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Volumn 3, Issue 22, 2001, Pages 3587-3590

Catalytic asymmetric allylic C-H activation as a surrogate of the asymmetric Claisen rearrangement

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ARTICLE;

EID: 0000835722     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0167255     Document Type: Article
Times cited : (72)

References (33)
  • 7
    • 0001758253 scopus 로고
    • For representative examples of intermolecular C-H insertions, see: (a) Scott, L. T.; DeCicco, G. J. J. Am. Chem. Soc. 1974, 96, 322.
    • (1974) J. Am. Chem. Soc. , vol.96 , pp. 322
    • Scott, L.T.1    DeCicco, G.J.2
  • 15
    • 0347716924 scopus 로고    scopus 로고
    • Aryldiazoacetates and vinyldiazoacetates have been used as carbenoid precursors in asymmetric intermolecular C-H insertions. Other diazo compounds that generate chemoselective donor/acceptor substituted carbenoids are alkynyldiazoacetates and heteroaryldiazoacetates. For a general review, see: Davies, H. M. L.: Antoulinakis, E. G. J. Organomet. Chem. 2001, 617-618, 47
    • (2001) J. Organomet. Chem. , vol.617-618 , pp. 47
    • Davies, H.M.L.1    Antoulinakis, E.G.2
  • 21
    • 0000217402 scopus 로고
    • Trost, B. M., Ed.; Pergamon Press: Oxford
    • For a review, see: (a) Wipf, P. In Comprehensive Organic Synthesis; Trost, B. M., Ed.; Pergamon Press: Oxford, 1991; Vol. 5, pp 827-874.
    • (1991) Comprehensive Organic Synthesis , vol.5 , pp. 827-874
    • Wipf, P.1
  • 31
    • 0042728146 scopus 로고    scopus 로고
    • The absolute configuration of 4 was determined to be (R) by comparison to a known sample (see ref 12b). The absolute configuration of the other C-H insertion products is assigned by analogy.
    • The absolute configuration of 4 was determined to be (R) by comparison to a known sample (see ref 12b). The absolute configuration of the other C-H insertion products is assigned by analogy.
  • 32
    • 0035971991 scopus 로고    scopus 로고
    • Relative stereochemistry is readily achived on the basis of distinctive chemical shifts in the proton NMR. For details, see: Davies, H. M. L.; Ren, P. Tetrahedron Lett. 2001, 42, 3149.
    • (2001) Tetrahedron Lett. , vol.42 , pp. 3149
    • Davies, H.M.L.1    Ren, P.2
  • 33
    • 0042227251 scopus 로고    scopus 로고
    • note
    • The determination of the relative and absolute stereochemistry for 16 and 17 is described in detail in Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.