-
1
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0010636960
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For recent reviews, see: (a) S. Trofimenko, Chem. Rev., 1993, 93, 943;
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Chem. Rev.
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Trofimenko, S.1
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7
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0002909119
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(g) P. K. Byers, A. J. Canty and R. T. Honeyman, Adv. Organomet. Chem., 1992, 34, 1.
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Adv. Organomet. Chem.
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Byers, P.K.1
Canty, A.J.2
Honeyman, R.T.3
-
10
-
-
33748496714
-
-
note
-
The abbreviations adopted here for tris(pyrazolyl)hydroborato ligands are based on those described by Trofimenko [ref. 1(a)]. Thus, the tris(pyrazolyl)hydroborato ligands are represented by the abbreviation Tp, with the 3- and 5-alkyl substituents listed respectively as superscripts. If the fourth substituent on boron is anything other than hydrogen, the substituent is listed as a prefix, e.g., [pzTp] and [RTp].
-
-
-
-
11
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-
0032517288
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-
See, for example: J. L. Kisko, T. Hascall and G. Parkin, J. Am. Chem. Soc., 1998, 120, 10561.
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(1998)
J. Am. Chem. Soc.
, vol.120
, pp. 10561
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Kisko, J.L.1
Hascall, T.2
Parkin, G.3
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15
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-
33748508885
-
-
ref. 5
-
(b) ref. 5;
-
-
-
-
17
-
-
4243558328
-
-
3] with pyrazole. See: F. A. Cotton, C. A. Murillo and B. R. Stults, Inorg. Chim. Acta, 1977, 22, 75.
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(1977)
Inorg. Chim. Acta
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-
-
Cotton, F.A.1
Murillo, C.A.2
Stults, B.R.3
-
18
-
-
85087244613
-
-
2 with excess pyrazole. See ref. 5
-
2 with excess pyrazole. See ref. 5.
-
-
-
-
19
-
-
0000322835
-
-
3N. Subsequent reaction of [FcTp]H with TlOEt gives the thallium complex Tl[FcTp]. F. Jäkle, K. Polborn and M. Wagner, Chem. Ber., 1996, 129, 603.
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(1996)
Chem. Ber.
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, pp. 603
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-
Jäkle, F.1
Polborn, K.2
Wagner, M.3
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20
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-
0000623329
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-
U. E. Bucher, T. F. Fässler, M. Hunziker, R. Nesper, H. Rüegger and L. M. Venanzi, Gazz. Chim. Ital., 1995, 125, 181.
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Gazz. Chim. Ital.
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Bucher, U.E.1
Fässler, T.F.2
Hunziker, M.3
Nesper, R.4
Rüegger, H.5
Venanzi, L.M.6
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21
-
-
0029554943
-
-
For example, terminal alkyl, hydride, hydroxide and chalcogenide moieties have been stabilized with such ligation. See, for example, ref. 1(b) and (a) M. C. Kuchta and G. Parkin, J. Am. Chem. Soc., 1995, 117, 12651;
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(1995)
J. Am. Chem. Soc.
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Kuchta, M.C.1
Parkin, G.2
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24
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0000012396
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-
B. Singaram, T. E. Cole and H. C. Brown, Organometallics, 1984, 3, 774.
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(1984)
Organometallics
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Singaram, B.1
Cole, T.E.2
Brown, H.C.3
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25
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85087245531
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-
unpublished work
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ButpzH) may be isolated. J. L. Kisko and G. Parkin, unpublished work.
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-
-
Kisko, J.L.1
Parkin, G.2
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28
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8344237511
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C. López, R. M. Claramunt, C. Foces-Foces, F. H. Cano and J. Elguero, Rev. Roum. Chim., 1994, 9, 795.
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Rev. Roum. Chim.
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López, C.1
Claramunt, R.M.2
Foces-Foces, C.3
Cano, F.H.4
Elguero, J.5
-
29
-
-
0031170287
-
-
RR′]H derivatives have also been prepared by this method. See: J. Blackwell, C. Lehr, Y. Sun, W. E. Piers, S. D. Pearce-Batchilder, M. J. Zaworotko and V. G. Young, Jr., Can J. Chem., 1997, 75, 702 and footnote 5 therein.
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Can J. Chem.
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Blackwell, J.1
Lehr, C.2
Sun, Y.3
Piers, W.E.4
Pearce-Batchilder, S.D.5
Zaworotko, M.J.6
Young Jr., V.G.7
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30
-
-
84974761339
-
-
RR′]M derivatives, see, for example: (a) C. M. Dowling, D. Leslie, M. H. Chisholm and G. Parkin, Main Group Chem., 1995, 1, 29;
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Main Group Chem.
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Dowling, C.M.1
Leslie, D.2
Chisholm, M.H.3
Parkin, G.4
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31
-
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0003141733
-
-
(b) C. Lopez, R. M. Claramunt, D. Sanz, C. Foces Foces, F. H. Cano, E. Faure, E. Cayon and J. Elguero, Inorg. Chim. Acta, 1990, 176, 195;
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Inorg. Chim. Acta
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Lopez, C.1
Claramunt, R.M.2
Sanz, D.3
Foces Foces, C.4
Cano, F.H.5
Faure, E.6
Cayon, E.7
Elguero, J.8
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32
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0002556691
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(c) G. G. Lobbia, P. Cecchi, R. Spagna, M. Colapietro, A. Pifferi and C. Pettinari, J. Organomet. Chem., 1995, 485, 45;
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J. Organomet. Chem.
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Lobbia, G.G.1
Cecchi, P.2
Spagna, R.3
Colapietro, M.4
Pifferi, A.5
Pettinari, C.6
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35
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0001134370
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(f) H. V. R. Dias, W. C. Jin, H. J. Kim and H.-L. Lu, Inorg. Chem., 1996, 35, 2317;
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Dias, H.V.R.1
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Lu, H.-L.4
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36
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0001407233
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(g) H. V. R. Dias, H.-L. Lu, R. E. Ratcliff and S. G. Bott, Inorg. Chem., 1995, 34, 1975.
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Dias, H.V.R.1
Lu, H.-L.2
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Bott, S.G.4
-
37
-
-
33748507623
-
-
note
-
Although three coordination of lithium is less common than its ubiquitous tetrahedral coordination, it is nevertheless well precedented. For example, ca. 20% of the lithium complexes listed in the Cambridge Structural Database have a coordination number of three for lithium.
-
-
-
-
38
-
-
0002087304
-
CSD Version 5.16, 1999, 3D Search and Research Using the Cambridge Structural Database
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CSD Version 5.16, 1999, 3D Search and Research Using the Cambridge Structural Database, F. H. Allen and O. Kennard, Chem. Des. Automat. News, 1993, 8, pp. 1, 31-37.
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Chem. Des. Automat. News
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Allen, F.H.1
Kennard, O.2
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39
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0000340328
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D. L. Reger, J. E. Collins, M. A. Matthews, A. L. Rheingold, L. M. Liable-Sands and I. A. Guzei, Inorg. Chem., 1997, 36, 6266.
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Reger, D.L.1
Collins, J.E.2
Matthews, M.A.3
Rheingold, A.L.4
Liable-Sands, L.M.5
Guzei, I.A.6
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40
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37049096762
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D. C. Bradley, M. B. Hursthouse, J. Newton and N. P. C. Walker, J. Chem. Soc., Chem. Commun., 1984, 188.
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J. Chem. Soc., Chem. Commun.
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Bradley, D.C.1
Hursthouse, M.B.2
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Walker, N.P.C.4
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41
-
-
33748722523
-
-
For a compilation of data, see: R. Han, P. Ghosh, P. J. Desrosiers, S. Trofimenko and G. Parkin, J. Chem. Soc., Dalton Trans., 1997, 3713.
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J. Chem. Soc., Dalton Trans.
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Han, R.1
Ghosh, P.2
Desrosiers, P.J.3
Trofimenko, S.4
Parkin, G.5
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42
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0002388406
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A. H. Cowley, R. L. Geerts, C. M. Nunn and S. Trofimenko, J. Organomet. Chem., 1989, 365, 19.
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Cowley, A.H.1
Geerts, R.L.2
Nunn, C.M.3
Trofimenko, S.4
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43
-
-
0000446662
-
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For other examples in which intraligand interactions influence the binding mode of poly(pyrazolyl)borate complexes, see: (a) Y. Sohrin, H. Kokusen and M. Matsui, Inorg. Chem., 1995, 34, 3928;
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Sohrin, Y.1
Kokusen, H.2
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44
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0000374692
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(b) D. L. Reger, M. F. Huff, A. L. Rheingold and B. S. Haggerty, Inorg. Chem., 1992, 114, 579;
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Reger, D.L.1
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45
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0008028776
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(c) F. A. Cotton, B. A. Frenz and C. A. Murillo, J. Am. Chem. Soc., 1975, 97, 2118.
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Cotton, F.A.1
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46
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0000628932
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(a) C. Dowling, P. Ghosh and G. Parkin, Polyhedron, 1997, 16, 3469;
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Polyhedron
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Dowling, C.1
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47
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0000007589
-
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(b) T. Fillebeen, T. Hascall and G. Parkin, Inorg. Chem., 1997, 36, 3787;
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Inorg. Chem.
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Fillebeen, T.1
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48
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33748479909
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(c) P. Ghosh, T. Hascall, C. Dowling and G. Parkin, J. Chem. Soc., Dalton Trans., 1998, 3355.
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J. Chem. Soc., Dalton Trans.
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Ghosh, P.1
Hascall, T.2
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Parkin, G.4
-
49
-
-
33748488276
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-
For example, only 7% of the structurally characterized lithium complexes listed in the Cambridge Structural Database are two coordinate
-
For example, only 7% of the structurally characterized lithium complexes listed in the Cambridge Structural Database are two coordinate.
-
-
-
-
50
-
-
0000253997
-
-
RR′]Tl complexes. See, for example: (a) G. Ferguson, M. C. Jennings, F. J. Lalor and C. Shanahan, Acta. Crystallogr., Sect. C, 1991, 47, 2079;
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Acta. Crystallogr., Sect. C
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-
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Ferguson, G.1
Jennings, M.C.2
Lalor, F.J.3
Shanahan, C.4
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51
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1542685177
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(b) A. L. Rheingold, L. M. Liable-Sands and S. Trofimenko, J. Chem. Soc., Chem. Commun., 1997, 1691;
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Rheingold, A.L.1
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52
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0032397586
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(c) C. Janiak, S. Temizdemir and T. G. Scharmann, Z. Anorg. Allg. Chem., 1998, 624, 755.
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Z. Anorg. Allg. Chem.
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-
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Janiak, C.1
Temizdemir, S.2
Scharmann, T.G.3
-
53
-
-
85087245646
-
-
note
-
205Tl NMR spectroscopic signals (2:2.6 at -70°C). In view of the potentially different relaxation times for the different thallium nuclei, the integral ratio is not expected to be an accurate measure of their relative concentrations.
-
-
-
-
54
-
-
85087244094
-
-
note
-
2:1 could correspond to the equatorial isomer of Scenario I.
-
-
-
-
55
-
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0002270541
-
-
U. E. Bucher, A. Currao, R. Nesper, H. Rüegger, L. M. Venanzi and E. Younger, Inorg. Chem., 1995, 34, 66.
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Bucher, U.E.1
Currao, A.2
Nesper, R.3
Rüegger, H.4
Venanzi, L.M.5
Younger, E.6
-
57
-
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0002820924
-
-
ed. A. L. Wayda and M. Y. Darensbourg, American Chemical Society, Washington, DC, ch. 2
-
(a) J. P. McNally, V. S. Leong and N. J. Cooper, in Experimental Organometallic Chemistry, ed. A. L. Wayda and M. Y. Darensbourg, American Chemical Society, Washington, DC, 1987, ch. 2, pp. 6-23;
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Experimental Organometallic Chemistry
, pp. 6-23
-
-
McNally, J.P.1
Leong, V.S.2
Cooper, N.J.3
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58
-
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0002522541
-
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eds. A. L. Wayda and M. Y. Darensbourg, American Chemical Society, Washington, DC, ch. 4
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(b) B. J. Burger and J. E. Bercaw, in Experimental Organometallic Chemistry, eds. A. L. Wayda and M. Y. Darensbourg, American Chemical Society, Washington, DC, 1987, ch. 4, pp. 79-98;
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Experimental Organometallic Chemistry
, pp. 79-98
-
-
Burger, B.J.1
Bercaw, J.E.2
-
61
-
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85087245405
-
-
2O (1.0, 0.5 and 0.25 M) were extrapolated to zero concentration
-
2O (1.0, 0.5 and 0.25 M) were extrapolated to zero concentration.
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-
-
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