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Volumn , Issue 21, 1999, Pages 3105-3110

Asymmetric synthesis of β-lactams and pseudopeptides via stereoselective conjugate additions of lithium (a-methylbenzyl)allylamide to ct,β-unsaturated iron acyl complexes

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EID: 0000850938     PISSN: 0300922X     EISSN: None     Source Type: Journal    
DOI: 10.1039/a906633k     Document Type: Article
Times cited : (25)

References (51)
  • 47
    • 0002902307 scopus 로고    scopus 로고
    • 1964, 2, 15; S. Quinn and A. Shaver, Inorg. Chim. Acta, 1980,38, 243.
    • R. B. King and M. Bisnette, J. Organomet. Chem., 1964, 2, 15; S. Quinn and A. Shaver, Inorg. Chim. Acta, 1980,38, 243.
    • J. Organomet. Chem.
    • King, R.B.1    Bisnette, M.2
  • 48
    • 33746444519 scopus 로고    scopus 로고
    • note
    • The diastereomeric ratios of the adducts were determined by integration of the cyclopentadienyl ring singlets in the 500 MHz 'H NMR spectra. For complexes 5a and 6a, the adducts were unambiguously synthesized via the non-stereoselective conjugate addition of (Ä)-a-methylbenzylamine to complex 3a, followed by Chromatographie separation and A'-allylation. Complexes 3b and 3c did not undergo conjugate addition of (7?)-a-methylbenzyIamine.


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