메뉴 건너뛰기




Volumn 36, Issue 4, 1997, Pages 1322-1336

Mathematical Modeling of Emulsion Copolymerization Reactors: Experimental Validation and Application to Complex Systems

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTORS; COMPUTER SIMULATION; EMULSION POLYMERIZATION; MATHEMATICAL MODELS; OPTIMIZATION; POLYMETHYL METHACRYLATES; STYRENE;

EID: 0031118176     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960464z     Document Type: Article
Times cited : (37)

References (41)
  • 3
    • 0016509377 scopus 로고
    • Orthogonal Collocation on Finite Elements
    • Carey, G. F.; Finlayson, B. A. Orthogonal Collocation on Finite Elements. Chem. Eng. Sci. 1975, 30, 587-596.
    • (1975) Chem. Eng. Sci. , vol.30 , pp. 587-596
    • Carey, G.F.1    Finlayson, B.A.2
  • 4
    • 0022752963 scopus 로고
    • The SCOPE Dynamic Model for Emulsion Polymerization I. Theory
    • Dougherty, E. The SCOPE Dynamic Model for Emulsion Polymerization I. Theory. J. Appl. Polym. Sci. 1986a, 32, 3051-3078.
    • (1986) J. Appl. Polym. Sci. , vol.32 , pp. 3051-3078
    • Dougherty, E.1
  • 5
    • 0022752432 scopus 로고
    • The SCOPE Dynamic Model for Emulsion Polymerization II. Comparison with Experiment and Applications
    • Dougherty, E. The SCOPE Dynamic Model for Emulsion Polymerization II. Comparison with Experiment and Applications. J. Appl. Polym. Sci. 1986b, 32, 3079-3095.
    • (1986) J. Appl. Polym. Sci. , vol.32 , pp. 3079-3095
    • Dougherty, E.1
  • 7
    • 0025411722 scopus 로고
    • Modelling of Unseeded Emulsion Copolymerization of Styrene and Methyl Methacrylate
    • Forcada, J.; Asúa, J. M. Modelling of Unseeded Emulsion Copolymerization of Styrene and Methyl Methacrylate. J. Polym. Sci., Part A: Polym. Chem. Ed. 1990, 28, 987-1009.
    • (1990) J. Polym. Sci., Part A: Polym. Chem. Ed. , vol.28 , pp. 987-1009
    • Forcada, J.1    Asúa, J.M.2
  • 8
    • 0026205528 scopus 로고
    • Emulsion Copolymerization of Styrene and Methyl Methacrylate. II. Molecular Weights
    • Forcada, J.; Asúa, J. M. Emulsion Copolymerization of Styrene and Methyl Methacrylate. II. Molecular Weights. J. Polym. Sci., Part A: Polym. Chem. Ed. 1991, 29, 1231-1242.
    • (1991) J. Polym. Sci., Part A: Polym. Chem. Ed. , vol.29 , pp. 1231-1242
    • Forcada, J.1    Asúa, J.M.2
  • 9
    • 0002740002 scopus 로고
    • Gel Effect in Emulsion Polymerization of Vinyl Monomers
    • Piirma, I., Gardon, J. L., Eds.; ACS Symposium Series 24; American Chemical Society: Washington, DC; Chapter 5
    • Friis, N.; Hamielec, A. E. Gel Effect in Emulsion Polymerization of Vinyl Monomers. In Emulsion Polymerization; Piirma, I., Gardon, J. L., Eds.; ACS Symposium Series 24; American Chemical Society: Washington, DC, 1976; Chapter 5, pp 82-91.
    • (1976) Emulsion Polymerization , pp. 82-91
    • Friis, N.1    Hamielec, A.E.2
  • 11
    • 0344169465 scopus 로고
    • Detection and Measurement of Branching in Polymers
    • National Academy of Sciences; Washington, DC
    • Graessley, W. W. Detection and Measurement of Branching in Polymers. In Characterization of Molecular Structure; National Academy of Sciences; Washington, DC, 1968.
    • (1968) Characterization of Molecular Structure
    • Graessley, W.W.1
  • 12
    • 0006105360 scopus 로고
    • A Thermodynamic Approach to Emulsion Copolymerization
    • Guillot, J. A Thermodynamic Approach to Emulsion Copolymerization. Makromol. Chem., Rapid Commun, 1980, 1, 697-702.
    • (1980) Makromol. Chem., Rapid Commun , vol.1 , pp. 697-702
    • Guillot, J.1
  • 13
    • 0027676047 scopus 로고
    • Modelling/Simulation of Elaboration and Properties of Emulsion Copolymers
    • Guillot, J. Modelling/Simulation of Elaboration and Properties of Emulsion Copolymers. Comput. Chem. Eng. 1993, 17 (S), S189-S194.
    • (1993) Comput. Chem. Eng. , vol.17 , Issue.S
    • Guillot, J.1
  • 14
    • 84994939231 scopus 로고
    • Multicomponent Free Radical Polymerization in Batch, Semibatch and Continuous Reactors
    • Hamielec, A. E.; MacGregor, J. F.; Penlidis, A. Multicomponent Free Radical Polymerization in Batch, Semibatch and Continuous Reactors. Makromol. Chem., Macromol. Symp. 1987, 10/11, 521-570.
    • (1987) Makromol. Chem., Macromol. Symp. , vol.10-11 , pp. 521-570
    • Hamielec, A.E.1    MacGregor, J.F.2    Penlidis, A.3
  • 15
    • 0027659488 scopus 로고
    • Modeling and Experimental Studies of Aqueous Suspension Polymerization Processes. 1. Modeling and Simulations
    • Kalfas, G.; Ray, W. H. Modeling and Experimental Studies of Aqueous Suspension Polymerization Processes. 1. Modeling and Simulations. Ind. Eng. Chem. Res. 1993, 32, 1822-1830.
    • (1993) Ind. Eng. Chem. Res. , vol.32 , pp. 1822-1830
    • Kalfas, G.1    Ray, W.H.2
  • 16
    • 0002939713 scopus 로고
    • Theoretical Prediction of the Particle Size and Molecular Weight Distribution in Emulsion Polymerizations
    • Piirma, I., Ed.; Academic Press: New York
    • Lichti, G.; Gilbert, R. G.; Napper, D. H. Theoretical Prediction of the Particle Size and Molecular Weight Distribution in Emulsion Polymerizations. In Emulsion Polymerization; Piirma, I., Ed.; Academic Press: New York, 1982; pp 93-144.
    • (1982) Emulsion Polymerization , pp. 93-144
    • Lichti, G.1    Gilbert, R.G.2    Napper, D.H.3
  • 17
    • 0009090473 scopus 로고
    • The Mechanisms of Latex Particle Formation and Growth in the Emulsion Polymerization of Styrene Using the Surfactant Sodium Dodecyl Sulfate
    • Lichti, G.; Gilbert, R. G.; Napper, D. H. The Mechanisms of Latex Particle Formation and Growth in the Emulsion Polymerization of Styrene Using the Surfactant Sodium Dodecyl Sulfate. J. Polym. Sci., Polym. Chem. Ed. 1983, 21, 269-291.
    • (1983) J. Polym. Sci., Polym. Chem. Ed. , vol.21 , pp. 269-291
    • Lichti, G.1    Gilbert, R.G.2    Napper, D.H.3
  • 18
    • 0027910846 scopus 로고
    • Propagation and Termination Processes in the Free-Radical Copolymerization of Methyl Methacrylate and Vinyl Acetate
    • Ma, Y.; Won, Y.; Kubo, K.; Fukuda, T. Propagation and Termination Processes in the Free-Radical Copolymerization of Methyl Methacrylate and Vinyl Acetate. Macromolecules 1993, 26, 6766-6770.
    • (1993) Macromolecules , vol.26 , pp. 6766-6770
    • Ma, Y.1    Won, Y.2    Kubo, K.3    Fukuda, T.4
  • 19
    • 0026137945 scopus 로고
    • Entry of Free Radicals into Latex Particles in Emulsion Polymerization
    • Maxwell, I. A.; Morrison, B. R.; Napper, D. H.; Gilbert, R. G. Entry of Free Radicals into Latex Particles in Emulsion Polymerization. Macromolecules 1991, 24, 1629-1640.
    • (1991) Macromolecules , vol.24 , pp. 1629-1640
    • Maxwell, I.A.1    Morrison, B.R.2    Napper, D.H.3    Gilbert, R.G.4
  • 21
    • 0020721068 scopus 로고
    • Role of Micellar Equilibria on Modelling of Batch Emulsion Polymerization Reactors
    • Morbidelli, M.; Storti, G.; Carrá, S. Role of Micellar Equilibria on Modelling of Batch Emulsion Polymerization Reactors. J. Appl. Polym. Sci. 1983, 28, 901-919.
    • (1983) J. Appl. Polym. Sci. , vol.28 , pp. 901-919
    • Morbidelli, M.1    Storti, G.2    Carrá, S.3
  • 22
    • 84944636531 scopus 로고
    • Kinetics of Emulsion Polymerization
    • O'Toole, J. T. Kinetics of Emulsion Polymerization. J. Appl. Polym. Sci. 1965, 9, 1291-1297.
    • (1965) J. Appl. Polym. Sci. , vol.9 , pp. 1291-1297
    • O'Toole, J.T.1
  • 24
    • 0027928422 scopus 로고
    • Tubular Reactors for Emulsion Polymerization I. Experimental Investigation
    • Paquet, D. A.; Ray, W. H. Tubular Reactors for Emulsion Polymerization I. Experimental Investigation. AIChE J. 1994, 40 (1), 73-87.
    • (1994) AIChE J. , vol.40 , Issue.1 , pp. 73-87
    • Paquet, D.A.1    Ray, W.H.2
  • 25
    • 0003452274 scopus 로고
    • DASSL: A Differential-Algebraic System Solver
    • Sandia National Laboratories
    • Petzold, L. R. DASSL: A Differential-Algebraic System Solver. Internal Report, Sandia National Laboratories, 1985.
    • (1985) Internal Report
    • Petzold, L.R.1
  • 26
    • 0020176542 scopus 로고
    • A Constrained Regularization Method for Inverting Data Represented by Linear Algebraic or Integral Equations
    • Provencher, S. W. A Constrained Regularization Method for Inverting Data Represented by Linear Algebraic or Integral Equations. Comput. Phys. Commun. 1982a, 27, 213-227.
    • (1982) Comput. Phys. Commun. , vol.27 , pp. 213-227
    • Provencher, S.W.1
  • 27
    • 0020176708 scopus 로고
    • CONTIN: A General Purpose Constrained Regularization Program for Inverting Noisy Linear Algebraic and Integral Equations
    • Provencher, S. W. CONTIN: A General Purpose Constrained Regularization Program for Inverting Noisy Linear Algebraic and Integral Equations. Comput. Phys. Commun. 1982, 27, 229-242.
    • (1982) Comput. Phys. Commun. , vol.27 , pp. 229-242
    • Provencher, S.W.1
  • 29
    • 0023984644 scopus 로고
    • The Modelling of Batch and Continuous Emulsion Polymerization Reactors. Part I: Model Formulation and Sensitivity to Parameters
    • Rawlings, J. B.; Ray, W. H. The Modelling of Batch and Continuous Emulsion Polymerization Reactors. Part I: Model Formulation and Sensitivity to Parameters. Polym. Eng. Sci. 1988, 28 (5), 237-256.
    • (1988) Polym. Eng. Sci. , vol.28 , Issue.5 , pp. 237-256
    • Rawlings, J.B.1    Ray, W.H.2
  • 30
    • 0141839473 scopus 로고    scopus 로고
    • Polymer Reaction Engineering Laboratory, University of Wisconsin
    • Ray, W. H. POLYRED. User's Manual Version 4.0, Polymer Reaction Engineering Laboratory, University of Wisconsin, 1996.
    • (1996) POLYRED. User's Manual Version 4.0
    • Ray, W.H.1
  • 31
    • 0024961876 scopus 로고
    • Mathematical Modeling of Emulsion Copolymerization Reactors
    • Richards, J. R.; Congalidis, J. P.; Gilbert, R. G. Mathematical Modeling of Emulsion Copolymerization Reactors. J. Appl. Polym. Sci. 1989, 37, 2727-2756.
    • (1989) J. Appl. Polym. Sci. , vol.37 , pp. 2727-2756
    • Richards, J.R.1    Congalidis, J.P.2    Gilbert, R.G.3
  • 33
    • 0031207439 scopus 로고    scopus 로고
    • Control of Semicontinuous Emulsion Copolymerization Reactors
    • in press
    • Saldívar, E.; Ray, W. H. Control of Semicontinuous Emulsion Copolymerization Reactors. AIChE J. 1997, in press.
    • (1997) AIChE J.
    • Saldívar, E.1    Ray, W.H.2
  • 34
    • 25944433155 scopus 로고    scopus 로고
    • Detailed Modeling of Emulsion Copolymerization Reactors I. Application to Reactors Operating above the CMC of the Emulsifier
    • in press
    • Saldívar, E.; Dafniotis, P.; Ray, W. H. Detailed Modeling of Emulsion Copolymerization Reactors I. Application to Reactors Operating Above the CMC of the Emulsifier. Macromol. Sci., Rev. Macromol. Chem. 1997, in press.
    • (1997) Macromol. Sci., Rev. Macromol. Chem.
    • Saldívar, E.1    Dafniotis, P.2    Ray, W.H.3
  • 35
    • 0019702653 scopus 로고
    • The Dynamic Behavior of Continuous Polymerization Reactors I. Isothermal Solution Polymerization in a CSTR
    • Schmidt, A. D.; Ray, W. H. The Dynamic Behavior of Continuous Polymerization Reactors I. Isothermal Solution Polymerization in a CSTR. Chem. Eng. Sci. 1981, 36, 1401-1410.
    • (1981) Chem. Eng. Sci. , vol.36 , pp. 1401-1410
    • Schmidt, A.D.1    Ray, W.H.2
  • 36
    • 0027539684 scopus 로고
    • Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Experimental Design and Preliminary Screening Experiments
    • Scott, P. J.; Penlidis, A.; Rempel, G. L. Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Experimental Design and Preliminary Screening Experiments. J. Polym. Sci., Part A: Polym. Chem. 1993a, 31, 403-426.
    • (1993) J. Polym. Sci., Part A: Polym. Chem. , vol.31 , pp. 403-426
    • Scott, P.J.1    Penlidis, A.2    Rempel, G.L.3
  • 37
    • 0027641010 scopus 로고
    • Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Use of Factorial Experiments for Improved Process Understanding
    • Scott, P. J.; Penlidis, A.; Rempel, G. L. Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Use of Factorial Experiments for Improved Process Understanding. J. Polym. Sci., Part A: Polym. Chem. 1993b, 31, 2205-2230.
    • (1993) J. Polym. Sci., Part A: Polym. Chem. , vol.31 , pp. 2205-2230
    • Scott, P.J.1    Penlidis, A.2    Rempel, G.L.3
  • 38
    • 1542717414 scopus 로고
    • Ethylene-Vinyl Acetate Emulsion Copolymerization: Monomer Partitioning and Preliminary Modelling
    • Scott, P. J.; Penlidis, A.; Rempel, G. L. Ethylene-Vinyl Acetate Emulsion Copolymerization: Monomer Partitioning and Preliminary Modelling. Polym. React. Eng. 1994a, 31, 2205-2230.
    • (1994) Polym. React. Eng. , vol.31 , pp. 2205-2230
    • Scott, P.J.1    Penlidis, A.2    Rempel, G.L.3
  • 39
    • 0028378404 scopus 로고
    • Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Use of Factorial Experiments for Process Optimization
    • Scott, P. J.; Penlidis, A.; Rempel, G. L.; Lawrence, A. D. Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Use of Factorial Experiments for Process Optimization. J. Polym. Sci., Part A: Polym. Chem., 1994b, 32, 539-555.
    • (1994) J. Polym. Sci., Part A: Polym. Chem. , vol.32 , pp. 539-555
    • Scott, P.J.1    Penlidis, A.2    Rempel, G.L.3    Lawrence, A.D.4
  • 40
    • 0024961870 scopus 로고
    • Kinetics of Multimonomer Emulsion Polymerization. the Pseudo-Homopolymerization Approach
    • Storti, G.; Carrà, S.; Morbidelli, M.; Vita, G. Kinetics of Multimonomer Emulsion Polymerization. The Pseudo-Homopolymerization Approach. J. Polym. Sci., Polym. Chem. Ed. 1989, 37, 2443-2467.
    • (1989) J. Polym. Sci., Polym. Chem. Ed. , vol.37 , pp. 2443-2467
    • Storti, G.1    Carrà, S.2    Morbidelli, M.3    Vita, G.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.