Total synthesis of (+)-calyculin a and (-)-calyculin B

Journal of Organic Chemistry

Volumn 63, Issue 22, 1998, Pages 7596-7597

  Smith III, Amos B ^a   Friestad, Gregory K ^a   Duan, James J W ^a   Barbosa, Joseph ^a   Hull, Kenneth G ^a   Iwashima, Makoto ^a   Qiu, Yuping ^a   Grant Spoors, P ^a   Bertounesque, Emmanuel ^a   Salvatore, Brian A ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001279402     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo981813x     Document Type: Article

References (37)

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14. At the start of our work, the absolute stereochemistry was unknown.
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37. D for natural 2 is +15° (c 0.07, EtOH). We also thank Professor David Evans (Harvard University) for an authentic sample of synthetic (+)-1.