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Volumn 118, Issue 41, 1996, Pages 9941-9952

Chromium dioxide cation OCrO+ in the gas phase: Structure, electronic states, and the reactivity with hydrogen and hydrocarbons

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE; METAL OXIDE;

EID: 0029973915     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960157k     Document Type: Article
Times cited : (116)

References (114)
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    • Technical note: When performing EI in the external ion source of the Spectrospin CMS 47X FTICR mass spectrometer used here, the parameter XDFL of the transfer optics should not exceed an absolute value of ±20 V, because this potential is used for deflection of the ions during mass-selection and the subsequent ion/molecule reactions. Otherwise externally generated ions may enter the ICR cell during the duty cycle and produce false results.
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    • + ions may be formed in excited rovibronic states. As we cannot discriminate between these two possibilities, we have not further attempted to resolve this issue.
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    • Most likely, the hydrogen atom from the methoxy group is directly transferred to the other hydrogen in 5 without involving a dihydrido-metal intermediate; see: (a) Holthausen, M. C.; Fiedler, A.; Schwarz, H.; Koch, W. Angew. Chem., Int. Ed. Engl. 1995, 34, 2282. (b) Holthausen, M. C.; Fiedler, A.; Schwarz, H.; Koch, W. J. Phys. Chem. 1996, 100, 6236.
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    • + precursor ion.
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    • + and have not attempted to further characterize this product.
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    • + does not require curve crossing.
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    • min, value is due to a sensitive dependence of the data on ion source conditions rather than too low ion intensities.
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    • note
    • 1) ground state; the latter ion is unreactive toward O2.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.