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1542782503
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note
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4g,15 has established that CT excitation of the EDA complex effects the transfer of an electron from the donor to the acceptor in less than 500 fs.
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36
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33947448345
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45
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1542677198
-
-
note
-
CC) on the picosecond time scale cannot be readily extracted. For a discussion of this problem in the context of peroxide decomposition, see ref 9.
-
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46
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37049131494
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Barnett, J. R.; Hopkins, A. S.; Ledwith, A. J. Chem. Soc., Perkin Trans. 2 1973, 80.
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0013166428
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56
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15844415139
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-
See Bockman, T. M.; Hubig, S. M.; Kochi, J. K. J. Am. Chem. Soc. 1996, 118, 4502 for a preliminary report of these results.
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57
-
-
1542677162
-
-
note
-
24b methylviologen triflate showed no interfering CT bands between anion and cation.
-
-
-
-
62
-
-
1542677163
-
-
note
-
-1. See ref 24b.]
-
-
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63
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0001565451
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Hayon, E.; Ibata, T.; Lichtin, N. N.; Simic, M. J. Phys. Chem. 1972, 76, 2072.
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64
-
-
1542467628
-
-
note
-
29b was unnecessary,
-
-
-
-
65
-
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0008761906
-
-
(b) Sharma, D. K.; Yip, R. W.; Williams, D. F.; Sugamori, S. E.; Bradley, L. L. T. Chem. Phys. Lett. 1976, 41, 460
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Sharma, D.K.1
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-
66
-
-
1542782462
-
-
note
-
exc > 370 nm). The experiment thus was carried out with the frequency-tripled output of a 25-ps mode-locked Nd:YAG laser.
-
-
-
-
67
-
-
1542677164
-
-
note
-
max = 650 nm, due to intermolecular association, would be too weak to be observed with our apparatus.
-
-
-
-
69
-
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0001198357
-
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(a) Johnston, L. J.; Lougnot, D. L.; Wintgens, V. Scaiano, J. C. J. Am. Chem. Soc. 1988, 110, 518.
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71
-
-
1542782463
-
-
note
-
28
-
-
-
-
72
-
-
37049122205
-
-
See also: (b) Davidson, R. S.; Santhanam, M. J. Chem. Soc., Perkin Trans. 2 1972, 2355 for its spectrum in various nonaqueous solvents. (c) For the spectrum of the triethylsilyl-substituted analogue, see: Chatgilialoglu, C.; Ingold, K. U.; Scaiano, J. C. J. Am. Chem. Soc. 1982, 104, 5119.
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Davidson, R.S.1
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73
-
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33845554944
-
-
See also: (b) Davidson, R. S.; Santhanam, M. J. Chem. Soc., Perkin Trans. 2 1972, 2355 for its spectrum in various nonaqueous solvents. (c) For the spectrum of the triethylsilyl-substituted analogue, see: Chatgilialoglu, C.; Ingold, K. U.; Scaiano, J. C. J. Am. Chem. Soc. 1982, 104, 5119.
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Chatgilialoglu, C.1
Ingold, K.U.2
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-
74
-
-
1542572176
-
-
In accord with the Mulliken formulation of the charge-transfer transition in ref 13
-
In accord with the Mulliken formulation of the charge-transfer transition in ref 13.
-
-
-
-
75
-
-
0000651332
-
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Bookman, T. M.; Karpinski, Z. J.; Sankararaman, S.; Kochi, J. K. J. Am. Chem. Soc. 1992, 114, 1970.
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Bookman, T.M.1
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77
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1842358783
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(b) Chattopadhyay, S. K.; Kumar, C. V.; Das, P. K. J. Photochem. 1985, 30, 81.
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Chattopadhyay, S.K.1
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78
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1542782460
-
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(c) Hurley, J. K.; Sinai, N.; Linshitz, H. Photochem. Photobiol. 1983, 38, 1.
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Hurley, J.K.1
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79
-
-
1542467630
-
-
note
-
2+ and tetramethoxybenzilate was an exception, and the orange solution remained unchanged in color even after prolonged irradiation.
-
-
-
-
80
-
-
37049091471
-
-
Heller, H. G.; Langan, J. R. J. Chem. Soc., Perkin Trans. 2 1981, 341. See also: Kuhn, H. J.; Braslavsky, S. E.; Schmidt, R. Pure Appl. Chem. 1989, 61, 187.
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Heller, H.G.1
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81
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0347750708
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Heller, H. G.; Langan, J. R. J. Chem. Soc., Perkin Trans. 2 1981, 341. See also: Kuhn, H. J.; Braslavsky, S. E.; Schmidt, R. Pure Appl. Chem. 1989, 61, 187.
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Kuhn, H.J.1
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Schmidt, R.3
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82
-
-
1542467629
-
-
Scaiano, J. C., ed; CRC Press: Boca Raton, FL
-
Eaton, D. R., in CRC Handbook of Photochemistry, Vol 1; Scaiano, J. C., ed; CRC Press: Boca Raton, FL, 1989, p. 1233.
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-
-
Eaton, D.R.1
-
83
-
-
1542677165
-
-
note
-
.+ absorbed more than 90% of the incident actinic light and the reaction effectively ceased.]
-
-
-
-
86
-
-
84945031851
-
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Kalyanasundaram, K.; Kiwi, J.; Grätzel, M. Helv. Chim. Acta 1978, 61, 2720.
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Kalyanasundaram, K.1
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89
-
-
1542677167
-
-
note
-
(b) Ketyl radicals are electron rich by virtue of their very low oxidation potentials and ease of oxidation in solution.
-
-
-
-
90
-
-
0000950074
-
-
See: (c) Baumann, H.; Merckel, C.; Timpe, H.-J.; Graness, A.; Kleinschmidt, J.; Gould, I. R.; Turro, N. J. Chem. Phys. Lett. 1984, 103, 497. (d) Kemp, T. J.; Martins, L. J. A. J. Chem. Soc., Perkin Trans. 2 1980, 1708. (e) Engel, P. S.; Wu, W. X. J. Am. Chem. Soc. 1989, 111, 1830.
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Baumann, H.1
Merckel, C.2
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Graness, A.4
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Gould, I.R.6
Turro, N.J.7
-
91
-
-
37049108203
-
-
See: (c) Baumann, H.; Merckel, C.; Timpe, H.-J.; Graness, A.; Kleinschmidt, J.; Gould, I. R.; Turro, N. J. Chem. Phys. Lett. 1984, 103, 497. (d) Kemp, T. J.; Martins, L. J. A. J. Chem. Soc., Perkin Trans. 2 1980, 1708. (e) Engel, P. S.; Wu, W. X. J. Am. Chem. Soc. 1989, 111, 1830.
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Kemp, T.J.1
Martins, L.J.A.2
-
92
-
-
0011167467
-
-
See: (c) Baumann, H.; Merckel, C.; Timpe, H.-J.; Graness, A.; Kleinschmidt, J.; Gould, I. R.; Turro, N. J. Chem. Phys. Lett. 1984, 103, 497. (d) Kemp, T. J.; Martins, L. J. A. J. Chem. Soc., Perkin Trans. 2 1980, 1708. (e) Engel, P. S.; Wu, W. X. J. Am. Chem. Soc. 1989, 111, 1830.
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-
-
Engel, P.S.1
Wu, W.X.2
-
93
-
-
0000652281
-
-
The escape of the benziloxy radicals out of the solvent cage is not included in the femtosecond kinetics, since it occurs on much slower time scales. See: Scott, T. W.; Liu, S. N. J. Phys. Chem. 1989, 93, 1393.
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-
-
Scott, T.W.1
Liu, S.N.2
-
94
-
-
1542782466
-
-
note
-
.+, arylacetoxy] radical pairs.
-
-
-
-
96
-
-
0027605450
-
-
Asaki, M. T.; Huang, C.-P.; Garvey, D.; Zhou, J.; Kapteyn, H. C.; Murnane, M. M. Opt. Lett. 1993, 18, 977.
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Asaki, M.T.1
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Kapteyn, H.C.5
Murnane, M.M.6
-
98
-
-
1542572174
-
-
Calculated by means of the Eyring equation in ref 49
-
Calculated by means of the Eyring equation in ref 49.
-
-
-
-
102
-
-
1542467633
-
-
note
-
-1) results in a similar (though less pronounced) effect (see Table 5).
-
-
-
-
103
-
-
1542677166
-
-
note
-
56
-
-
-
-
104
-
-
1542467634
-
-
note
-
CT < 360 nm and thus could not be excited with the Ti:sapphire laser.
-
-
-
-
105
-
-
0002415957
-
-
(a) Schlag, E. W.; Sehneider, S.; Fischer, S. Ann. Rev. Phys. Chem. 1971, 22, 465.
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-
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Schlag, E.W.1
Sehneider, S.2
Fischer, S.3
-
107
-
-
1542782465
-
-
note
-
11c Alternatively, the rate of the clock reaction used by these authors (decarboxylation of the 9-methylfluorenecarboxyl radical) may be somewhat overestimated. (See footnote 20 in ref 9.)
-
-
-
-
108
-
-
1542467638
-
-
note
-
+ = -1.73 for the back-electron transfer.
-
-
-
-
109
-
-
0041548540
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1542467637
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note
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(a) It is remarkable that the competing processes of back-electron transfer and carbon-carbon bond cleavage are completely independent and the rate of one process is not affected by the presence of the other.
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125
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note
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64
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Elemental analyses were performed by Atlantic Microlabs, Norcross, GA
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Elemental analyses were performed by Atlantic Microlabs, Norcross, GA.
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Ware, W. R., Ed.; Dekker: New York
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De Mayo, P.1
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