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11b suggested the nucleic acid bases form most stable H-bonding at nonplanner structures. But energy improvement by nonplanarity is very small. So we adopt the planar structure as simplified models
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11b suggested the nucleic acid bases form most stable H-bonding at nonplanner structures. But energy improvement by nonplanarity is very small. So we adopt the planar structure as simplified models.
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The dihedral angles of these substituents are 0° (on plane) except for Ph (ca. 45°) and Pf (ca. 60°). See Supporting Information (Tables 2 and 4) for the details
-
The dihedral angles of these substituents are 0° (on plane) except for Ph (ca. 45°) and Pf (ca. 60°). See Supporting Information (Tables 2 and 4) for the details.
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See Supporting Information (Table 1) for the details.
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See Supporting Information (Table 5) for the details.
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See Supporting Information (Table 2) for the details.
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Considerations based on frontier molecular orbital theory are not so good to explain the substitution effect on hydrogen bonding. See Supporting Information
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Considerations based on frontier molecular orbital theory are not so good to explain the substitution effect on hydrogen bonding. See Supporting Information.
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