Borato-cyclopentadienyl half-sandwich complexes. Crystal structures of [NEt4][C5H5B(C6F5) 3]·CH2Cl2 and [NEt4]2[{C5H4B(C6F 5)3}Zr(μ-Cl)Cl2]2

Organometallics

Volumn 17, Issue 18, 1998, Pages 3829-3831

  Lancaster, Simon J ^a   Thornton Pett, Mark ^a   Dawson, David M ^a   Bochmann, Manfred ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001498297     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980395j     Document Type: Article

References (25)

1. Bochmann, M.; Lancaster, S. J.; Robinson, O. B. J. Chem. Soc., Chem. Commun. 1995, 2081.
2. Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255. Kaminsky, W. J. Chem. Soc., Dalton Trans. 1998, 1413.
3. Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255. Kaminsky, W. J. Chem. Soc., Dalton Trans. 1998, 1413.
4. Ruwwe, J.; Erker, G.; Fröhlich, R. Angew. Chem., Int. Ed. Engl. 1996, 35, 80. For related zwitterionic complexes see: Song, X.; Bochmann, M. J. Organomet. Chem. 1997, 545-546, 597. Sun, Y.; Spence, R. E. v. H.; Piers, W. E.; Parvez, M.; Yap, G. P. A. J. Am. Chem. Soc. 1997, 119, 5132. Piers, W. E. Chem. Eur. J. 1998, 4, 13.
5. Ruwwe, J.; Erker, G.; Fröhlich, R. Angew. Chem., Int. Ed. Engl. 1996, 35, 80. For related zwitterionic complexes see: Song, X.; Bochmann, M. J. Organomet. Chem. 1997, 545-546, 597. Sun, Y.; Spence, R. E. v. H.; Piers, W. E.; Parvez, M.; Yap, G. P. A. J. Am. Chem. Soc. 1997, 119, 5132. Piers, W. E. Chem. Eur. J. 1998, 4, 13.
6. Ruwwe, J.; Erker, G.; Fröhlich, R. Angew. Chem., Int. Ed. Engl. 1996, 35, 80. For related zwitterionic complexes see: Song, X.; Bochmann, M. J. Organomet. Chem. 1997, 545-546, 597. Sun, Y.; Spence, R. E. v. H.; Piers, W. E.; Parvez, M.; Yap, G. P. A. J. Am. Chem. Soc. 1997, 119, 5132. Piers, W. E. Chem. Eur. J. 1998, 4, 13.
7. Ruwwe, J.; Erker, G.; Fröhlich, R. Angew. Chem., Int. Ed. Engl. 1996, 35, 80. For related zwitterionic complexes see: Song, X.; Bochmann, M. J. Organomet. Chem. 1997, 545-546, 597. Sun, Y.; Spence, R. E. v. H.; Piers, W. E.; Parvez, M.; Yap, G. P. A. J. Am. Chem. Soc. 1997, 119, 5132. Piers, W. E. Chem. Eur. J. 1998, 4, 13.
8. Shafiq, F. A.; Abboud, K. A.; Richardson, D. E.; Boncella, J. M. Organometallics 1998, 17, 982.
9. 15N: C, 48.5; H, 3.4; N, 1.8. Found: C, 49.1; H, 3.5; N, 1.5. For spectroscopic details and the synthesis of 1b see the Supporting Information.
10. 3, Z = 4, F(000) = 1600, 5391 independent reflections, final R1 = 0.0428, wR2 = 0.1110 (I > 2σ(I)). The structure was solved by direct methods.
11. Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. Diamond, G. M.; Rodewald, S.; Jordan, R. F. Organometallics 1995, 14, 5. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4030. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045. Christopher, J. N.; Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4038.
12. Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. Diamond, G. M.; Rodewald, S.; Jordan, R. F. Organometallics 1995, 14, 5. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4030. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045. Christopher, J. N.; Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4038.
13. Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. Diamond, G. M.; Rodewald, S.; Jordan, R. F. Organometallics 1995, 14, 5. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4030. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045. Christopher, J. N.; Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4038.
14. Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. Diamond, G. M.; Rodewald, S.; Jordan, R. F. Organometallics 1995, 14, 5. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4030. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045. Christopher, J. N.; Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4038.
15. Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. Diamond, G. M.; Rodewald, S.; Jordan, R. F. Organometallics 1995, 14, 5. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4030. Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045. Christopher, J. N.; Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4038.
16. FF = 20.3 Hz, m-F).
17. 3, Z = 2, F(000) = 1960, 12 925 independent reflections, final R1 = 0.0374, wR2 = 0.0986 (I > 2σ(I)). The structure was solved by Patterson methods.
18. (a) Jiménez Pindado, G.; Thornton-Pett, M.; Bowkamp, M., Meetsma, A.; Hessen, B.; Bochmann, M. Angew. Chem. 1997, 109, 2457; Angew. Chem., Int. Ed. Engl. 1997, 36, 2358.
19. (a) Jiménez Pindado, G.; Thornton-Pett, M.; Bowkamp, M., Meetsma, A.; Hessen, B.; Bochmann, M. Angew. Chem. 1997, 109, 2457; Angew. Chem., Int. Ed. Engl. 1997, 36, 2358.
20. (b) Jiménez Pindado, G.; Thornton-Pett, M.; Bochmann, M. J. Chem. Soc., Dalton Trans. 1997, 3115.
21. (a) Temme, B.; Erker, G.; Karl, J.; Luftmann, R.; Fröhlich, R.; Kotila, S. Angew. Chem. 1995, 107, 1867; Angew. Chem., Int. Ed. Engl. 1995, 34, 1755.
22. (a) Temme, B.; Erker, G.; Karl, J.; Luftmann, R.; Fröhlich, R.; Kotila, S. Angew. Chem. 1995, 107, 1867; Angew. Chem., Int. Ed. Engl. 1995, 34, 1755.
23. (b) Karl, J.; Erker, G.; Fröhlich, R. J. Am. Chem. Soc. 1997, 119, 11165.
24. 2, 20°C): δ -14.07.
25. Duchateau, R.; Lancaster, S. J.; Thornton-Pett, M.; Bochmann, M. Organometallics 1997, 16, 4995.