Cycloheptyne-cobalt complexes via allylation of stabilized γ-carbonyl cations

Chemical Communications

Volumn , Issue 16, 1998, Pages 1751-1752

  Green, James R ^a  

^a UNIVERSITY OF WINDSOR   (Canada)

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EID: 0000607857     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a803316a     Document Type: Article

References (25)

1. A. Krebs and J. Wilke, Top. Curr. Chem., 1983, 109, 189;
2. H. Meier, Adv. Strain Org. Chem., 1991, 1, 215.
3. M. J. Went, Adv. Organomet. Chem., 1997, 41, 69.
4. The stabilization of other strained alkynes also has been accomplished by complexation to the hexacarbonyldicobalt unit; see Y. Rubin, C. B. Knobler and F. Diederich, J. Am. Chem. Soc., 1990, 112, 4966;
5. M. H. Haley and B. L. Langsdorf, Chem. Commun., 1997, 1121.
6. R. S. Dickson and P. J. Fraser, Adv. Organomet. Chem., 1974, 12, 323.
7. A. J. M. Caffyn and K. M. Nicholas, in Comprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, ed. L. S. Hegedus, Pergamon, Oxford, 1995, vol. 12, ch. 7.1;
8. K. M. Nicholas, Acc. Chem. Res., 1987, 20, 207.
9. N. E. Schore, in Comprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, ed. L. S. Hegedus, Pergamon, Oxford, 1995, vol. 12, ch. 7.2;
10. N. E. Schore, Org. React., 1991, 40, 1;
11. N. E. Schore, in Comprehensive Organic Synthesis, ed. B. M. Trost, ed. L. A. Paquette, Pergamon, Oxford, 1991, vol. 5, ch. 9.1;
12. N. E. Schore, Chem. Rev., 1988, 88, 1081.
13. S. L. Schreiber, M. T. Klimas and T. Sammakia, J. Am. Chem. Soc., 1986, 108, 3128;
14. T. Nakamura, T. Matsui, K. Tanino and I. Kuwajima, J. Org. Chem., 1997, 62, 3032.
15. N. E. Schore and S. D. Najdi, J. Org. Chem., 1987, 52, 5296;
16. M. Isobe, C. Yenjai and S. Tanaka, Synlett, 1994, 916;
17. S. Hosokawa and M. Isobe, Synlett, 1995, 1179.
18. S. Takano, T. Sugihara and K. Ogasawara, Synlett, 1992, 70.
19. C. S. Vizniowski, J. R. Green, T. L. Breen and A. V. Dalacu, J. Org. Chem., 1995, 60, 7496.
20. G. E. Keck and D. R. Romer, J. Org. Chem., 1993, 58, 6083.
21. M. Pereyre, J.-P. Quintard and A. Rahm, Tin in Organic Synthesis, Butterworths, London, 1987, pp. 216-218;
22. A. Yanagisawa, A. Ishiba, H. Nakashima and H. Yamamoto, Synlett, 1997, 88.
23. P. A. Jacobi, S. C. Buddhu, D. Fry and S. Rajeswari, J. Org. Chem., 1997, 62, 2894.
24. Prepared in 90% yield, as adapted from the procedure of J. M. Muchowski, R. Naef and M. L. Maddox, Tetrahedron Lett., 1985, 26, 5375.
25. Prepared in 60% yield by the stannylation of 2-chloromethyl-3-trimethylsilylprop-1-ene according to S. Chandrasekhar, S. Latour, J. D. Wuest and B. Zacharie, J. Org. Chem., 1983, 48, 3810.