1H NMR study of the conformation of metallapentacycles N - C - C - O - M [M = Rh(III) and Ir(III)] resulting in a Karplus-type relationship for vicinal H-C(sp3)-N(sp3)-H coupling constants

Magnetic Resonance in Chemistry

Volumn 34, Issue 1, 1996, Pages 42-46

  Jimeno, M Luisa ^a   Elguero, José ^a   Carmona, Daniel ^b   Lamata, M Pilar ^b   San José, Emilio ^b  

^a INSTITUTO DE QUÍMICA MÉDICA   (Spain)

^b UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

1H NMR; 1H,1H vicinal coupling constants; Aminoacidate complexes; Conformational analysis; Five membered metallacycles; Karplus type relationship; NMR

Indexed keywords

IRIDIUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RHODIUM COMPOUNDS;

1H NMR; 1H,1H VICINAL COUPLING CONSTANT; AMINOACIDATE COMPLEX; CONFORMATIONAL ANALYSIS; FIVE-MEMBERED METALLACYCLE; GLYCINATE; KARPLUS-TYPE RELATIONSHIP; METALLACYCLES; NMR STUDIES; VICINAL COUPLING CONSTANTS;

CONFORMATIONS;

EID: 0030559764     PISSN: 07491581     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-458X(199601)34:1<42::AID-OMR827>3.0.CO;2-9     Document Type: Article

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