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Technical note: When performing EI in the external ion source of the Spectrospin CMS 47X FTICR mass spectrometer used here, the parameter XDFL of the transfer optics should not exceed an absolute value of ±20 V, because this potential is used for deflection of the ions during mass-selection and the subsequent ion/molecule reactions. Otherwise externally generated ions may enter the ICR cell during the duty cycle and produce false results.
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+ ions may be formed in excited rovibronic states. As we cannot discriminate between these two possibilities, we have not further attempted to resolve this issue.
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, pp. 7711
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Schalley, C.A.1
Wesendrup, R.2
Schröder, D.3
Schwarz, H.4
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81
-
-
84989509356
-
-
(b) Wesendrup, R.; Schalley, C. A.; Schröder, D.; Schwarz, H. Chem. Eur. J. 1995, I, 608.
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(1995)
Chem. Eur. J.
, vol.1
, pp. 608
-
-
Wesendrup, R.1
Schalley, C.A.2
Schröder, D.3
Schwarz, H.4
-
84
-
-
0021095667
-
-
(a) Carlin, T. J.; Sallans, L.; Cassady, C. J.; Jacobson, D. B.; Freiser, B. S. J. Am. Chem. Soc. 1983, 105, 6320.
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J. Am. Chem. Soc.
, vol.105
, pp. 6320
-
-
Carlin, T.J.1
Sallans, L.2
Cassady, C.J.3
Jacobson, D.B.4
Freiser, B.S.5
-
85
-
-
0021510766
-
-
(b) Cassady, C. J.; Freiser, B. S.; McElvany, S. W.; Allison, J. J. Am. Chem. Soc. 1984, 106, 6125.
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, vol.106
, pp. 6125
-
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Cassady, C.J.1
Freiser, B.S.2
McElvany, S.W.3
Allison, J.4
-
86
-
-
0030152598
-
-
(c) Fiedler, A.; Schröder, D.; Schwarz, H.; Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc., 1996, 118, 5047.
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(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 5047
-
-
Fiedler, A.1
Schröder, D.2
Schwarz, H.3
Tjelta, B.L.4
Armentrout, P.B.5
-
87
-
-
33748863535
-
-
Most likely, the hydrogen atom from the methoxy group is directly transferred to the other hydrogen in 5 without involving a dihydrido-metal intermediate; see: (a) Holthausen, M. C.; Fiedler, A.; Schwarz, H.; Koch, W. Angew. Chem., Int. Ed. Engl. 1995, 34, 2282. (b) Holthausen, M. C.; Fiedler, A.; Schwarz, H.; Koch, W. J. Phys. Chem. 1996, 100, 6236.
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(1995)
Angew. Chem., Int. Ed. Engl.
, vol.34
, pp. 2282
-
-
Holthausen, M.C.1
Fiedler, A.2
Schwarz, H.3
Koch, W.4
-
88
-
-
0030123831
-
-
Most likely, the hydrogen atom from the methoxy group is directly transferred to the other hydrogen in 5 without involving a dihydrido-metal intermediate; see: (a) Holthausen, M. C.; Fiedler, A.; Schwarz, H.; Koch, W. Angew. Chem., Int. Ed. Engl. 1995, 34, 2282. (b) Holthausen, M. C.; Fiedler, A.; Schwarz, H.; Koch, W. J. Phys. Chem. 1996, 100, 6236.
-
(1996)
Phys. Chem.
, vol.100
, pp. 6236
-
-
Holthausen, M.C.1
Fiedler, A.2
Schwarz, H.3
Koch, W.J.4
-
89
-
-
33748235293
-
-
Schröder, D.; Schwarz, H. Angew. Chem., Int. Ed. Engl. 1991, 30, 991.
-
(1991)
Angew. Chem., Int. Ed. Engl.
, vol.30
, pp. 991
-
-
Schröder, D.1
Schwarz, H.2
-
90
-
-
10344242718
-
-
note
-
+ precursor ion.
-
-
-
-
91
-
-
84914751407
-
-
Proton affinities were taken from: Lias, S. G.; Liebman, J. F.; Levin, R. D. J. Phys. Chem. Ref. Data 1984, 13, 695.
-
(1984)
J. Phys. Chem. Ref. Data
, vol.13
, pp. 695
-
-
Lias, S.G.1
Liebman, J.F.2
Levin, R.D.3
-
92
-
-
0242491903
-
-
+ complexes, see: Schröder, D.; Wesendrup, R.; Schalley, C. A.; Zummack, W.; Schwarz, H. Helv. Chim. Acta 1996, 79, 123.
-
(1996)
Helv. Chim. Acta
, vol.79
, pp. 123
-
-
Schröder, D.1
Wesendrup, R.2
Schalley, C.A.3
Zummack, W.4
Schwarz, H.5
-
93
-
-
10344254625
-
-
note
-
+ and have not attempted to further characterize this product.
-
-
-
-
95
-
-
33748232179
-
-
(b) Schröder, D.; Schwarz, H. Angew. Chem., Int. Ed. Engl. 1990, 29, 1431.
-
(1990)
Angew. Chem., Int. Ed. Engl.
, vol.29
, pp. 1431
-
-
Schröder, D.1
Schwarz, H.2
-
96
-
-
0000041330
-
-
For recent discussions of [2 + 2] versus [3 + 2] pathways in the reactions of osmium(VIII) compounds with alkenes, see: (a) Veldkamp, A.; Frenking, G. J. Am. Chem. Soc. 1994, 116, 4937.
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 4937
-
-
Veldkamp, A.1
Frenking, G.2
-
97
-
-
0000770498
-
-
(b) Norrby, P.-O.; Kolb, H. C.; Sharpless, K. B. J. Am. Chem. Soc. 1994, 116, 8470.
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 8470
-
-
Norrby, P.-O.1
Kolb, H.C.2
Sharpless, K.B.3
-
101
-
-
0001590480
-
-
Becker, H.; Schröder, D.; Zummack, W.; Schwarz, H. J. Am. Chem. Soc. 1994, 116, 1096.
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 1096
-
-
Becker, H.1
Schröder, D.2
Zummack, W.3
Schwarz, H.4
-
102
-
-
0001356962
-
-
Schröder, D.; Zummack, W.; Schwarz, H. Organometallics 1993, 12, 1079.
-
(1993)
Organometallics
, vol.12
, pp. 1079
-
-
Schröder, D.1
Zummack, W.2
Schwarz, H.3
-
104
-
-
10344250726
-
-
note
-
+ does not require curve crossing.
-
-
-
-
106
-
-
10344267259
-
-
note
-
min, value is due to a sensitive dependence of the data on ion source conditions rather than too low ion intensities.
-
-
-
-
107
-
-
10344253590
-
-
unpublished results
-
+. However, a more detailed theoretical treatment is indicated: Kretzchmar, I.; Fiedler, A.; Schröder, D.; Schwarz, H., unpublished results.
-
-
-
Kretzchmar, I.1
Fiedler, A.2
Schröder, D.3
Schwarz, H.4
-
108
-
-
0004251925
-
-
Freiser, B. S., Ed.; Kluwer: Dordrecht
-
Armentrout, P. B.; Kickel, B. L., In Organometallic Ion Chemistry; Freiser, B. S., Ed.; Kluwer: Dordrecht, 1996, p 1.
-
(1996)
Organometallic Ion Chemistry
, pp. 1
-
-
Armentrout, P.B.1
Kickel, B.L.2
-
109
-
-
0000689755
-
-
This argument is based on the kinetic method; for a review, see: Cooks, R. G.; Patrick, J. S.; Kotiaho, T.; McLuckey, S. A. Mass Spectrom. Rev. 1995, 13, 287.
-
(1995)
Mass Spectrom. Rev.
, vol.13
, pp. 287
-
-
Cooks, R.G.1
Patrick, J.S.2
Kotiaho, T.3
McLuckey, S.A.4
-
110
-
-
10344220817
-
-
note
-
1) ground state; the latter ion is unreactive toward O2.
-
-
-
-
112
-
-
33748225314
-
-
(a) Schröder, D.; Schwarz, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1420.
-
(1993)
Angew. Chem., Int. Ed. Engl.
, vol.32
, pp. 1420
-
-
Schröder, D.1
Schwarz, H.2
-
113
-
-
10344256448
-
-
Technische Universität Berlin
-
(b) Wesendrup, R.; Diplomarbeit, Technische Universität Berlin, 1994.
-
(1994)
Diplomarbeit
-
-
Wesendrup, R.1
-
114
-
-
0001151868
-
-
(c) Boissel, P.; Marty, P.; Klotz, A.; de Parseval, P.; Chaudret, B.; Serra, G. Int. J. Mass Spectrom. Ion Processes 1995, 242, 157.
-
(1995)
Int. J. Mass Spectrom. Ion Processes
, vol.242
, pp. 157
-
-
Boissel, P.1
Marty, P.2
Klotz, A.3
De Parseval, P.4
Chaudret, B.5
Serra, G.6
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