behnke W. (1992) Heterogeneous photochemical sources of atomic Cl in the Troposphere. Ber. Bunsenges. Phys. Chem. 96, 488-493.