Gas-phase chemistry of hydrogen peroxide and alkyl hydroperoxides with "bare" first-row transition-metal cations Cr+-Co+. Generation of MO+ cations using H2O2 as oxidant

Organometallics

Volumn 15, Issue 2, 1996, Pages 678-683

  Schalley, Christoph A ^a   Wesendrup, Ralf ^a   Schröder, Detlef ^a   Schwarz, Helmut ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001673661     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950573y     Document Type: Article

References (65)

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7. For recent reviews on the chemistry of transition-metal ions in the gas phase, see: (a) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121. (b) Eller, K. Coord. Chem. Rev. 1993, 126, 93. (c) Freiser, B. S. Acc. Chem. Res. 1994, 27, 353.
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26. 3 transfers in cationic metal alkoxides, see: (a) Cassady, C. J.; Freiser, B. S.; McElvany, S. W.; Allison, J. J. Am. Chem. Soc. 1984, 106, 6125. (b) Schröder, D.; Schwarz, H. Angew. Chem. 1990, 102, 925; Angew. Chem., Int. Ed. Engl. 1990, 29, 910. (c) Fiedler, A.; Schröder, D.; Schwarz, H.; Tjelta, B. L.; Armentrout, P. B., submitted for publication.
27. 3 transfers in cationic metal alkoxides, see: (a) Cassady, C. J.; Freiser, B. S.; McElvany, S. W.; Allison, J. J. Am. Chem. Soc. 1984, 106, 6125. (b) Schröder, D.; Schwarz, H. Angew. Chem. 1990, 102, 925; Angew. Chem., Int. Ed. Engl. 1990, 29, 910. (c) Fiedler, A.; Schröder, D.; Schwarz, H.; Tjelta, B. L.; Armentrout, P. B., submitted for publication.
28. 3 transfers in cationic metal alkoxides, see: (a) Cassady, C. J.; Freiser, B. S.; McElvany, S. W.; Allison, J. J. Am. Chem. Soc. 1984, 106, 6125. (b) Schröder, D.; Schwarz, H. Angew. Chem. 1990, 102, 925; Angew. Chem., Int. Ed. Engl. 1990, 29, 910. (c) Fiedler, A.; Schröder, D.; Schwarz, H.; Tjelta, B. L.; Armentrout, P. B., submitted for publication.
29. 3 transfers in cationic metal alkoxides, see: (a) Cassady, C. J.; Freiser, B. S.; McElvany, S. W.; Allison, J. J. Am. Chem. Soc. 1984, 106, 6125. (b) Schröder, D.; Schwarz, H. Angew. Chem. 1990, 102, 925; Angew. Chem., Int. Ed. Engl. 1990, 29, 910. (c) Fiedler, A.; Schröder, D.; Schwarz, H.; Tjelta, B. L.; Armentrout, P. B., submitted for publication.
30. + exceeds 130 kcal/mol.
31. Thermochemical data were taken from: (a) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1. (b) Lias, S. G.; Liebman, J. F.; Levin, R. D.; Kafafi, S. A. NIST Standard Reference Database, Positive Ion Energetics, Version 2.01; NBS: Gaithersburg, MD, Jan 1994. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629. For recent surveys of accurate thermodynamics of small organometallic ions, see: (d) Armentrout, P. B.; Kickel, B. L. In Organometallic Ion Chemistry; Freiser, B. S., Ed.; Kluwer: Dordrecht, The Netherlands, 1995; p 1. (e) Freiser, B. S. Ibid.
32. Thermochemical data were taken from: (a) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1. (b) Lias, S. G.; Liebman, J. F.; Levin, R. D.; Kafafi, S. A. NIST Standard Reference Database, Positive Ion Energetics, Version 2.01; NBS: Gaithersburg, MD, Jan 1994. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629. For recent surveys of accurate thermodynamics of small organometallic ions, see: (d) Armentrout, P. B.; Kickel, B. L. In Organometallic Ion Chemistry; Freiser, B. S., Ed.; Kluwer: Dordrecht, The Netherlands, 1995; p 1. (e) Freiser, B. S. Ibid.
33. Thermochemical data were taken from: (a) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1. (b) Lias, S. G.; Liebman, J. F.; Levin, R. D.; Kafafi, S. A. NIST Standard Reference Database, Positive Ion Energetics, Version 2.01; NBS: Gaithersburg, MD, Jan 1994. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629. For recent surveys of accurate thermodynamics of small organometallic ions, see: (d) Armentrout, P. B.; Kickel, B. L. In Organometallic Ion Chemistry; Freiser, B. S., Ed.; Kluwer: Dordrecht, The Netherlands, 1995; p 1. (e) Freiser, B. S. Ibid.
34. Thermochemical data were taken from: (a) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1. (b) Lias, S. G.; Liebman, J. F.; Levin, R. D.; Kafafi, S. A. NIST Standard Reference Database, Positive Ion Energetics, Version 2.01; NBS: Gaithersburg, MD, Jan 1994. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629. For recent surveys of accurate thermodynamics of small organometallic ions, see: (d) Armentrout, P. B.; Kickel, B. L. In Organometallic Ion Chemistry; Freiser, B. S., Ed.; Kluwer: Dordrecht, The Netherlands, 1995; p 1. (e) Freiser, B. S. Ibid.
35. Thermochemical data were taken from: (a) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1. (b) Lias, S. G.; Liebman, J. F.; Levin, R. D.; Kafafi, S. A. NIST Standard Reference Database, Positive Ion Energetics, Version 2.01; NBS: Gaithersburg, MD, Jan 1994. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629. For recent surveys of accurate thermodynamics of small organometallic ions, see: (d) Armentrout, P. B.; Kickel, B. L. In Organometallic Ion Chemistry; Freiser, B. S., Ed.; Kluwer: Dordrecht, The Netherlands, 1995; p 1. (e) Freiser, B. S. Ibid.
36. +; see also refs 17 and 19.
37. Schröder, D.; Schwarz, H. J. Organomet. Chem., in press.
38. (a) Allison, J.; Ridge, D. P. J. Am. Chem. Soc. 1976, 98, 7445.
39. (b) Allison, J.; Ridge, D. P. J. Am. Chem. Soc. 1979, 101, 4998.
40. (c) Prüsse, T.; Schwarz, H. Organometallics 1989, 8, 2856.
41. Benson, S. W. Thermochemical Kinetics, 2nd ed.; Wiley: New York, 1976.
42. For an application to an organometallic system, see: Becker, H.; Schröder, D.; Zummack, W.; Schwarz, H. J. Am. Chem. Soc. 1994, 116, 1096.
43. Examples: (a) Reference 17b. (b) Rosi, M.; Bauschlicher, C. W., Jr. J. Chem. Phys. 1990, 92, 1876. (c) Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc. 1995, 117, 5531.
44. Examples: (a) Reference 17b. (b) Rosi, M.; Bauschlicher, C. W., Jr. J. Chem. Phys. 1990, 92, 1876. (c) Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc. 1995, 117, 5531.
45. Examples: (a) Reference 17b. (b) Rosi, M.; Bauschlicher, C. W., Jr. J. Chem. Phys. 1990, 92, 1876. (c) Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc. 1995, 117, 5531.
46. • losses).
47. + in a ca. 5:1 ratio.
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52. + with aliphatic alcohols, see: (a) Schröder, D. Ph.D. Thesis, Technische Universität Berlin D83, 1992. (b) Schröder, D.; Wesendrup, R.; Schalley, C. A.; Zummack, W.; Schwarz, H. Helv. Chim. Acta, submitted for publication.
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