The chemistry of vanadium-carbon bond functionalities over an oxo-surface defined by the calix[4]arene skeleton: The redox relationship between vanadium(III) and vanadium(IV) assisted by carbon-oxygen bond cleavage

Organometallics

Volumn 17, Issue 11, 1998, Pages 2328-2336

  Castellano, Barbara ^a   Solari, Euro ^a   Floriani, Carlo ^a   Re, Nazzareno ^b   Chiesi Villa, Angiola ^c   Rizzoli, Corrado ^c  

^a UNIVERSITY OF LAUSANNE   (Switzerland)

^b UNIVERSITY OF PERUGIA   (Italy)

^c UNIVERSITY OF PARMA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001549212     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9800389     Document Type: Article

References (70)

1. (a) Gutsche, C. D. Calixarenes; The Royal Society of Chemistry: Cambridge, U.K., 1989.
2. (b) Calixarenes, A Versatile Class of Macrocyclic Compounds; Vicens, J. Böhmer, V., Eds.; Kluwer: Dordrecht, The Netherlands, 1991.
3. (a) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1998, 120, 823-824.
4. (b) Zanotti-Gerosa, A.; Solari, E.; Giannini, L.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1998, 120, 437.
5. (c) Giannini, L.; Caselli, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N.; Sgamellotti, A. J. Am. Chem. Soc. 1997, 119, 9198.
6. (d) Ibid. 1997, 119, 9709.
7. (e) Caselli, A.; Giannini, L.; Solari, E.; Floriani, C.; Re, N.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1997, 16, 5457.
8. (f) Giannini, L.; Solari, E.; Zanotti-Gerosa, A.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1997, 36, 753.
9. (g) Giannini, L.; Solari, E.; Zanotti-Gerosa, A.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1996, 35, 2825.
10. (h) Castellano, B.; Zanotti-Gerosa, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1996, 15, 4894.
11. (i) Giannini, L.; Solari, E.; Zanotti-Gerosa, A.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1996, 35, 85.
12. (j) Gardiner, M. G.; Lawrence, S. M.; Raston, C. L.; Skelton, B. W.; White, A. H. Chem. Commun. 1996, 2491.
13. (k) Gardiner, M. G.; Koutsantonis, G. A.; Lawrence, S. M.; Nichols, P. J.; Raston, C. L. Chem. Commun. 1996, 2035.
14. (l) Gibson, V. C.; Redshaw, C.; Clegg, W.; Elsegood, M. R. J. J. Chem. Soc., Chem. Commun. 1995, 2371.
15. (m) Acho, J. A.; Doerrer, L. H.; Lippard, S. J. Inorg. Chem. 1995, 34, 2542.
16. (a) Vilas Boas, L. F.; Costa Pessoa, J. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, 1987; Vol. 3, Chapter 33, p 453.
17. (b) Vanadium in Biological Systems; Chasteen, N. D. Ed.; Kluwer: Dordrecht, The Netherlands, 1990.
18. (c) Mazzanti, M.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. J. Chem. Soc., Dalton Trans. 1989, 1793.
19. (d) Mazzanti, M.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1988, 27, 576.
20. Seidel, W.; Kreisel, G. Z. Chem. 1981, 21, 295. Preuss, F.; Ogger, L. Z. Naturforsch. 1982, 37b, 957. Seangprasertkij, R.; Riechel, T. L. Inorg. Chem. 1986, 25, 3121. Preuss, F.; Becker H. Z. Naturforsch. 1986, 41b, 185.
21. Seidel, W.; Kreisel, G. Z. Chem. 1981, 21, 295. Preuss, F.; Ogger, L. Z. Naturforsch. 1982, 37b, 957. Seangprasertkij, R.; Riechel, T. L. Inorg. Chem. 1986, 25, 3121. Preuss, F.; Becker H. Z. Naturforsch. 1986, 41b, 185.
22. Seidel, W.; Kreisel, G. Z. Chem. 1981, 21, 295. Preuss, F.; Ogger, L. Z. Naturforsch. 1982, 37b, 957. Seangprasertkij, R.; Riechel, T. L. Inorg. Chem. 1986, 25, 3121. Preuss, F.; Becker H. Z. Naturforsch. 1986, 41b, 185.
23. Seidel, W.; Kreisel, G. Z. Chem. 1981, 21, 295. Preuss, F.; Ogger, L. Z. Naturforsch. 1982, 37b, 957. Seangprasertkij, R.; Riechel, T. L. Inorg. Chem. 1986, 25, 3121. Preuss, F.; Becker H. Z. Naturforsch. 1986, 41b, 185.
24. Parkin, B. C.; Clark, J. R.; Visciglio, V. M.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1995, 14, 3002. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1995, 553. Yu, J. S.; Ankianiec, B. C.; Rothwell, I. P.; Nguyen, M. T. J. Am. Chem. Soc. 1992, 114, 1927. Chesnut, R. W.; Jacob, G. G.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1991, 10, 321. Bonanno, J. B.; Lobkovsky, E. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 11159. Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 5, Chapter 2, pp 57-153.
25. Parkin, B. C.; Clark, J. R.; Visciglio, V. M.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1995, 14, 3002. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1995, 553. Yu, J. S.; Ankianiec, B. C.; Rothwell, I. P.; Nguyen, M. T. J. Am. Chem. Soc. 1992, 114, 1927. Chesnut, R. W.; Jacob, G. G.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1991, 10, 321. Bonanno, J. B.; Lobkovsky, E. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 11159. Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 5, Chapter 2, pp 57-153.
26. Parkin, B. C.; Clark, J. R.; Visciglio, V. M.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1995, 14, 3002. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1995, 553. Yu, J. S.; Ankianiec, B. C.; Rothwell, I. P.; Nguyen, M. T. J. Am. Chem. Soc. 1992, 114, 1927. Chesnut, R. W.; Jacob, G. G.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1991, 10, 321. Bonanno, J. B.; Lobkovsky, E. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 11159. Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 5, Chapter 2, pp 57-153.
27. Parkin, B. C.; Clark, J. R.; Visciglio, V. M.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1995, 14, 3002. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1995, 553. Yu, J. S.; Ankianiec, B. C.; Rothwell, I. P.; Nguyen, M. T. J. Am. Chem. Soc. 1992, 114, 1927. Chesnut, R. W.; Jacob, G. G.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1991, 10, 321. Bonanno, J. B.; Lobkovsky, E. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 11159. Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 5, Chapter 2, pp 57-153.
28. Parkin, B. C.; Clark, J. R.; Visciglio, V. M.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1995, 14, 3002. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1995, 553. Yu, J. S.; Ankianiec, B. C.; Rothwell, I. P.; Nguyen, M. T. J. Am. Chem. Soc. 1992, 114, 1927. Chesnut, R. W.; Jacob, G. G.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1991, 10, 321. Bonanno, J. B.; Lobkovsky, E. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 11159. Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 5, Chapter 2, pp 57-153.
29. Parkin, B. C.; Clark, J. R.; Visciglio, V. M.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1995, 14, 3002. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1995, 553. Yu, J. S.; Ankianiec, B. C.; Rothwell, I. P.; Nguyen, M. T. J. Am. Chem. Soc. 1992, 114, 1927. Chesnut, R. W.; Jacob, G. G.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1991, 10, 321. Bonanno, J. B.; Lobkovsky, E. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 11159. Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 5, Chapter 2, pp 57-153.
30. Parkin, B. C.; Clark, J. R.; Visciglio, V. M.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1995, 14, 3002. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1995, 553. Yu, J. S.; Ankianiec, B. C.; Rothwell, I. P.; Nguyen, M. T. J. Am. Chem. Soc. 1992, 114, 1927. Chesnut, R. W.; Jacob, G. G.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1991, 10, 321. Bonanno, J. B.; Lobkovsky, E. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 11159. Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570. Wigley, D. E.; Gray, S. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 5, Chapter 2, pp 57-153.
31. Karol, F. J.; Cann, K. J.; Wagner, B. E. In Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer: New York, 1988; pp 149-161.
32. Feher, F. J.; Newman, D. A.; Walzer, J. F. J. Am. Chem. Soc. 1989, 111, 1741. Feher, F. J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689. Feher, F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618. Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886. Feher, F. J.; Blanski, R. L. Organometallics 1993, 12, 958. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239 and references therein.
33. Feher, F. J.; Newman, D. A.; Walzer, J. F. J. Am. Chem. Soc. 1989, 111, 1741. Feher, F. J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689. Feher, F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618. Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886. Feher, F. J.; Blanski, R. L. Organometallics 1993, 12, 958. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239 and references therein.
34. Feher, F. J.; Newman, D. A.; Walzer, J. F. J. Am. Chem. Soc. 1989, 111, 1741. Feher, F. J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689. Feher, F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618. Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886. Feher, F. J.; Blanski, R. L. Organometallics 1993, 12, 958. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239 and references therein.
35. Feher, F. J.; Newman, D. A.; Walzer, J. F. J. Am. Chem. Soc. 1989, 111, 1741. Feher, F. J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689. Feher, F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618. Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886. Feher, F. J.; Blanski, R. L. Organometallics 1993, 12, 958. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239 and references therein.
36. Feher, F. J.; Newman, D. A.; Walzer, J. F. J. Am. Chem. Soc. 1989, 111, 1741. Feher, F. J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689. Feher, F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618. Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886. Feher, F. J.; Blanski, R. L. Organometallics 1993, 12, 958. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239 and references therein.
37. Feher, F. J.; Newman, D. A.; Walzer, J. F. J. Am. Chem. Soc. 1989, 111, 1741. Feher, F. J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689. Feher, F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618. Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886. Feher, F. J.; Blanski, R. L. Organometallics 1993, 12, 958. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239 and references therein.
38. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
39. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
40. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
41. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
42. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
43. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
44. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
45. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
46. For related molecular approaches to oxo-surfaces binding organometallic functionalities see: Chisholm, M. H. Chemtracts-Inorg. Chem. 1992, 4, 273. Klaui, W. Angew. Chem., Int. Ed. Engl. 1990xe229, 627. Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239. Nagata, T.; Pohl, M.; Weiner, H.; Finke, R. G. Inorg. Chem. 1997, 36, 1366. Pohl, M.; Lyon, D. K.; Mizuno, N.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1995, 34, 1413. Corker, J.; Lefebvre, F.; Lecuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 277, 966. Niccolai, G. P.; Basset, J.-M. Appl. Catal., A 1996, 146, 145. Vidai, V.; Theolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595. Mechanisms of Reactions of Organometallic Compounds with Surfaces; Cole-Hamilton, D. J., Williams, J. O., Eds.; Plenum: New York, 1989.
47. Arduini, A.; Casnati, A. In Macrocycle Synthesis; Parker, O., Ed.; Oxford University Press: New York, 1996; Chapter 7.
48. Manzer, L. E. Inorg. Synth. 1982, 21, 135.
49. Lawton, S. L.; Jacobson, R. A. TRACER (a cell reduction program); Ames Laboratory, Iowa State University of Science and Technology: Ames, IA, 1965.
50. Lehmann, M. S.; Larsen, F. K. Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 1974, A30, 580-584.
51. Wilson, A. J. C. Nature 1942, 150, 151.
52. Ugozzoli, F. Comput. Chem. 1987, 11, 109.
53. North, A. C. T.; Phillips, D. C.; Mathews, F. S. Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 1968, A24, 351.
54. (a) International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1974; Vol. IV, p 99.
55. (b) Ibid. p 149.
56. Stewart, R. F.; Davidson, E. R.; Simpson, W. T. J. Chem. Phys. 1965, 42, 3175.
57. Sheldrick, G. M. SHELX76. Program for crystal structure determination. University of Cambridge: England, 1976.
58. Sheldrick, G. M. SHELXL92. Program for Crystal Structure Refinement. University of Göttingen: Göttingen, Germany, 1992.
59. See paragraph at the end regarding Supporting Information.
60. Zanotti-Gerosa, A.; Solari, E.; Giannini, L.; Floriani, C.; Re, N.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chim. Acta 1998, 270, 298.
61. Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802 and 1794. Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1811. Jacoby, D.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Chem. Soc., Chem. Commun. 1991, 790. Rosset, J.-M.; Floriani, C.; Mazzanti, M.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1990, 29, 3991.
62. Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802 and 1794. Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1811. Jacoby, D.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Chem. Soc., Chem. Commun. 1991, 790. Rosset, J.-M.; Floriani, C.; Mazzanti, M.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1990, 29, 3991.
63. Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802 and 1794. Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1811. Jacoby, D.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Chem. Soc., Chem. Commun. 1991, 790. Rosset, J.-M.; Floriani, C.; Mazzanti, M.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1990, 29, 3991.
64. Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802 and 1794. Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1811. Jacoby, D.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Chem. Soc., Chem. Commun. 1991, 790. Rosset, J.-M.; Floriani, C.; Mazzanti, M.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1990, 29, 3991.
65. Durfee, L. D.; Rothwell, I. P. Chem. Rev. 1988, 88, 1059 and references therein.
66. Andreetti, G. D.; Ugozzoli, F. In Calixarenes, A Versabile Class of Macrocyclic Compounds; Vicens, J., Böhmer, V., Eds.; Kluwer: Dordrecht, The Netherlands, 1991; pp 88-122.
67. Hoffmann, R.; Lipscomb, W. N. J. Chem. Phys. 1962, 36, 2179. Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.
68. Hoffmann, R.; Lipscomb, W. N. J. Chem. Phys. 1962, 36, 2179. Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.
69. Poli, R. Chem. Rev. 1996, 96, 2135.
70. A preliminary X-ray analysis confirmed the structure proposed for 14.