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Volumn 63, Issue 13, 1998, Pages 4291-4298

Ruthenium-Catalyzed Polycyclization Reactions

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Indexed keywords


EID: 0001117364     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo972279g     Document Type: Article
Times cited : (99)

References (36)
  • 4
  • 14
    • 0030992869 scopus 로고    scopus 로고
    • and references therein
    • Recent examples of RCM of α,ω-dienes: (a) Grubbs, R. H.; Chang, S. B. Tetrahedron 1997, 38, 4757-4760 and references therein, (b) General RCM: Grubbs, R. H.; Miller, S. J.; Fu, G. C. Acc. Chem. Res. 1995, 28, 446-452 and references therein. General olefin metathesis: Ivin, K. J.; Mol, J. C. Olefin Metathesis and Metathesis Polymerization; Academic: San Diego, 1997.
    • (1997) Tetrahedron , vol.38 , pp. 4757-4760
    • Grubbs, R.H.1    Chang, S.B.2
  • 15
    • 1542763298 scopus 로고
    • and references therein
    • Recent examples of RCM of α,ω-dienes: (a) Grubbs, R. H.; Chang, S. B. Tetrahedron 1997, 38, 4757-4760 and references therein, (b) General RCM: Grubbs, R. H.; Miller, S. J.; Fu, G. C. Acc. Chem. Res. 1995, 28, 446-452 and references therein. General olefin metathesis: Ivin, K. J.; Mol, J. C. Olefin Metathesis and Metathesis Polymerization; Academic: San Diego, 1997.
    • (1995) Acc. Chem. Res. , vol.28 , pp. 446-452
    • Grubbs, R.H.1    Miller, S.J.2    Fu, G.C.3
  • 16
    • 0003985187 scopus 로고    scopus 로고
    • Academic: San Diego
    • Recent examples of RCM of α,ω-dienes: (a) Grubbs, R. H.; Chang, S. B. Tetrahedron 1997, 38, 4757-4760 and references therein, (b) General RCM: Grubbs, R. H.; Miller, S. J.; Fu, G. C. Acc. Chem. Res. 1995, 28, 446-452 and references therein. General olefin metathesis: Ivin, K. J.; Mol, J. C. Olefin Metathesis and Metathesis Polymerization; Academic: San Diego, 1997.
    • (1997) Olefin Metathesis and Metathesis Polymerization
    • Ivin, K.J.1    Mol, J.C.2
  • 17
    • 0001623127 scopus 로고    scopus 로고
    • A cascade of diene RCM reactions was employed in the quantitative RCM of poly(1,2-butadiene) to produce a cyclopentene-based polymer. Coates, G. W.; Grubbs, R. H. J. Am. Chem. Soc. 1996, 118, 230-231
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 230-231
    • Coates, G.W.1    Grubbs, R.H.2
  • 20
    • 85034476576 scopus 로고    scopus 로고
    • Propargyl chloride 3, rather than the tosylate, was isolated from the reaction of 2 with tosyl chloride
    • Propargyl chloride 3, rather than the tosylate, was isolated from the reaction of 2 with tosyl chloride.
  • 27
    • 85034467017 scopus 로고    scopus 로고
    • note
    • Compounds 4 and 5 have been protected as trialkylsilyl ethers. Cyclization proceeds without this protection, but the reaction rate is slowed dramatically, possibly due to intramolecular chelation.
  • 28
    • 85034475716 scopus 로고    scopus 로고
    • note
    • The extra substituent on the disubstituted olefin is employed to increase the relative rate of metathesis at the monosubstituted "productive" olefln. When the reaction is conducted with an acyclic precursor containing two monosubstituted olefins, product formation is observed at a slower rate and to a lesser extent.
  • 29
    • 33845379363 scopus 로고
    • A related process involving carbene-acetylene metathesis, enyne metathesis ring-closure, has been reported utilizing tungsten and ruthenium carbene complexes, (a) Katz, T. J.; Sivavec, T. M. J. Am. Chem. Soc. 1985, 107, 737. (b) Kinoshita, A.; Mori, M. Synlett 1994, 1020. (c) Kinoshita, A.; Mori, M. J. Org. Chem. 1996, 61, 8356. Similarly, carbene-acetylene metathesis allows for the recently reported rearrangement-cyclization of triynes to produce aromatics, an example of which is shown, (d) Peters, J. U.; Blechert, S. Chem. Commun. 1997, 1983.
    • (1985) J. Am. Chem. Soc. , vol.107 , pp. 737
  • 30
    • 33845379363 scopus 로고
    • A related process involving carbene-acetylene metathesis, enyne metathesis ring-closure, has been reported utilizing tungsten and ruthenium carbene complexes, (a) Katz, T. J.; Sivavec, T. M. J. Am. Chem. Soc. 1985, 107, 737. (b) Kinoshita, A.; Mori, M. Synlett 1994, 1020. (c) Kinoshita, A.; Mori, M. J. Org. Chem. 1996, 61, 8356. Similarly, carbene-acetylene metathesis allows for the recently reported rearrangement-cyclization of triynes to produce aromatics, an example of which is shown, (d) Peters, J. U.; Blechert, S. Chem. Commun. 1997, 1983.
    • (1994) Synlett , vol.1020
    • Kinoshita, A.1    Mori, M.2
  • 31
    • 0029956640 scopus 로고    scopus 로고
    • A related process involving carbene-acetylene metathesis, enyne metathesis ring-closure, has been reported utilizing tungsten and ruthenium carbene complexes, (a) Katz, T. J.; Sivavec, T. M. J. Am. Chem. Soc. 1985, 107, 737. (b) Kinoshita, A.; Mori, M. Synlett 1994, 1020. (c) Kinoshita, A.; Mori, M. J. Org. Chem. 1996, 61, 8356. Similarly, carbene-acetylene metathesis allows for the recently reported rearrangement-cyclization of triynes to produce aromatics, an example of which is shown, (d) Peters, J. U.; Blechert, S. Chem. Commun. 1997, 1983.
    • (1996) J. Org. Chem. , vol.61 , pp. 8356
    • Kinoshita, A.1    Mori, M.2
  • 32
    • 0002869555 scopus 로고    scopus 로고
    • A related process involving carbene-acetylene metathesis, enyne metathesis ring-closure, has been reported utilizing tungsten and ruthenium carbene complexes, (a) Katz, T. J.; Sivavec, T. M. J. Am. Chem. Soc. 1985, 107, 737. (b) Kinoshita, A.; Mori, M. Synlett 1994, 1020. (c) Kinoshita, A.; Mori, M. J. Org. Chem. 1996, 61, 8356. Similarly, carbene-acetylene metathesis allows for the recently reported rearrangement-cyclization of triynes to produce aromatics, an example of which is shown, (d) Peters, J. U.; Blechert, S. Chem. Commun. 1997, 1983.
    • (1997) Chem. Commun. , pp. 1983
    • Peters, J.U.1    Blechert, S.2
  • 33
    • 85034468341 scopus 로고    scopus 로고
    • note
    • Although olefin substitution results only in a 4% increase in yield of 31 (Table 2, entries 1 and 2), the workup is greatly simplified due to the absence of difficult to separate impurities.


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