-
8
-
-
0001017304
-
-
E. R. Th. Kerstel, K. K. Lehmann, T. F. Mentel, B. H. Pate, and G. Scoles, J. Phys. Chem. 95, 8282 (1991).
-
(1991)
J. Phys. Chem.
, vol.95
, pp. 8282
-
-
Kerstel, E.R.Th.1
Lehmann, K.K.2
Mentel, T.F.3
Pate, B.H.4
Scoles, G.5
-
12
-
-
0006863240
-
-
D. Green, R. Holmberg, C. Y. Lee, D. A. McWhorter, and B. H. Pate, J. Chem. Phys. 109, 4407 (1998).
-
(1998)
J. Chem. Phys.
, vol.109
, pp. 4407
-
-
Green, D.1
Holmberg, R.2
Lee, C.Y.3
McWhorter, D.A.4
Pate, B.H.5
-
14
-
-
0033593152
-
-
preceding paper
-
B. H. Pate, J. Chem. Phys. 110, 1990 (1999), preceding paper.
-
(1999)
J. Chem. Phys.
, vol.110
, pp. 1990
-
-
Pate, B.H.1
-
16
-
-
33645975958
-
-
M. Perttila, J. Murto, A. Kivinen, and K. Turunen, Spectrochim. Acta A 34, 9 (1978).
-
(1978)
Spectrochim. Acta A
, vol.34
, pp. 9
-
-
Perttila, M.1
Murto, J.2
Kivinen, A.3
Turunen, K.4
-
17
-
-
85025720975
-
-
J. Pourcin, G. Davidovics, H. Bodot, L. Abouaf-Marguin, and B. Gauthier-Roy, Chem. Phys. Lett. 74, 147 (1980).
-
(1980)
Chem. Phys. Lett.
, vol.74
, pp. 147
-
-
Pourcin, J.1
Davidovics, G.2
Bodot, H.3
Abouaf-Marguin, L.4
Gauthier-Roy, B.5
-
19
-
-
0000388548
-
-
J. Pourcin, M. Monnier, P. Verlaque, G. Davidovics, R. Lauricella, C. Colonna, and H. Bodot, J. Mol. Spectrosc. 109, 186 (1985).
-
(1985)
J. Mol. Spectrosc.
, vol.109
, pp. 186
-
-
Pourcin, J.1
Monnier, M.2
Verlaque, P.3
Davidovics, G.4
Lauricella, R.5
Colonna, C.6
Bodot, H.7
-
26
-
-
0033593151
-
-
first paper in this series
-
D. Green, S. Hammond, J. Keske, and B. H. Pate, J. Chem. Phys. 110, 1979 (1999), first paper in this series.
-
(1999)
J. Chem. Phys.
, vol.110
, pp. 1979
-
-
Green, D.1
Hammond, S.2
Keske, J.3
Pate, B.H.4
-
33
-
-
0039951502
-
-
E. R. Th. Kerstel, K. K. Lehmann, J. E. Gambogi, X. Yang, and G. Scoles, J. Chem. Phys. 99, 8559 (1993).
-
(1993)
J. Chem. Phys.
, vol.99
, pp. 8559
-
-
Kerstel, E.R.Th.1
Lehmann, K.K.2
Gambogi, J.E.3
Yang, X.4
Scoles, G.5
-
36
-
-
0006827793
-
-
C. C. Miller, L. A. Philips, A. M. Andrews, G. T. Fraser, B. H. Pate, and R. D. Suenram, J. Chem. Phys. 100, 831 (1994).
-
(1994)
J. Chem. Phys.
, vol.100
, pp. 831
-
-
Miller, C.C.1
Philips, L.A.2
Andrews, A.M.3
Fraser, G.T.4
Pate, B.H.5
Suenram, R.D.6
-
37
-
-
21844493515
-
-
A. Ainetschian, G. T. Fraser, B. H. Pate, and R. D. Suenram, Chem. Phys. 190, 231 (1995).
-
(1995)
Chem. Phys.
, vol.190
, pp. 231
-
-
Ainetschian, A.1
Fraser, G.T.2
Pate, B.H.3
Suenram, R.D.4
-
40
-
-
0000004107
-
-
S. Cupp, C. Y. Lee, D. A. McWhorter, and B. H. Pate, J. Chem. Phys. 109, 4302 (1998).
-
(1998)
J. Chem. Phys.
, vol.109
, pp. 4302
-
-
Cupp, S.1
Lee, C.Y.2
McWhorter, D.A.3
Pate, B.H.4
-
41
-
-
36549094188
-
-
There are not enough collisions in the molecular beam expansion to relax out the higher energy conformers, producing sufficient population of these conformers for rotational studies; R. S. Ruoff, T. D. Klots, T. Emilsson, and H. S. Gutowsky, J. Chem. Phys. 93, 3142 (1990).
-
(1990)
J. Chem. Phys.
, vol.93
, pp. 3142
-
-
Ruoff, R.S.1
Klots, T.D.2
Emilsson, T.3
Gutowsky, H.S.4
-
43
-
-
85034549380
-
-
note
-
j-dependence of the transition moment is small for low J transitions.
-
-
-
-
44
-
-
85034546699
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-
note
-
The double-resonance signal is estimated via a calculation of the decrease in infrared signal intensity as a function of the position of two dressed states with a given interaction matrix coupling element. In Fig. 4(a), the relative frequency position of 0 MHz corresponds to the resonance condition of the two dressed states (see Fig. 2) and thus reflects the position of greatest double-resonance signal modulation.
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-
-
-
45
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-
85034537167
-
-
note
-
We note that our instrumental double-resonance linewidth (6 MHz) is less than the predicted value for a 5 MHz infrared linewidth (9 MHz). The infrared linewidth results from residual Doppler broadening in the collimated molecular beam. This lower measured line width suggests that the double-resonance measurements achieve a small sub-Doppler linewidth reduction.
-
-
-
-
47
-
-
0001932636
-
-
J. R. Durig, P. Klaeboe, G. A. Guirgis, L. Wang, and J. Liu, Z. Phys. Chem. I 191, 23 (1995).
-
(1995)
Z. Phys. Chem. I
, vol.191
, pp. 23
-
-
Durig, J.R.1
Klaeboe, P.2
Guirgis, G.A.3
Wang, L.4
Liu, J.5
-
48
-
-
0040197444
-
-
This view of the dynamics is similar to the picture used to discuss the vibrational dynamics of weakly bound molecular complexes; G. T. Fraser, J. Chem. Phys. 90, 2097 (1989).
-
(1989)
J. Chem. Phys.
, vol.90
, pp. 2097
-
-
Fraser, G.T.1
-
49
-
-
0008990093
-
-
The vibrational spectroscopy of molecules with torsional motions is similar to the spectroscopy of weakly bound molecular complexes. However, for single molecules, direct transitions to higher torsional states in the vibrational excited state are typically not observed. In contrast, direct excitation of high-frequency/low-frequency combination bands has been observed for weakly bound complexes, although only with very high sensitivity methods; C. M. Lovejoy and D. J. Nesbitt, Chem. Phys. Lett. 146, 582 (1988).
-
(1988)
Chem. Phys. Lett.
, vol.146
, pp. 582
-
-
Lovejoy, C.M.1
Nesbitt, D.J.2
-
51
-
-
0010922186
-
-
Gaussian, Inc., Pittsburgh, Pennsylvania
-
GAUSSIAN 94 (Revision D.I), M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. A. Keith, G. A. Petersson, J. A. Montgomery, K. Ragavachari, M. A. Al-Laham, V. G. Kakrzewski, J. V. Ortiz, J. B. Foresman, J. Cioslowski, B. B. Stefanov, A. Nanayakkara, M. Challacombe, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andres, E. S. Replogle, R. Gomperts, R. L. Martin, D. J. Fox, J. S. Binkley, D. J. Defrees, J. Baker, J. P. Stewart, M. Head-Gordon, C. Gonzales, and J. A. Pople, Gaussian, Inc., Pittsburgh, Pennsylvania, 1995.
-
(1995)
GAUSSIAN 94 (Revision D.I)
-
-
Frisch, M.J.1
Trucks, G.W.2
Schlegel, H.B.3
Gill, P.M.W.4
Johnson, B.G.5
Robb, M.A.6
Cheeseman, J.R.7
Keith, T.A.8
Petersson, G.A.9
Montgomery, J.A.10
Ragavachari, K.11
Al-Laham, M.A.12
Kakrzewski, V.G.13
Ortiz, J.V.14
Foresman, J.B.15
Cioslowski, J.16
Stefanov, B.B.17
Nanayakkara, A.18
Challacombe, M.19
Peng, C.Y.20
Ayala, P.Y.21
Chen, W.22
Wong, M.W.23
Andres, J.L.24
Replogle, E.S.25
Gomperts, R.26
Martin, R.L.27
Fox, D.J.28
Binkley, J.S.29
Defrees, D.J.30
Baker, J.31
Stewart, J.P.32
Head-Gordon, M.33
Gonzales, C.34
Pople, J.A.35
more..
-
52
-
-
0002199283
-
-
edited by J. R. Durig Elsevier, Amsterdam
-
J. K. G. Watson, Vibrational Spectra and Structure, edited by J. R. Durig (Elsevier, Amsterdam, 1978), Vol. 6, pp. 1-89.
-
(1978)
Vibrational Spectra and Structure
, vol.6
, pp. 1-89
-
-
Watson, J.K.G.1
-
53
-
-
85034555177
-
-
private communication
-
The rotational spectrum was fit using the program developed by A. G. Maki at the NIST (private communication).
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NIST
-
-
Maki, A.G.1
-
55
-
-
0001279018
-
-
J. D. Lewis, T. B. Malloy, T. H. Chao, and J. Laane, J. Mol. Struct. 12, 427 (1972).
-
(1972)
J. Mol. Struct.
, vol.12
, pp. 427
-
-
Lewis, J.D.1
Malloy, T.B.2
Chao, T.H.3
Laane, J.4
-
56
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-
85034529812
-
-
note
-
-1. This provides the justification for the estimate in this spectrum.
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-
-
-
57
-
-
85034549535
-
-
note
-
-1 (at J = 2).
-
-
-
-
58
-
-
0348164015
-
-
Wiley, New York
-
C. Cohen-Tanoudji, B. Diu, and F. Laloe, Quantum Mechanics (Wiley, New York, 1977), Vol. 2, pp. 1299-1301.
-
(1977)
Quantum Mechanics
, vol.2
, pp. 1299-1301
-
-
Cohen-Tanoudji, C.1
Diu, B.2
Laloe, F.3
-
59
-
-
0003549646
-
-
Wiley, New York, Appendix 9
-
H. Günther, NMR Spectroscopy: Basic Principles, Concepts, and Applications in Chemistry (Wiley, New York, 1995), Appendix 9, pp. 529-531.
-
(1995)
NMR Spectroscopy: Basic Principles, Concepts, and Applications in Chemistry
, pp. 529-531
-
-
Günther, H.1
-
60
-
-
85034563951
-
-
Ph.D. thesis, University of Virginia, August
-
Details of the spectral simulations can be found in D. A. McWhorter, Ph.D. thesis, University of Virginia, August 1998.
-
(1998)
-
-
McWhorter, D.A.1
-
69
-
-
0348164027
-
-
J. Kommandeur, W. A. Majewski, W. L. Meerts, and D. W. Pratt, Annu. Rev. Phys. Chem. 38, 443 (1987).
-
(1987)
Annu. Rev. Phys. Chem.
, vol.38
, pp. 443
-
-
Kommandeur, J.1
Majewski, W.A.2
Meerts, W.L.3
Pratt, D.W.4
-
70
-
-
0000760241
-
-
J. K. Lundberg, R. W. Field, C. D. Sherrill, E. T. Seidl, Y. Xie, and H. F. Schaefer III, J. Chem. Phys. 98, 8384 (1993).
-
(1993)
J. Chem. Phys.
, vol.98
, pp. 8384
-
-
Lundberg, J.K.1
Field, R.W.2
Sherrill, C.D.3
Seidl, E.T.4
Xie, Y.5
Schaefer H.F. III6
-
71
-
-
0027579543
-
-
M. A. Suhm, J. T. Farrel Jr., S. H. Ashworth, and D. J. Nesbitt, J. Chem. Phys. 98, 5985 (1993).
-
(1993)
J. Chem. Phys.
, vol.98
, pp. 5985
-
-
Suhm, M.A.1
Farrel J.T., Jr.2
Ashworth, S.H.3
Nesbitt, D.J.4
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