Emulsion copolymerization of acrylonitrile and butadiene. Calculation of the detailed macromolecular structure

International Journal of Polymeric Materials and Polymeric Biomaterials

Volumn 51, Issue 6, 2002, Pages 511-527

  Rodriguez V I ^a   Estenoz, D A ^a   Gugliotta, L M ^a   Meira, G R ^a  

^a UNIVERSIDAD NACIONAL DEL LITORAL   (Argentina)

Author keywords

Branching distribution; CCD; Emulsion polymerization; MWD; NBR

Indexed keywords

EMULSION POLYMERIZATION; MACROMOLECULES; MONOMERS; PARTICLE SIZE ANALYSIS;

BIVARAITE DISTRIBUTIONS; COPOLYMER COMPOSITIONS; MONOMER CONVERSION;

COPOLYMERS;

EID: 0012378679     PISSN: 00914037     EISSN: 1563535X     Source Type: Journal    
DOI: 10.1080/00914030209696297     Document Type: Conference Paper

References (33)

1. Vega, J., Gugliotta, L., Bielsa, R., Brandolini, M. and Meira, G. (1997). Ind. Eng. Chem. Res., 36, 1238.
2. Gugliotta, L., Vega, J., Antonione, C. and Meira, G. (1997). Polym. Reac. Eng., 7, 531.
3. Dubé, M., Penlidis, A., Mutha, R. and Cluett, W. (1996). Ind. Eng. Chem. Res., 35, 4434.
4. Saldfvar, E., Dafniotis, P. and Ray, W. (1998). J. Macromol. Sci. - Rev. Macromol. Chem. Phys., C38, 207.
5. van Doremaele, G., van Herk, A. and German, A. (1992). Polym. Int., 27, 95.
6. van Doremaele, G., Geerts, F., aan de Meulen, L. and German, A. (1992). Polymer, 33, 1512.
7. Tobita, H. and Yamamoto, K. (1994). Macromolecules, 27, 3389.
8. Tobita, H. and Hamielec, A. (1995). J. Polym. Sci. - Polym. Chem. Ed., 33, 441.
9. Charmot, D. and Guillot, G. (1992). Polymer, 33, 352.
10. Teymour, F. and Campbell, J. (1994). Macromolecules, 27, 2460.
11. Arzamendi, G., Forcada, J. and Asua, J. (1994). Macromolecules, 27, 6068.
12. Arzamendi, G. and Asua, J. (1995). Macromolecules, 28, 7479.
13. Arzamendi, G., Sayer, C., Zoco, N. and Asua, J. (1998). Polym. Reac. Eng., 6, 193.
14. Min, K. and Ray, W. (1974). J. Macromol. Sci. - Rev. Macromol. Chem., C11, 177.
15. Forcada, J. and Asua, J. (1990). J. Polym. Sci. - Polym. Chem. Ed., 29, 1231.
16. Saldívar, E. and Ray, W. (1997). Ind. Eng. Chem. Res., 36, 1322.
17. Lichti, G., Gilbert, R. and Napper, D. (1980). J. Polym. Sci. - Polym. Chem. Ed., 18, 1297.
18. Storti, G., Polotti, G., Cociani, M. and Morbidelli, M. (1992). J. Polym. Sci. - Polym. Chem. Ed., 30, 731.
19. Tobita, H., Takada, Y. and Nomura, M. (1994). Macromolecules, 27, 3804.
20. Salazar, A., Gugliotta, L., Vega, J. and Meira, G. (1998). Ind. Eng. Chem. Res., 37, 3582.
21. Echevarría, A., Leiza, J., de la Cal, J. and Asua, J. (1998). AICHE J, 44, 1667.
22. Ullmann's Encyclopedia of Industrial Chemistry, Vol. A23, VCH Publishers, Inc., 1993.
23. Ambler, M. (1976). J. Appl. Polym. Sci., 20, 2259.
24. Estenoz, D., Valdez, E., Oliva, H. and Meira, G. (1996). J. Appl. Polym. Sci., 59, 861.
25. Estenoz, D. A., Vega, J. R., Oliva, H. M. and Meira, G. R., Analysis of a Styrene-Butadiene Graft Copolymer by Size Exclusion Chromatography. I. Computer Simulation Study for Estimating the Biases Induced by Branching Under Ideal Fractionation and Detection, Int. J of Pol. Charact. (in the press).
26. Kolthoff, I., Sandell, E., Meehan, E. and Bruckenstein, S. (1969). Quantitative Chemical Analysis, 4th edn., Macmillan, New York.
27. Vega, J., Gugliotta, L., Castañeda, J. and Meira, G. (1998). Proceedings of the IV Latin American Symposium of Polymer Science, Vina del Mar, Chile, p. 133.
28. Vega, J. R., Estenoz, D. A., Oliva, H. M. and Meira, G. R., Analysis of a Styrene-Butadiene Graft Copolymer by Size Exclusion Chromatography. II. Determination of the Branching Exponent with the Help of a Polymerization Model, Int. J of Pol. Charact. (in the press).
29. Zimm, B. and Stockmayer, W. (1949). J. Chem. Phys., 17, 1301.
30. Graessley, W. and Mittelhauser, H. (1967). J. Polym. Sci. A-2, 5, 431.
31. Small, P. (1975). Adv. Polym. Sci., 18, 1.
32. Brandrup, J. and Immergut, E. (1989). Polymer Handbook, 3rd edn., J. Wiley & Sons, New York.
33. Broadhead, T. (1984). Dynamic Modeling of the Emulsion Copolymerization of Styrene/Butadiene. M. Eng. Thesis, McMaster "University, Hamilton, Ontario, Canada, 1984.