Intriguing Coordination Behaviors of Aquo and Amine Ligands Bound to the Organoruthenium(II) Cation [Ru(η6-C6H6)(bpop)]2+ (bpop = 2,2-Bis[4(R)-phenyl-1,3-oxazolon-2-yl]propane)

Inorganic Chemistry

Volumn 35, Issue 20, 1996, Pages 5760-5761

  Asano, Hideo ^a   Katayama, Kyoshige ^a   Kurosawa, Hideo ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000468969     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960410h     Document Type: Article

References (21)

1. (a) Maitlis, P. M. Chem. Soc. Rev. 1981, 10, 1.
2. (b) Consiglio, G.; Morandini, F. Chem. Rev. 1987, 87, 761.
3. (c) Bozec, H. L.; Touchard, D.; Dixneuf, P. H. Adv. Organomet. Chem. 1989, 29, 163.
4. (d) Bennett, M. A.; Khan, K.; Wenger, E. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, U.K., 1995; Chapters 7.8 and 7.9, pp 473-602.
5. (e) Faller, J. W.; Smart, C. J. Tetrahedron Lett. 1989, 30, 1189.
6. (f) Derien, S.; Dixneuf, P. H. J. Chem. Soc., Chem. Commun. 1994, 2551.
7. (g) Trost, B. M. Angew, Chem., Int. Ed. Engl. 1995, 34, 259.
8. (h) Chaudret, B. Bull. Soc. Chim. Fr. 1995, 132, 268.
9. 2+ complexes, see: (a) Stebler-Röthlisberger, M.; Hummel, W.; Pittet, P.-A.; Bürgi, H.-B.; Ludi, A.; Merbach, A. E. Inorg. Chem. 1988, 27, 1358. (b) Karlen, T.; Hauser, A.; Ludi, A. Inorg. Chem. 1994, 33, 2213. (c) Dadci, L.; Elias, H.; Frey, U.; Hörnig, A.; Koelle, U.; Merbach, A. E.; Paulus, H.; Schneider. J. S. Inorg. Chem. 1995, 34, 306.
10. 2+ complexes, see: (a) Stebler-Röthlisberger, M.; Hummel, W.; Pittet, P.-A.; Bürgi, H.-B.; Ludi, A.; Merbach, A. E. Inorg. Chem. 1988, 27, 1358. (b) Karlen, T.; Hauser, A.; Ludi, A. Inorg. Chem. 1994, 33, 2213. (c) Dadci, L.; Elias, H.; Frey, U.; Hörnig, A.; Koelle, U.; Merbach, A. E.; Paulus, H.; Schneider. J. S. Inorg. Chem. 1995, 34, 306.
11. 2+ complexes, see: (a) Stebler-Röthlisberger, M.; Hummel, W.; Pittet, P.-A.; Bürgi, H.-B.; Ludi, A.; Merbach, A. E. Inorg. Chem. 1988, 27, 1358. (b) Karlen, T.; Hauser, A.; Ludi, A. Inorg. Chem. 1994, 33, 2213. (c) Dadci, L.; Elias, H.; Frey, U.; Hörnig, A.; Koelle, U.; Merbach, A. E.; Paulus, H.; Schneider. J. S. Inorg. Chem. 1995, 34, 306.
12. 4. For detailed preparation procedures for all complexes, see the Supporting Information.
13. w = 0.055.
14. 0 is the instrument frequency and Δδ is the difference in chemical shifts for the coalescing pair of peaks. See the Supporting Information.
15. w = 0.100.
16. 3OD] = 24.6 M.
17. 6), 5.82 (dd, J = 4.0, 9.8 Hz, 1H). 7.33-7.50 (m, 10H, 2 × Ph).
18. (a) Carroll, J. M.; Norton, J. R. J. Am. Chem. Soc. 1992, 114, 8744.
19. (b) Kramarz, K. W.; Norton, J. R. Prog. Inorg. Chem. 1994, 42, 1.
20. (c) La, T.; Miskelly, G. M. J. Am. Chem. Soc. 1995, 117, 3613.
21. Darensbourg, M. Y. Prog. Inorg. Chem. 1985, 33, 221.