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(a) The slight slope of the linear fit (β = 0.2) is negligible compared to the error limits (±20%) of the kinetic measurements, (b) In the case of benzene/TCNB complexes (see entry a in Chart I), the data were operationally fitted to a straight line, although some curvature in the data points was apparent (see Figure 5).
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52 etc., have been introduced, each indicative of a particular theoretical perspective. Accordingly, we choose ξ as an unbiased (operational) designation to avoid confinement to a particular theoretical viewpoint.
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•-, or of any other species) was observed. The lifetime of the photoexcited TCNE was evidently too short ( < 100 ps) to be diffusionally quenched by donors even when they were present at high (ca. 1 M) concentrations.
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•- with that of the biphenyl cation radical in the picosecond transient spectra observed upon excitation of the EDA complex of TCNB with biphenyl. For the extinction coefficient of biphenyl cation radical, see ref 7a. For the photoexcitation of the biphenyl/TCNB complex in acetonitrile see ref 37b.
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