메뉴 건너뛰기




Volumn 18, Issue 19, 1999, Pages 3778-3780

Synthesis and Structure of [Ni{Ga-C(SiMe3)3}4] and Quantum-Chemical Verification of Strong π Back-Bonding in the Model Compounds [Ni(EMe)4] (E = B, Al, Ga, In, Tl)

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0000664923     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990417h     Document Type: Article
Times cited : (87)

References (43)
  • 2
    • 33747569885 scopus 로고
    • (a) Dohmeier, C.; Robl, C.; Tacke, M.; Schnöckel, H. Angew. Chem. 1991, 103, 594; Angew. Chem., Int. Ed. Engl. 1991, 30, 564.
    • (1991) Angew. Chem., Int. Ed. Engl. , vol.30 , pp. 564
  • 5
    • 0032479726 scopus 로고    scopus 로고
    • (c) Schnitter, C.; Roesky, H. W.; Röpken, C.; Herbst-Irmer, R.; Schmidt, H.-G.; Noltemeyer, M. Angew. Chem. 1998, 110, 2059; Angew. Chem., Int. Ed. 1998, 37, 1952.
    • (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 1952
  • 7
    • 33745168627 scopus 로고
    • Uhl, W.; Hiller, W.; Layh, M.; Schwarz, W. Angew. Chem. 1992, 104, 1378; Angew. Chem., Int. Ed. Engl. 1992, 31, 1364.
    • (1992) Angew. Chem., Int. Ed. Engl. , vol.31 , pp. 1364
  • 16
    • 0031980690 scopus 로고    scopus 로고
    • Uhl, W.; Pohlmann, M.; Wartchow, R. Angew. Chem. 1998, 110, 1007; Angew. Chem., Int. Ed. 1998, 37, 961.
    • (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 961
  • 18
    • 0003876666 scopus 로고    scopus 로고
    • Weiss, J.; Stetzkamp, D.; Nuber, B.; Fischer, R. A.; Boehme, C.; Frenking, G. Angew. Chem. 1997, 109, 95; Angew. Chem., Int. Ed. Engl. 1997, 36, 70.
    • (1997) Angew. Chem., Int. Ed. Engl. , vol.36 , pp. 70
  • 20
    • 0041507988 scopus 로고    scopus 로고
    • note
    • +, in accordance with a calculated isotope pattern.
  • 21
    • 0043010774 scopus 로고    scopus 로고
    • note
    • 3. The cyclopentane molecules are located on special positions and are strongly disordered; their atoms were refined isotropically, and hydrogen atoms were not considered.
  • 24
    • 0042509769 scopus 로고    scopus 로고
    • note
    • 19
  • 32
    • 6144226868 scopus 로고
    • (a) The CDA (charge decomposition analysis) decomposes the wave function or the Kohn-Sham determinant of a complex [ML] in terms of fragment orbitals of the chosen ligand L and the metal fragment [M]. The [M]←L donation d is then given by the mixing of the occupied orbitals of L and vacant orbitals of [M]. The [M]→L back-donation b is given by the mixing of the occupied orbitals of [M] and vacant orbitals of L. Mixing of occupied orbitals of both fragments gives the repulsive polarization r: Dapprich, S.; Frenking, G. J. Phys. Chem. 1995, 99, 9352.
    • (1995) J. Phys. Chem. , vol.99 , pp. 9352
    • Dapprich, S.1    Frenking, G.2
  • 34
    • 0042008971 scopus 로고
    • Phillips-Universität Marburg
    • The CDA calculations were carried out with the program CDA 2.1: Dapprich, S.; Frenking, G. Phillips-Universität Marburg, 1994. The program is freely available: ftp.chemie.uni-marburg.de/pub/cda.
    • (1994)
    • Dapprich, S.1    Frenking, G.2
  • 39
    • 0032484178 scopus 로고    scopus 로고
    • Braunschweig, H.; Kollann, C.; Englert, U. Angew. Chem. 1998, 110, 3355; Angew. Chem., Int. Ed. 1998, 37, 3177.
    • (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 3177


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.