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SAMs derived from the chemisorption of n-alkanethiols on Au(111) represent the only other systems for which a highly ordered, commensurate overlayer structure has been unequivocally shown to exist. See: (a) Camillone, N., III; Chidsey, C. E. D.; Liu, G.-Y.; Scoles, G. J. Chem. Phys. 1993, 98, 3503. (b) Poirier, G. E.; Tarlov, M. J. Langmuir 1994, 10, 2853.
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SAMs derived from the chemisorption of n-alkanethiols on Au(111) represent the only other systems for which a highly ordered, commensurate overlayer structure has been unequivocally shown to exist. See: (a) Camillone, N., III; Chidsey, C. E. D.; Liu, G.-Y.; Scoles, G. J. Chem. Phys. 1993, 98, 3503. (b) Poirier, G. E.; Tarlov, M. J. Langmuir 1994, 10, 2853.
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and references cited therein
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For SAM systems that are known to form ordered, but incommensurate overlayer structures, see: (a) Liu, G.-Y.; Fenter, P.; Chidsey, C. E. D.; Ogletree, D. F.; Eisenberger, P.; Salmeron, M. J. Chem. Phys. 1994, 101, 4301 and references cited therein. (b) Wolf, H.; Ringsdorf, H.; Delamarche, E.; Takami, T.; Kang, H.; Michel, B.; Gerber, C.; Jaschke, M.; Butt, H.-J.; Bamberg, E. J. Phys. Chem. 1995, 99, 7102. (c) Caldwell, W. B.; Campbell, D. J.; Chen, K.; Herr, B. R.; Mirkin, C. A.; Malik, A.; Durbin, M. K.; Dutta, P.; Huang, K. G. J. Am. Chem. Soc. 1995, 117, 6071.
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For previous studies of SAMs derived from conjugated arenethiols in which order has been proposed but not unequivocally established, see: (a) Chang, S. C.; Chao, I.; Tao, Y. J. Am. Chem. Soc. 1994, 116, 6792. (b) Tour, J. M.; Jones, L.; Pearson, D. L.; Lamba, J. J. S.; Burgin, T. P.; Whitesides, G. M.; Allara, D. L.; Parikh, A. N.; Atre, S. V. J. Am. Chem. Soc. 1995, 117, 9529. (c) Sabatani, E.; Cohen-Boulakia, J.; Bruening, M.; Rubinstein, I. Langmuir 1993; 9, 2974.
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For previous studies of SAMs derived from conjugated arenethiols in which order has been proposed but not unequivocally established, see: (a) Chang, S. C.; Chao, I.; Tao, Y. J. Am. Chem. Soc. 1994, 116, 6792. (b) Tour, J. M.; Jones, L.; Pearson, D. L.; Lamba, J. J. S.; Burgin, T. P.; Whitesides, G. M.; Allara, D. L.; Parikh, A. N.; Atre, S. V. J. Am. Chem. Soc. 1995, 117, 9529. (c) Sabatani, E.; Cohen-Boulakia, J.; Bruening, M.; Rubinstein, I. Langmuir 1993; 9, 2974.
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For previous electrochemical studies of SAMs of rigid rod arenethiol adsorbates, see ref 7c and (a) Kwan, W. S. V.; Atanasoska, L.; Miller, L. L. Langmuir 1991, 7, 1419. (b) Kwan, V. W. S.; Cammarata, V.; Miller, L. L.; Hill, M. G.; Mann, K. R. Langmuir 1992, 8, 3003.
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5344264483
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note
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The predicted thickness of SAMs of 1a is measured from the outer edge of the van der Waal surface of the terminal aryl hydrogen atom to the Au surface and assuming a Au-S bond length of 2.4 Å.
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Tat prepared SAMs of TPM using water as the "solvent"
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Tat prepared SAMs of TPM using water as the "solvent".
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44
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0030567289
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