Multiply charged redox-active oligomers in the gas phase: Electrolytic electrospray ionization mass spectrometry of metallocenes

Journal of Physical Chemistry B

Volumn 102, Issue 49, 1998, Pages 10078-10086

  McCarley, Tracy Donovan ^a   Lufaso, Michael W ^b   Curtin, Larry S ^b   McCarley, Robin L ^a  

^a LOUISIANA STATE UNIVERSITY   (United States)

^b YOUNGSTOWN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001027144     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9838700     Document Type: Article

References (59)

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55. -A/v] where A is a constant that depends on the masstransport characteristics of the analyte and dimensions of the electrospray needle.
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59. From a statistical point of view, the hexamer and the octamer can be treated as a trimer and a tetramer, respectively, for the first electrontransfer event. That is to say that the population of a given charge state for the first electron-transfer event will not be affected by the presence of the other ferrocene sites that will be oxidized at a higher potential. Thus, the charge state populations were calculated for 5 and 6 using eq 8 with n = 3 and 4, respectively.