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Volumn 35, Issue 12, 1996, Pages 4434-4448

Mathematical Modeling of Emulsion Copolymerization of Acrylonitrile/Butadiene

Author keywords

[No Author keywords available]

Indexed keywords

BUTADIENE; COMPOSITION; COPOLYMERIZATION; EMULSION POLYMERIZATION; MATHEMATICAL MODELS; MOLECULAR WEIGHT; PARTICLE SIZE ANALYSIS; POLYBUTADIENES; REACTION KINETICS;

EID: 0030397367     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie9502704     Document Type: Article
Times cited : (32)

References (93)
  • 2
    • 0008790699 scopus 로고
    • Redox kinetics of the peroxydisulfate-iron-sulfoxylate system
    • Andersen, H. M.; Proctor, S. I. Redox kinetics of the peroxydisulfate-iron-sulfoxylate system. J. Polym. Sci., Part A 1965, 3, 2343.
    • (1965) J. Polym. Sci., Part A , vol.3 , pp. 2343
    • Andersen, H.M.1    Proctor, S.I.2
  • 4
    • 0001136293 scopus 로고
    • Improved methods for solving the Smith-Ewart equations in the steady state
    • Ballard, M. J.; Gilbert, R. G.; Napper, D. H. Improved methods for solving the Smith-Ewart equations in the steady state. J. Polym. Sci., Polym. Lett. Ed. 1981, 19, 533.
    • (1981) J. Polym. Sci., Polym. Lett. Ed. , vol.19 , pp. 533
    • Ballard, M.J.1    Gilbert, R.G.2    Napper, D.H.3
  • 9
    • 0000062016 scopus 로고
    • Dynamic modelling of the batch semibatch and continuous production of styrene/butadiene copolymers by emulsion polymerization
    • Broadhead, T. O.; Hamielec, A. E.; MacGregor, J. R. Dynamic modelling of the batch semibatch and continuous production of styrene/butadiene copolymers by emulsion polymerization. Makromol. Chem., Suppl. 1985, 10/11, 105.
    • (1985) Makromol. Chem., Suppl. , vol.10-11 , pp. 105
    • Broadhead, T.O.1    Hamielec, A.E.2    MacGregor, J.R.3
  • 10
    • 0014924177 scopus 로고
    • Copolymerization of styrene and butadiene in emulsion. II. Relative rates of crosslinking and propagation
    • Burnett, G. M.; Cameron, G. G.; Thorat, P. L. Copolymerization of styrene and butadiene in emulsion. II. Relative rates of crosslinking and propagation. J. Polym. Sci., Polym. Chem. Ed. 1970, 8, 3443.
    • (1970) J. Polym. Sci., Polym. Chem. Ed. , vol.8 , pp. 3443
    • Burnett, G.M.1    Cameron, G.G.2    Thorat, P.L.3
  • 12
    • 0028452824 scopus 로고
    • Effect of impurities on continuous solution methyl methacrylate polymerization reactors. II. Closed-loop process real-time control
    • Chien, D. C. H.; Penlidis, A. Effect of impurities on continuous solution methyl methacrylate polymerization reactors. II. Closed-loop process real-time control. Chem. Eng. Sci. 1994, 49, 1855.
    • (1994) Chem. Eng. Sci. , vol.49 , pp. 1855
    • Chien, D.C.H.1    Penlidis, A.2
  • 13
    • 0022752963 scopus 로고
    • The SCOPE dynamic model for emulsion polymerization I. Theory
    • Dougherty, E. P. The SCOPE dynamic model for emulsion polymerization I. Theory. J. Appl. Polym. Sci. 1986, 32, 3051.
    • (1986) J. Appl. Polym. Sci. , vol.32 , pp. 3051
    • Dougherty, E.P.1
  • 15
    • 0029252701 scopus 로고
    • A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/ methyl methacrylate/vinyl acetate example I. Bulk copolymerization
    • Dubé, M. A.; Penlidis, A. A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/ methyl methacrylate/vinyl acetate example I. Bulk copolymerization. Polymer 1995a, 36, 587.
    • (1995) Polymer , vol.36 , pp. 587
    • Dubé, M.A.1    Penlidis, A.2
  • 16
    • 0001618271 scopus 로고
    • A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/ methyl methacrylate/vinyl acetate example 2. Bulk (and solution) terpolymerization
    • Dubé, M. A.; Penlidis, A. A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/ methyl methacrylate/vinyl acetate example 2. Bulk (and solution) terpolymerization. Macromol. Chem. Phys. 1995b, 196, 1101.
    • (1995) Macromol. Chem. Phys. , vol.196 , pp. 1101
    • Dubé, M.A.1    Penlidis, A.2
  • 17
    • 0029357992 scopus 로고
    • A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/ methyl methacrylate/vinyl acetate example 3. Emulsion homoand Copolymerization in a pilot plant reactor
    • Dubé, M. A.; Penlidis, A. A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/ methyl methacrylate/vinyl acetate example 3. Emulsion homoand Copolymerization in a pilot plant reactor. Polym. Int. 1995c, 37, 235.
    • (1995) Polym. Int. , vol.37 , pp. 235
    • Dubé, M.A.1    Penlidis, A.2
  • 18
    • 0030126086 scopus 로고    scopus 로고
    • A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/methyl methacrylate/vinyl acetate example IV. Optimal Bayesian design of emulsion terpolymerization experiments in a pilot plant reactor
    • Dubé, M. A.; Penlidis, A.; Reilly, P. M. A systematic approach to the study of multicomponent polymerization kinetics: The butyl acrylate/methyl methacrylate/vinyl acetate example IV. Optimal Bayesian design of emulsion terpolymerization experiments in a pilot plant reactor. J. Polym. Sci., Polym. Chem. Ed. 1996, 34, 811.
    • (1996) J. Polym. Sci., Polym. Chem. Ed. , vol.34 , pp. 811
    • Dubé, M.A.1    Penlidis, A.2    Reilly, P.M.3
  • 19
    • 2742565313 scopus 로고
    • Compositional heterogeneity of butadiene-aerylonitrile copolymers prepared in emulsion at 5 °C
    • Embree, W. H.; Mitchell, J. M.; Williams, H. L. Compositional heterogeneity of butadiene-aerylonitrile copolymers prepared in emulsion at 5 °C. Can. J. Chem. 1951, 29, 253.
    • (1951) Can. J. Chem. , vol.29 , pp. 253
    • Embree, W.H.1    Mitchell, J.M.2    Williams, H.L.3
  • 20
    • 0014867554 scopus 로고
    • Polymer colloids: Particle formation in nonmicellar systems
    • Fitch, R. M.; Tsai, C. H. Polymer colloids: particle formation in nonmicellar systems. Polym. Lett. 1970, 8, 703.
    • (1970) Polym. Lett. , vol.8 , pp. 703
    • Fitch, R.M.1    Tsai, C.H.2
  • 21
    • 0004291576 scopus 로고
    • Particle formation in polymer colloids. Ill: Prediction of the number of particles by a homogeneous nucleation theory
    • Fitch, R. M., Ed.; Plenum Press: New York
    • Fitch, R. M.; Tsai, C. H. Particle formation in polymer colloids. Ill: Prediction of the number of particles by a homogeneous nucleation theory. In Polymer Colloids; Fitch, R. M., Ed.; Plenum Press: New York, 1971; pp 73-101.
    • (1971) Polymer Colloids , pp. 73-101
    • Fitch, R.M.1    Tsai, C.H.2
  • 22
    • 84948880219 scopus 로고
    • Simulation of mini/macro emulsion polymerizations. I. Development of the model
    • Fontenot, K.; Schork, F. J. Simulation of mini/macro emulsion polymerizations. I. Development of the model. Polym. React. Eng. 1992 93a 1, 75.
    • (1992) Polym. React. Eng. , vol.1 , pp. 75
    • Fontenot, K.1    Schork, F.J.2
  • 23
    • 84948261967 scopus 로고
    • Simulation of mini/macro emulsion polymerizations. II. Sensitivities and experimental comparison
    • Fontenot, K.; Schork, F. J. Simulation of mini/macro emulsion polymerizations. II. Sensitivities and experimental comparison. Polym. React. Eng. 1992-93b, 1, 289.
    • (1992) Polym. React. Eng. , vol.1 , pp. 289
    • Fontenot, K.1    Schork, F.J.2
  • 24
    • 0022902451 scopus 로고
    • Initiation reactions and the modeling of polymerization kinetics
    • Provder, T., Ed.; ACS Symposium Series 313; American Chemical Society: Washington, DC
    • Garcia-Rubio, L. H.; Mehta, J. Initiation reactions and the modeling of polymerization kinetics. In Computer Applications in the Polymer Laboratory; Provder, T., Ed.; ACS Symposium Series 313; American Chemical Society: Washington, DC, 1986; pp 202-218.
    • (1986) Computer Applications in the Polymer Laboratory , pp. 202-218
    • Garcia-Rubio, L.H.1    Mehta, J.2
  • 25
    • 0022225846 scopus 로고
    • Bulk copolymerization of styrene and acrylonitrile: Experimental kinetics and mathematical modelling
    • Garcia-Rubio, L. H.; Lord, M. G.; MacGregor, J. F.; Hamielec, A. E. Bulk copolymerization of styrene and acrylonitrile: Experimental kinetics and mathematical modelling. Polymer 1985, 26, 2001.
    • (1985) Polymer , vol.26 , pp. 2001
    • Garcia-Rubio, L.H.1    Lord, M.G.2    MacGregor, J.F.3    Hamielec, A.E.4
  • 26
    • 0008763475 scopus 로고
    • Some thermodynamic aspects in emulsion copolymerization
    • Guillot, J. Some thermodynamic aspects in emulsion copolymerization. Makromol. Chem. Suppl. 1985, 10/11, 235.
    • (1985) Makromol. Chem. Suppl. , vol.10-11 , pp. 235
    • Guillot, J.1
  • 27
    • 0021447003 scopus 로고
    • Controlled composition in emulsion copolymerization application to butadiene-acrylonitrile copolymers
    • Guyot, A.; Guillot, J.; Graillat, C.; Llauro, M. F. Controlled composition in emulsion copolymerization application to butadiene-acrylonitrile copolymers. J. Macromol. Sci., Chem. 1984, A21, 683.
    • (1984) J. Macromol. Sci., Chem. , vol.A21 , pp. 683
    • Guyot, A.1    Guillot, J.2    Graillat, C.3    Llauro, M.F.4
  • 28
    • 84994939231 scopus 로고
    • Multicomponent free-radical polymerization in batch, semi-batch and continuous reactors
    • Hamielec, A. E.; MacGregor, J. F.; Penlidis, A. Multicomponent free-radical polymerization in batch, semi-batch and continuous reactors. Makromol. Chem., Macromol. Symp. 1987, 10/11, 521.
    • (1987) Makromol. Chem., Macromol. Symp. , vol.10-11 , pp. 521
    • Hamielec, A.E.1    MacGregor, J.F.2    Penlidis, A.3
  • 29
    • 0018006080 scopus 로고
    • Particle nucleation in emulsion polymerization. I. A theory for homogeneous nucleation
    • Hansen, F. K.; Ugelstad, J. Particle nucleation in emulsion polymerization. I. A theory for homogeneous nucleation. J. Polym. Sci., Polym. Chem. Ed. 1978, 16, 1953.
    • (1978) J. Polym. Sci., Polym. Chem. Ed. , vol.16 , pp. 1953
    • Hansen, F.K.1    Ugelstad, J.2
  • 30
    • 0011752086 scopus 로고
    • Particle nucleation in emulsion polymerization. IV. Nucleation in monomer droplets
    • Hansen, F. K.; Ugelstad, J. Particle nucleation in emulsion polymerization. IV. Nucleation in monomer droplets. J. Polym. Sci., Polym. Chem. Ed. 1979, 17, 3069.
    • (1979) J. Polym. Sci., Polym. Chem. Ed. , vol.17 , pp. 3069
    • Hansen, F.K.1    Ugelstad, J.2
  • 31
    • 0002943248 scopus 로고
    • Particle formation mechanisms
    • Piirma, I., Ed.; Academic Press: New York
    • Hansen, F. K.; Ugelstad, J. Particle formation mechanisms. In Emulsion Polymerization; Piirma, I., Ed.; Academic Press: New York, 1982; pp 51-92.
    • (1982) Emulsion Polymerization , pp. 51-92
    • Hansen, F.K.1    Ugelstad, J.2
  • 32
    • 85081185499 scopus 로고
    • The modeling of emulsion copolymerization reactors
    • Hamielec, A. E., Ed.; McMaster University: Hamilton, Ontario, Canada
    • Hoffman, T. W. The modeling of emulsion copolymerization reactors. In Short Intensive Industrial Course Notes; Hamielec, A. E., Ed.; McMaster University: Hamilton, Ontario, Canada, 1981.
    • (1981) Short Intensive Industrial Course Notes
    • Hoffman, T.W.1
  • 35
    • 33947454767 scopus 로고
    • The chemistry of persulfate. I. The kinetics and mechanism of the decomposition of the persulfate ion in aqueous medium
    • Kolthoff, I. M.; Miller, I. K The chemistry of persulfate. I. The kinetics and mechanism of the decomposition of the persulfate ion in aqueous medium. J. Am. Chem. Soc. 1951, 73, 3055.
    • (1951) J. Am. Chem. Soc. , vol.73 , pp. 3055
    • Kolthoff, I.M.1    Miller, I.K.2
  • 36
    • 0028532980 scopus 로고
    • Radical entry into particles during emulsion polymerization of vinyl acetate
    • Kahirsagar, R. S.; Poehlein, G. W. Radical entry into particles during emulsion polymerization of vinyl acetate. J. Appl. Polym. Sci. 1994, 54, 909.
    • (1994) J. Appl. Polym. Sci. , vol.54 , pp. 909
    • Kahirsagar, R.S.1    Poehlein, G.W.2
  • 37
    • 0001376889 scopus 로고
    • Nucleation of particles in seeded emulsion polymerization of vinyl acetate with poly(vinyl alcohol) as emulsifier
    • Lepizzera, S. M.; Hamielec, A. E. Nucleation of particles in seeded emulsion polymerization of vinyl acetate with poly(vinyl alcohol) as emulsifier. Macromol. Chem. Phys. 1994, 195, 3103.
    • (1994) Macromol. Chem. Phys. , vol.195 , pp. 3103
    • Lepizzera, S.M.1    Hamielec, A.E.2
  • 38
    • 0027640847 scopus 로고
    • Prediction of the average number of radicals per particle for emulsion polymerization
    • Li, B.; Brooks, B. W. Prediction of the average number of radicals per particle for emulsion polymerization. J. Polym. Sci., Part A: Polym. Chem. 1993, 31, 2397.
    • (1993) J. Polym. Sci., Part A: Polym. Chem. , vol.31 , pp. 2397
    • Li, B.1    Brooks, B.W.2
  • 39
    • 0019551295 scopus 로고
    • Simulation model for the emulsion copolymerization of acrylonitrile and styrene in azeotropic composition
    • Lin, C.-C.; Ku, H.-C.; Chiu, W.-Y. Simulation model for the emulsion copolymerization of acrylonitrile and styrene in azeotropic composition. J. Appl. Polym. Sci. 1981, 26, 1327.
    • (1981) J. Appl. Polym. Sci. , vol.26 , pp. 1327
    • Lin, C.-C.1    Ku, H.-C.2    Chiu, W.-Y.3
  • 40
    • 0001535812 scopus 로고
    • Determination of surface area and particle size of synthetic latex by adsorption II. Latices containing rosin acid soaps
    • Maron, S. H.; Elder, M. E.; Moore, C. Determination of surface area and particle size of synthetic latex by adsorption II. Latices containing rosin acid soaps. J. Colloid Sci. 1954, 9, 104.
    • (1954) J. Colloid Sci. , vol.9 , pp. 104
    • Maron, S.H.1    Elder, M.E.2    Moore, C.3
  • 41
    • 0026137945 scopus 로고
    • Entry of free radicals into latex particles in emulsion polymerization
    • Maxwell, I. A.; Morrison, B. R.; Napper, D. H.; Gilbert, R. G. Entry of free radicals into latex particles in emulsion polymerization. Macromolecules 1991, 24, 1629.
    • (1991) Macromolecules , vol.24 , pp. 1629
    • Maxwell, I.A.1    Morrison, B.R.2    Napper, D.H.3    Gilbert, R.G.4
  • 42
    • 0001063526 scopus 로고
    • The effect of chain transfer agent on the entry of free radicals in emulsion polymerization
    • Maxwell, I. A.; Morrisson, B. R.; Napper, D. H.; Gilbert, R. G. The effect of chain transfer agent on the entry of free radicals in emulsion polymerization. Makromol. Chem. 1992, 193, 303.
    • (1992) Makromol. Chem. , vol.193 , pp. 303
    • Maxwell, I.A.1    Morrisson, B.R.2    Napper, D.H.3    Gilbert, R.G.4
  • 43
    • 0024143449 scopus 로고
    • Emulsion copolymerization of styrene - Methyl acrylate and styrene-acrylonitrile in continuous stirred tank reactors. 1
    • Mead, R. N.; Poehlein, G. W. Emulsion copolymerization of styrene - methyl acrylate and styrene-acrylonitrile in continuous stirred tank reactors. 1. Ind. Eng. Chem. Res. 1988, 27, 2283.
    • (1988) Ind. Eng. Chem. Res. , vol.27 , pp. 2283
    • Mead, R.N.1    Poehlein, G.W.2
  • 44
    • 0024302325 scopus 로고
    • Emulsion copolymerization of styrene - Methyl acrylate and styrene-acrylonitrile in continuous stirred tank reactors. 2. Aqueous-phase polymerization and radical capture
    • Mead, R. N.; Poehlein, G. W. Emulsion copolymerization of styrene - methyl acrylate and styrene-acrylonitrile in continuous stirred tank reactors. 2. Aqueous-phase polymerization and radical capture. Ind. Eng. Chem. Res. 1989a, 28, 51.
    • (1989) Ind. Eng. Chem. Res. , vol.28 , pp. 51
    • Mead, R.N.1    Poehlein, G.W.2
  • 45
    • 0024962136 scopus 로고
    • Free-radical transport from latex particles
    • Mead, R. N.; Poehlein, G. W. Free-radical transport from latex particles. J. Appl. Polym. Sci. 1989b, 38, 105.
    • (1989) J. Appl. Polym. Sci. , vol.38 , pp. 105
    • Mead, R.N.1    Poehlein, G.W.2
  • 46
    • 2742577400 scopus 로고
    • Absolute propagation rates in emulsion polymerization. II. Butadiene in hydroperoxide-polyamine systems
    • Morton, M.; Salatiello, P. P.; Landfield, H. Absolute propagation rates in emulsion polymerization. II. Butadiene in hydroperoxide-polyamine systems. J. Polym. Sci. 1952, 8, 215.
    • (1952) J. Polym. Sci. , vol.8 , pp. 215
    • Morton, M.1    Salatiello, P.P.2    Landfield, H.3
  • 48
    • 0019342799 scopus 로고
    • Rate coefficient for radical desorption in emulsion polymerization
    • Nomura, M.; Harada, M. Rate coefficient for radical desorption in emulsion polymerization. J. Appl. Polym. Sci. 1981, 26, 17.
    • (1981) J. Appl. Polym. Sci. , vol.26 , pp. 17
    • Nomura, M.1    Harada, M.2
  • 50
    • 0026104477 scopus 로고
    • The acceleration of decomposition of potassium persulfate in the presence of sodium dodecyl sulfate and polymer particles as a model of emulsion polymerization system
    • Okubo, M.; Fujimura, M.; Mori, T. The acceleration of decomposition of potassium persulfate in the presence of sodium dodecyl sulfate and polymer particles as a model of emulsion polymerization system. Colloid Polym. Sci. 1991, 269, 121.
    • (1991) Colloid Polym. Sci. , vol.269 , pp. 121
    • Okubo, M.1    Fujimura, M.2    Mori, T.3
  • 51
    • 0022682420 scopus 로고
    • The computer modeling of multicomponent, semibatch emulsion copolymerization
    • Omi, S.; Kushibiki, K.; Iso, M. The computer modeling of multicomponent, semibatch emulsion copolymerization. Polym. Eng. Sci. 1987, 27, 470.
    • (1987) Polym. Eng. Sci. , vol.27 , pp. 470
    • Omi, S.1    Kushibiki, K.2    Iso, M.3
  • 52
    • 0006597232 scopus 로고
    • Kinetics of the reactions between iron-(II) and some hydroperoxides based upon cumene and cyclohexane
    • Orr, R. J.; Williams, H. L. Kinetics of the reactions between iron-(II) and some hydroperoxides based upon cumene and cyclohexane. J. Phys. Chem. 1953, 57, 925.
    • (1953) J. Phys. Chem. , vol.57 , pp. 925
    • Orr, R.J.1    Williams, H.L.2
  • 53
    • 84944636531 scopus 로고
    • Kinetics of emulsion polymerization
    • O'Toole, J. T. Kinetics of emulsion polymerization. J. Appl. Polym. Sci. 1965, 9, 1291.
    • (1965) J. Appl. Polym. Sci. , vol.9 , pp. 1291
    • O'Toole, J.T.1
  • 54
    • 1542511055 scopus 로고
    • Ph.D. Thesis, Department of Chemical Engineering, McMaster University, Hamilton, Ontario, Canada
    • Penlidis, A. Latex production technology-Reactor design considerations. Ph.D. Thesis, Department of Chemical Engineering, McMaster University, Hamilton, Ontario, Canada, 1986.
    • (1986) Latex Production Technology-Reactor Design Considerations
    • Penlidis, A.1
  • 55
    • 0022075722 scopus 로고
    • Dynamic modeling of emulsion polymerization reactors
    • Penlidis, A.; MacGregor, J. F.; Hamielec, A. E. Dynamic modeling of emulsion polymerization reactors. AIChE J. 1985, 31, 881.
    • (1985) AIChE J. , vol.31 , pp. 881
    • Penlidis, A.1    MacGregor, J.F.2    Hamielec, A.E.3
  • 56
    • 0022866201 scopus 로고
    • Mathematical modelling of emulsion polymerization reactors: A population balance approach and its applications
    • Provder, T., Ed.; ACS Symposium Series 313; American Chemical Society: Washington, DC
    • Penlidis, A.; MacGregor, J. F.; Hamielec, A. E. Mathematical modelling of emulsion polymerization reactors: A population balance approach and its applications. In Computer Applications in the Polymer Laboratory; Provder, T., Ed.; ACS Symposium Series 313; American Chemical Society: Washington, DC, 1986; pp 219-240.
    • (1986) Computer Applications in the Polymer Laboratory , pp. 219-240
    • Penlidis, A.1    MacGregor, J.F.2    Hamielec, A.E.3
  • 57
    • 0024034925 scopus 로고
    • Effect of impurities on emulsion polymerization: Case I kinetics
    • Penlidis, A.; MacGregor, J. F.; Hamielec, A. E. Effect of impurities on emulsion polymerization: Case I kinetics. J. Appl. Polym. Sci. 1988, 35, 2023.
    • (1988) J. Appl. Polym. Sci. , vol.35 , pp. 2023
    • Penlidis, A.1    MacGregor, J.F.2    Hamielec, A.E.3
  • 58
    • 85081185580 scopus 로고
    • Personal communication
    • Poehlein, G. W. Personal communication, 1990.
    • (1990)
    • Poehlein, G.W.1
  • 59
    • 0007115898 scopus 로고
    • Free radical transport and reactions in emulsion polymerization
    • Reichert, K. H., Geiseler, W., Eds.; Berlin Workshop: Hüthig and Wepf
    • Poehlein, G. W.; Lee, H. C.; Chern, C.-S. Free radical transport and reactions in emulsion polymerization. In Polymer Reaction Engineering; Reichert, K. H., Geiseler, W., Eds.; Berlin Workshop: Hüthig and Wepf, 1986; pp 59-70.
    • (1986) Polymer Reaction Engineering , pp. 59-70
    • Poehlein, G.W.1    Lee, H.C.2    Chern, C.-S.3
  • 61
    • 0023984644 scopus 로고
    • The modeling of batch and continuous emulsion polymerization reactors. Part 1: Model formulation and sensitivity to parameters
    • Rawlings, J. B.; Ray, W. H. The modeling of batch and continuous emulsion polymerization reactors. Part 1: Model formulation and sensitivity to parameters. Polym. Eng. Sci. 1988, 28, 237.
    • (1988) Polym. Eng. Sci. , vol.28 , pp. 237
    • Rawlings, J.B.1    Ray, W.H.2
  • 62
    • 84947850703 scopus 로고
    • On the mathematical modeling of polymerization reactors
    • Ray, W. H. On the mathematical modeling of polymerization reactors. J. Macromol. Sci., Rev. Macromol. Chem. 1972, C8, 1.
    • (1972) J. Macromol. Sci., Rev. Macromol. Chem. , vol.C8 , pp. 1
    • Ray, W.H.1
  • 63
    • 0024048094 scopus 로고
    • Initiator efficiencies in high-conversion bulk polymerization
    • Russell, G. T.; Napper, D. H.; Gilbert, R. G. Initiator efficiencies in high-conversion bulk polymerization. Macromolecules 1988, 27, 2141.
    • (1988) Macromolecules , vol.27 , pp. 2141
    • Russell, G.T.1    Napper, D.H.2    Gilbert, R.G.3
  • 64
    • 0024089167 scopus 로고
    • Persulfate initiated aqueous polymerization of acrylonitrile at 50 °C in an inert atmosphere of nitrogen gas
    • Sarkar, S.; Adhikari, M. S.; Banerjee, M.; Konar, R. S. Persulfate initiated aqueous polymerization of acrylonitrile at 50 °C in an inert atmosphere of nitrogen gas. J. Appl. Polym. Sci. 1988, 36, 1865.
    • (1988) J. Appl. Polym. Sci. , vol.36 , pp. 1865
    • Sarkar, S.1    Adhikari, M.S.2    Banerjee, M.3    Konar, R.S.4
  • 65
    • 0025700374 scopus 로고
    • Mechanism of persulfate decomposition in aqueous solution at 50 °C in the presence of vinyl acetate and nitrogen
    • Sarkar, S.; Adhikari, M. S.; Banerjee, M.; Konar, R. S. Mechanism of persulfate decomposition in aqueous solution at 50 °C in the presence of vinyl acetate and nitrogen. J. Appl. Polym. Sci. 1990, 39, 1061.
    • (1990) J. Appl. Polym. Sci. , vol.39 , pp. 1061
    • Sarkar, S.1    Adhikari, M.S.2    Banerjee, M.3    Konar, R.S.4
  • 66
    • 0023861685 scopus 로고
    • Particle formation in emulsion polymerization: Transient particle concentration
    • Song, Z.; Poehlein, G. W. Particle formation in emulsion polymerization: Transient particle concentration. J. Macromol. Sci., Chem. 1988a, A25, 403.
    • (1988) J. Macromol. Sci., Chem. , vol.A25 , pp. 403
    • Song, Z.1    Poehlein, G.W.2
  • 67
    • 0024136426 scopus 로고
    • Particle formation in emulsion polymerization: Particle number at steady state
    • Song, Z.; Poehlein, G. W. Particle formation in emulsion polymerization: particle number at steady state. J. Macromol. Sci., Chem. 1988b, A25, 1587.
    • (1988) J. Macromol. Sci., Chem. , vol.A25 , pp. 1587
    • Song, Z.1    Poehlein, G.W.2
  • 68
    • 0001527388 scopus 로고
    • Note on the kinetics of emulsion polymerization
    • Stockmayer, W. H. Note on the kinetics of emulsion polymerization. J. Polym. Sci. 1957, 24, 314.
    • (1957) J. Polym. Sci. , vol.24 , pp. 314
    • Stockmayer, W.H.1
  • 69
    • 0025798880 scopus 로고
    • Kinetics of free-radical copolymerization: The pseudo-kinetic rate constant method
    • Tobita, H.; Hamielec, A. E. Kinetics of free-radical copolymerization: the pseudo-kinetic rate constant method. Polymer 1991, 32, 2641.
    • (1991) Polymer , vol.32 , pp. 2641
    • Tobita, H.1    Hamielec, A.E.2
  • 70
    • 0016974394 scopus 로고
    • Kinetics and mechanism of emulsion polymerization
    • Ugelstad, J.; Hansen, F. K. Kinetics and mechanism of emulsion polymerization. Rubber Chem. Technol. 1976, 49, 536.
    • (1976) Rubber Chem. Technol. , vol.49 , pp. 536
    • Ugelstad, J.1    Hansen, F.K.2
  • 72
    • 0001600471 scopus 로고
    • Emulsion polymerizations: Initiation of polymerization in monomer droplets
    • Ugelstad, J.; El-Aasser, M.; Vanderhoff, J. Emulsion polymerizations: Initiation of polymerization in monomer droplets. J. Polym. Sci., Polym. Lett. 1973, 11, 503.
    • (1973) J. Polym. Sci., Polym. Lett. , vol.11 , pp. 503
    • Ugelstad, J.1    El-Aasser, M.2    Vanderhoff, J.3
  • 73
    • 0001172787 scopus 로고
    • Emulsion polymerization of styrene with sodium hexadecyl sulfate/hexadecanol mixtures as emulsifiers. Initiation in monomer droplets
    • Ugelstad, J.; Hansen, F. K.; Lange, S. Emulsion polymerization of styrene with sodium hexadecyl sulfate/hexadecanol mixtures as emulsifiers. Initiation in monomer droplets. Makromol. Chem. 1974, 175, 507.
    • (1974) Makromol. Chem. , vol.175 , pp. 507
    • Ugelstad, J.1    Hansen, F.K.2    Lange, S.3
  • 77
    • 0027912433 scopus 로고
    • Seeded emulsion polymerization of butadiene. 2. Effects of persulfate and teri-dodecyl mercaptan
    • Verdurmen, E. M.; Geurts, J. M.; Verstegen, J. M.; Maxwell, I. A.; German, A. L. Seeded emulsion polymerization of butadiene. 2. Effects of persulfate and teri-dodecyl mercaptan. Macromolecules 1993b, 26, 6289.
    • (1993) Macromolecules , vol.26 , pp. 6289
    • Verdurmen, E.M.1    Geurts, J.M.2    Verstegen, J.M.3    Maxwell, I.A.4    German, A.L.5
  • 78
    • 2742544610 scopus 로고
    • Particle growth in butadiene emulsion polymerization, 2. Gamma radiolysis
    • Verdurmen, E. M.; German, A. L.; Sudol, E. D.; Gilbert, R. G. Particle growth in butadiene emulsion polymerization, 2. Gamma radiolysis. Macromol. Chem. Phys. 1994a, 195, 635.
    • (1994) Macromol. Chem. Phys. , vol.195 , pp. 635
    • Verdurmen, E.M.1    German, A.L.2    Sudol, E.D.3    Gilbert, R.G.4
  • 79
    • 0344521825 scopus 로고
    • Particle growth in butadiene emulsion polymerization, 1. The use of Fremy salt as aqueous radical scavenger
    • Verdurmen, E. M.; Geurts, J. M.; German, A. L. Particle growth in butadiene emulsion polymerization, 1. The use of Fremy salt as aqueous radical scavenger. Macromol. Chem. Phys. 1994b, 195, 621.
    • (1994) Macromol. Chem. Phys. , vol.195 , pp. 621
    • Verdurmen, E.M.1    Geurts, J.M.2    German, A.L.3
  • 80
    • 84986753311 scopus 로고
    • Particle growth in butadiene emulsion polymerization, 3. Radical adsorption and desorption rate coefficients
    • Verdurmen, E. M.; Geurts, J. M.; German, A. L. Particle growth in butadiene emulsion polymerization, 3. Radical adsorption and desorption rate coefficients. Macromol. Chem. Phys. 1994c, 195, 641.
    • (1994) Macromol. Chem. Phys. , vol.195 , pp. 641
    • Verdurmen, E.M.1    Geurts, J.M.2    German, A.L.3
  • 81
    • 0742324775 scopus 로고
    • Particle growth in butadiene emulsion polymerization, 4. The promoting effect of mercaptans
    • Verdurmen, E. M.; Verstegen, J. M.; German, A. L. Particle growth in butadiene emulsion polymerization, 4. The promoting effect of mercaptans. Macromol. Chem. Phys. 1994d, 195, 647.
    • (1994) Macromol. Chem. Phys. , vol.195 , pp. 647
    • Verdurmen, E.M.1    Verstegen, J.M.2    German, A.L.3
  • 82
    • 84952393642 scopus 로고
    • Acrylonitrile copolymerizations. IV. Butadiene copolymerization
    • Vialle, J.; Guillot, J.; Guyot, A. Acrylonitrile copolymerizations. IV. Butadiene copolymerization. J. Macromol. Sci., Chem. 1971, A5, 1229
    • (1971) J. Macromol. Sci., Chem. , vol.A5 , pp. 1229
    • Vialle, J.1    Guillot, J.2    Guyot, A.3
  • 83
    • 0042936404 scopus 로고
    • Properties of polymers as functions of conversion. IV. Composition studies of rubber-like copolymers
    • Wall, F.T.; Powers, R. W.; Sands, G. D.; Stent, G. S. Properties of polymers as functions of conversion. IV. Composition studies of rubber-like copolymers. J. Am. Chem. Soc. 1948, 70, 1031.
    • (1948) J. Am. Chem. Soc. , vol.70 , pp. 1031
    • Wall, F.T.1    Powers, R.W.2    Sands, G.D.3    Stent, G.S.4
  • 85
    • 0026138167 scopus 로고
    • Kinetic aspects of the emulsion polymerization of butadiene
    • Weerts, P. A.; German, A. L. Kinetic aspects of the emulsion polymerization of butadiene. Macromolecules 1991, 24, 1622.
    • (1991) Macromolecules , vol.24 , pp. 1622
    • Weerts, P.A.1    German, A.L.2
  • 86
    • 0024069255 scopus 로고
    • Initiation phenomena in the emulsion polymerization of butadiene and isoprene
    • Weerts, P. A.; van der Loos, J. L. M.; German, A. L. Initiation phenomena in the emulsion polymerization of butadiene and isoprene. Polym. Commun. 1988, 29, 278.
    • (1988) Polym. Commun. , vol.29 , pp. 278
    • Weerts, P.A.1    Van Der Loos, J.L.M.2    German, A.L.3
  • 87
    • 0042444313 scopus 로고
    • Emulsion polymerization of butadiene, 1. The effects of initiator and emulsifier concentration
    • Weerts, P. A.; van der Loos, J. L. M.; German, A. L. Emulsion polymerization of butadiene, 1. The effects of initiator and emulsifier concentration. Makromol. Chem. 1989, 190, 777.
    • (1989) Makromol. Chem. , vol.190 , pp. 777
    • Weerts, P.A.1    Van Der Loos, J.L.M.2    German, A.L.3
  • 88
    • 0011134837 scopus 로고
    • Emulsion polymerization of butadiene, 2. Polymerizations with sodium dodecyl sulfate
    • Weerts, P. A.; van der Loos, J. L. M.; German, A. L. Emulsion polymerization of butadiene, 2. Polymerizations with sodium dodecyl sulfate. Makromol. Chem. 1990, 191, 2615.
    • (1990) Makromol. Chem. , vol.191 , pp. 2615
    • Weerts, P.A.1    Van Der Loos, J.L.M.2    German, A.L.3
  • 89
    • 0000083861 scopus 로고
    • Emulsion polymerization of butadiene, 3. Kinetic effects of stirring conditions and monomer/water ratio
    • Weerts, P. A.; van der Loos, J. L. M.; German, A. L. Emulsion polymerization of butadiene, 3. Kinetic effects of stirring conditions and monomer/water ratio. Makromol. Chem. 1991a, 192, 1993.
    • (1991) Makromol. Chem. , vol.192 , pp. 1993
    • Weerts, P.A.1    Van Der Loos, J.L.M.2    German, A.L.3
  • 90
    • 0001256578 scopus 로고
    • Emulsion polymerization of butadiene, 4. Effect of thiols
    • Weerts, P. A.; van der Loos, J. L. M.; German, A. L. Emulsion polymerization of butadiene, 4. Effect of thiols. Makromol. Chem. 1991b, 192, 2009.
    • (1991) Makromol. Chem. , vol.192 , pp. 2009
    • Weerts, P.A.1    Van Der Loos, J.L.M.2    German, A.L.3
  • 91
    • 84981454185 scopus 로고
    • Modelling free-radical copolymerization kinetics-evaluation of the pseudo-kinetic rate constant method, 1. Molecular weight calculation for linear copolymers
    • Xie, T.; Hamielec, A. E. Modelling free-radical copolymerization kinetics-evaluation of the pseudo-kinetic rate constant method, 1. Molecular weight calculation for linear copolymers. Makromol. Chem., Theory Simul. 1993a, 2, 421.
    • (1993) Makromol. Chem., Theory Simul. , vol.2 , pp. 421
    • Xie, T.1    Hamielec, A.E.2
  • 92
    • 84981425975 scopus 로고
    • Modelling free-radical copolymerization kinetics-evaluation of the pseudo-kinetic rate constant method, 2. Molecular weight calculations for copolymers with long chain branching
    • Xie, T.; Hamielec, A. E. Modelling free-radical copolymerization kinetics-evaluation of the pseudo-kinetic rate constant method, 2. Molecular weight calculations for copolymers with long chain branching. Makromol. Chem., Theory Simul. 1993b, 2, 455.
    • (1993) Makromol. Chem., Theory Simul. , vol.2 , pp. 455
    • Xie, T.1    Hamielec, A.E.2
  • 93
    • 0025383274 scopus 로고
    • Radical trapping and termination in free-radical polymerization of MMA
    • Zhu, S.; Tian, Y.; Hamielec, A. E.; Eaton, D. R. Radical trapping and termination in free-radical polymerization of MMA. Macromolecules 1990, 23, 1144.
    • (1990) Macromolecules , vol.23 , pp. 1144
    • Zhu, S.1    Tian, Y.2    Hamielec, A.E.3    Eaton, D.R.4


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