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Solid samples of different compositions can be prepared by recrystallization from different solvents. Thus, for example, the orange solid (brown for complex 3) which spontaneously precipitates in the preparation of the complexes (see Experimental Section) has the following a;a′ composition imolar ratio): 1, >98:<2; 2, 48:52; 3, >98: <2; 4, >98:<2; 5, >98:<2; 6, 50:50. Error limits on each integer are estimated as ±2.
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Unpublished results
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6] was prepared as described for the related indium analogues 1-6 and epimerizes at rhodium in refluxing methanol: Carmona, D.; Lahoz, F. J.; Elipe, S.; Oro, L. A.; Lamata, M. P.; Viguri, F.; García-Correas, R.; Vega, C.; Cativiela, C.; López-Ram de Víu, M. P. Unpublished results.
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85034283446
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Complexes 7, 8, and 10 contained variable amounts of water of crystallization, as inferred from their IR spectra
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Complexes 7, 8, and 10 contained variable amounts of water of crystallization, as inferred from their IR spectra.
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74
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