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Volumn 19, Issue 3, 1998, Pages 276-278

Epoxidation of Olefins by a Water-Soluble Iron(III) Porphyrin Complex and Hydroperoxides in Aqueous Solution

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Indexed keywords


EID: 0001280454     PISSN: 02532964     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (7)

References (38)
  • 4
    • 0002801757 scopus 로고
    • Valentine, J. S.; Foote, C. S.; Greenberg, A.; Liebman, J. F., Eds.; Blackie Academic & Professional, Chapman & Hall: London
    • (a) Traylor, T. G.; Traylor, P. S. In Active Oxygen in Biochemistry; Valentine, J. S.; Foote, C. S.; Greenberg, A.; Liebman, J. F., Eds.; Blackie Academic & Professional, Chapman & Hall: London, 1995; pp 84-187.
    • (1995) Active Oxygen in Biochemistry , pp. 84-187
    • Traylor, T.G.1    Traylor, P.S.2
  • 7
    • 0011697055 scopus 로고
    • (d) Meunier, B. Chem. Rev. 1992, 92, 1411-1456.
    • (1992) Chem. Rev. , vol.92 , pp. 1411-1456
    • Meunier, B.1
  • 21
    • 0542386139 scopus 로고    scopus 로고
    • Fe(TDFPPS) was obtained from Mid-Century Chemical
    • Fe(TDFPPS) was obtained from Mid-Century Chemical.
  • 22
    • 0542409717 scopus 로고    scopus 로고
    • note
    • 5, respectively) was added to a reaction solution containing Fe(TDCPPS) (0.04 mM) and CBZ (1 mM, introduced as a 0.1 M solution in methanol) in buffered aqueous solution (5 mL). Reactions at pH 2-3 were performed in formate buffer (0.1 M), at pH 4-5 in acetate buffer (0.1 M), and at pH 6-7 in phosphate (0.1 M), and the pH of the reaction solutions was adjusted by adding either HCl (3 N) or NaOH (3 N) solutions whenever it was necessary. The reaction mixture was stirred in air for 30 min at 25 °C, and then analyzed by Orom Vintage 2000 HPLC equipped with a variable wavelength UV-200 detector. CBZ and its epoxide derivative were separated on Waters Symmetry C18 column, 5 μM, eluted by a mixture of methanol/water, 60:40 (v/v), with retention times of 4.8 and 3.5 min, respectively. Detection was made at 215 nm. Calculation of the conversions of CBZ and the yields of CBZ-10,11- oxide was determined on the corresponding calibration curves of CBZ and the authentic CBZ-10,11-oxide prepared by a literature method. See ref 6 for the preparation of CBZ-10,11-oxide as an authentic sample.
  • 30
    • 0542386137 scopus 로고    scopus 로고
    • note
    • 18O.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.