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Although doublets are involved, the coalescence temperature could be reasonably well-established because of the relatively large difference in the chemical shift between the diastereotopic orthoprotons in this case.
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4c,d and (ii) no reaction was observed for diphenylacetylene, which is known to insert into Pd-C bonds, see: (a) Beydoun, N.; Pfeffer, M.; DeCian, A.; Fischer, J. Organometallics 1991, 10, 3693. (b) Vicente, J.; Saura-Llamas, I.; Ramirez de Arellano, M. C. J. Chem. Soc., Dalton Trans. 1995, 2529.
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(1995)
J. Chem. Soc., Dalton Trans.
, pp. 2529
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Vicente, J.1
Saura-Llamas, I.2
Ramirez De Arellano, M.C.3
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94
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0001296078
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One must bear in mind that E / Z-isomerizations of dienyl fragments in σ-dienylpalladium compounds have been reported, see: Ryabov, A. D.; van Eldik, R.; Le Borgne, G.; Pfeffer, M. Organometallics 1993, 12, 1386.
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(1993)
Organometallics
, vol.12
, pp. 1386
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Ryabov, A.D.1
Van Eldik, R.2
Le Borgne, G.3
Pfeffer, M.4
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