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Volumn 12, Issue 25, 1996, Pages 6065-6073

Polymeric self-assembled monolayers. 5. Synthesis and characterization of ω-functionalized, self-assembled diacetylenic and polydiacetylenic monolayers

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Indexed keywords


EID: 0001120159     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la960810h     Document Type: Article
Times cited : (70)

References (67)
  • 17
    • 4243166987 scopus 로고
    • Bloor. D. Chance. R., Eds.; Nijhoff: Dordrecht, The Netherlands
    • Lando. J. B. In Palydiocetylenes, Bloor. D. Chance. R., Eds.; Nijhoff: Dordrecht, The Netherlands. 1985.
    • (1985) Palydiocetylenes
    • Lando, J.B.1
  • 50
    • 4243123026 scopus 로고    scopus 로고
    • note
    • In ref 3 we estimated the length of DA-COOH and PDA-COOH molecules to be 30 and 28 A, respectively, but using computer modeling methods (InsightII, Biosym), we have refined these values slightly. The correct lengths of all-trans, extended DA-COOH and PDA-COOH are 32 and 30 A, respectively.
  • 55
    • 4243166986 scopus 로고    scopus 로고
    • note
    • -1 higher than we reported previously for MUA (see refs 48, 49, and 56). This apparent discrepancy arises from a structural change that occurs during aging of the films. In previous studies we always measured the IR spectrum immediately after forming the SAM, but all the acid-terminated films discussed here were aged for periods of up to 2 days prior to spectral acquisition. The shift in the mehylene bands in the acid-terminated SAMs (only) upon aging is a fully reproducible effect and probably reflects relaxation of the hydrocarbon chains.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.