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Volumn 18, Issue 4, 1999, Pages 606-618

Metal-porphyrinogen organometallic chemistry: The intramolecular reactivity of η2-acyls bonded to titanium(IV) -meso-octaethyl mono(pyridine)-tris(pyrrole) and to vanadium(III)-meso-octaethyl bis(pyridine)-bis(pyrrole) macrocycle

(6) Crescenzi, Raffaella a Solari, Euro a Floriani, Carlo a Re, Nazzareno b Chiesi Villa, Angiola c Rizzoli, Corrado c

a UNIVERSITY OF LAUSANNE (Switzerland)

b UNIVERSITY OF CHIETI (Italy)

c UNIVERSITY OF PARMA (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001176570 PISSN: 02767333 EISSN: None Source Type: Journal
DOI: 10.1021/om980888o Document Type: Article

Times cited : (17)

References (109)

1
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- note
- For leading references on organometallic chemistry based on macrocyclic ligands see refs 2-4.

2
- 85045808722
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
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- Goedken, V.L.¹ Ladd, J.A.²

3
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- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1982) J. Chem. Soc., Chem. Commun. , pp. 142

4
- 33746330901
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1987) Angew. Chem., Int. Ed. Engl. , vol.26 , pp. 70
- Floriani, C.¹ Ciurli, S.² Chiesi-Villa, A.³ Guastini, C.⁴

5
- 6244289473
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1992) Inorg. Chem. , vol.31 , pp. 96
- Solan, E.¹ De Angelis, S.² Floriani, C.³ Chiesi-Villa, A.⁴ Rizzoli, C.⁵

6
- 0039039234
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1992) Inorg. Chem. , vol.31 , pp. 2520
- De Angelia, S.¹ Solari, E.² Gallo, E.³ Floriani, C.⁴ Chiesi-Villa, A.⁵ Rizzoli, C.⁶

7
- 33748226412
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 2204
- Giannini, L.¹ Solari, E.² Floriani, C.³ Chiesi-Villa, A.⁴ Rizzoli, C.⁵

8
- 0001312097
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1995) J. Am. Chem. Soc. , vol.117 , pp. 6801
- Giannini, L.¹ Solari, E.² De Angelis, S.³ Ward, T.R.⁴ Floriani, C.⁵ Chiesi-Villa, A.⁶ Rizzoli, C.⁷

9
- 0029344739
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1995) Organometallics , vol.14 , pp. 3539
- Black, D.G.¹ Swenson, D.C.² Jordan, R.F.³

10
- 0001914231
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1996) Chem. Commun. , pp. 1835
- Blake, A.J.¹ Mountford, P.² Nikonov, G.I.³ Swallow, D.⁴

11
- 0006829256
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1996) Inorg. Chem. , vol.35 , pp. 1808
- Schumann, H.¹

12
- 0001027517
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1997) Inorg. Chem. , vol.36 , pp. 1107
- Nikonov, G.I.¹ Blake, A.J.² Mountford, P.³

13
- 0000309067
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
- (1997) Inorg. Chem. , vol.36 , pp. 103
- Black, D.G.¹ Jordan, R.F.² Rogers, R.D.³

14
- 0000419140
- For tmtaa [dibenzotetramethyltetraaza[14]annulene], see: (a) Goedken, V. L.; Ladd, J. A. J. Chem. Soc., Chem. Commun. 1981, 910; 1982, 142. (b) Floriani, C.; Ciurli, S.; Chiesi-Villa, A.; Guastini, C. Angew. Chem., Int. Ed. Engl. 1987, 26, 70. (c) Solan, E.; De Angelis, S.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 96. (d) De Angelia, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1992, 31, 2520. (e) Giannini, L.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Angew. Chem., Int. Ed. Engl. 1994, 33, 2204. (f) Giannini, L.; Solari, E.; De Angelis, S.; Ward, T. R.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. J. Am. Chem. Soc. 1995, 117, 6801. (g) Black, D. G.; Swenson, D. C.; Jordan, R. F. Organometallics 1995, 14, 3539. (h) Blake, A. J.; Mountford, P.; Nikonov, G. I.; Swallow, D. Chem. Commun. 1996, 1835. (i) Schumann, H. Inorg. Chem. 1996, 35, 1808. (j) Nikonov, G. I.; Blake, A. J.; Mountford, P. Inorg. Chem. 1997, 36, 1107. (k) Black, D. G.; Jordan, R. F.; Rogers, R. D. Inorg. Chem. 1997, 36, 103. (l) Martin, A.; Uhrhammer, R.; Gardner, T. G.; Jordan, R. F. Organometallics 1998, 17, 382. (m) Mountford, P. Chem. Soc. Rev. 1998, 27, 105.
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- Martin, A.¹ Uhrhammer, R.² Gardner, T.G.³ Jordan, R.F.⁴

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25
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26
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27
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28
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29
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30
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31
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32
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