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Volumn 3, Issue 20, 2001, Pages 3075-3078

A dendritic active site: Catalysis of the Henry reaction

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE;

EID: 0000746859     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol016197x     Document Type: Article
Times cited : (45)

References (44)
  • 28
    • 0035804426 scopus 로고    scopus 로고
    • For a recent review of the nitroaldol (Henry) reaction see: Luzzio, F. A. Tetrahedron 2001, 57, 915-945.
    • (2001) Tetrahedron , vol.57 , pp. 915-945
    • Luzzio, F.A.1
  • 32
    • 0041872365 scopus 로고
    • U.S. Patent 4,289,872, assigned to Allied Corp.
    • For a discussion of some properties and the synthesis of these L-lysine branches, see: (a) Denkewalter, R. G.; Kolc, J.; Lukasavage, W. J. U.S. Patent 4,289,872, 1981, assigned to Allied Corp.
    • (1981)
    • Denkewalter, R.G.1    Kolc, J.2    Lukasavage, W.J.3
  • 38
    • 0042874440 scopus 로고    scopus 로고
    • note
    • 2+, 100) [appropriate isotope peaks for these main peaks were also observed at half mass unit intervals].
  • 39
    • 0001524276 scopus 로고    scopus 로고
    • The crude mixture obtained from the reaction was consistent with being a mixture of syn/anti products and a little unreacted aldehyde. For full characterization data of the nitro alcohol products, see: Ballini, R.; Bosica, G. J. Org. Chem. 1997, 62, 425-427.
    • (1997) J. Org. Chem. , vol.62 , pp. 425-427
    • Ballini, R.1    Bosica, G.2
  • 40
    • 0042874441 scopus 로고    scopus 로고
    • note
    • The capacity of these chiral dendritic catalysts to generate ee's was not investigated on this occasion.


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