New chiral complexes of palladium(0) containing P,S- and P,P-bidentate ligands

Organometallics

Volumn 16, Issue 15, 1997, Pages 3447-3453

  Tschoerner, Matthias ^a   Trabesinger, Gerald ^a   Albinati, Alberto ^b   Pregosin, Paul S ^a  

^a ETH ZURICH   (Switzerland)

^b UNIVERSITY OF MILAN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001571061     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970185r     Document Type: Article

References (60)

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50. For applications of 2-D exchange spectroscopy, see: (a) Pregosin, P. S.; Salzmann, R. Coord. Chem. Rev. 1996, 155, 35. (b) Togni, A.; Burckhardt, U.; Gramlich, V.; Pregosin, P.; Salzmann, R. J. Am. Chem. Soc. 1996, 118, 1031. (c) Barbaro, P.; Pregosin, P. S.; Salzmann, R.; Albinati, A.; Kunz, R. W. Organometallics 1995, 14, 5160. (d) Herrmann, J.; Pregosin, P. S.; Salzmann, R.; Albinati, A. Organometallics 1995, 14, 3311. (e) Pregosin, P. S.; Salzmann, R.; Togni, A. Organometallics 1995, 14, 842. (f) Breutel, C.; Pregosin, P. S.; Salzmann, R.; Togni, A. J. Am. Chem. Soc. 1994, 116, 4067.
51. For applications of 2-D exchange spectroscopy, see: (a) Pregosin, P. S.; Salzmann, R. Coord. Chem. Rev. 1996, 155, 35. (b) Togni, A.; Burckhardt, U.; Gramlich, V.; Pregosin, P.; Salzmann, R. J. Am. Chem. Soc. 1996, 118, 1031. (c) Barbaro, P.; Pregosin, P. S.; Salzmann, R.; Albinati, A.; Kunz, R. W. Organometallics 1995, 14, 5160. (d) Herrmann, J.; Pregosin, P. S.; Salzmann, R.; Albinati, A. Organometallics 1995, 14, 3311. (e) Pregosin, P. S.; Salzmann, R.; Togni, A. Organometallics 1995, 14, 842. (f) Breutel, C.; Pregosin, P. S.; Salzmann, R.; Togni, A. J. Am. Chem. Soc. 1994, 116, 4067.
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54. Close inspection of the aromatic region of 7 reveals two broad signals, with very similar chemical shifts. One of these broad signals lies almost completely under a different sharp resonance. We assign these broad resonances to two nonequivalent ortho protons of one P-aryl ring, so that one of the four rings is indeed, exhibiting restricted rotation. Nevertheless, the rotational barriers for 7 are smaller than those for 8.
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