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26844476617
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note
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Josh Kehoe, Ryan Petersen, and Charles Johnson were the unfortunate souls to have gotten stuck with all the variations towards 8b. I gratefully acknowledge their many efforts.
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37
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26844546104
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note
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Robert Schneidmiller of Professor David Johnson's laboratory at Oregon has kindly provided us with all of the needed DSC results over the last 2+ years.
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26844447047
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note
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Adam Matzger, the talented graduate student who prepared 19, joined Peter's group just as I left for Oregon; thus, I was unaware of the projects Peter had him exploring.
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(a) Polydiacetylenes, Bloor, D.; Chance, R. R. (Eds.); Martinus Nijhoff: Boston, 1985, and references therein.
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The first edition of reference 17a contained the preparation of the parent molecule, but stated that the diyne proved to be very unstable. Other groups have reported similar problems using free phenylbutadiynes in synthesis; see: Godt, A. J. Org. Chem. 1997, 62, 7471.
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note
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Work on macrocycles 23 and 24 is currently in progress by Stephen Brand.
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Semi-empirical calculations (AM1, PM3) were performed on a SGI workstation using Spartan molecular modelling software (Version 4.1.1).
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