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Volumn 109, Issue 11, 1998, Pages 4316-4326

Intramolecular vibrational energy redistribution in the acetylenic C-H and hydroxyl stretches of propynol

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Indexed keywords


EID: 0001751778     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.477075     Document Type: Article
Times cited : (33)

References (51)
  • 22
    • 22244490930 scopus 로고    scopus 로고
    • (unpublished results). The dipole moment components of propynol were measured using the molecular Stark effect on a Fourier transform microwave (FTMW) spectrometer at NIST, Gaithersburg. Additional high frequency microwave transitions were measured using a Stark cell spectrometer
    • F. J. Lovas, R. D. Suenram, M. Y. Tretyakov, G. T. Fraser, and B. H. Pate (unpublished results). The dipole moment components of propynol were measured using the molecular Stark effect on a Fourier transform microwave (FTMW) spectrometer at NIST, Gaithersburg. Additional high frequency microwave transitions were measured using a Stark cell spectrometer.
    • Lovas, F.J.1    Suenram, R.D.2    Tretyakov, M.Y.3    Fraser, G.T.4    Pate, B.H.5
  • 24
    • 22244468288 scopus 로고    scopus 로고
    • See AIP Document No. E-PAPS: E-JCPSA6-109-018835* for a complete listing of transition frequencies and intensities of the acetylenic CH and OH stretch spectra. E-PAPS document files may be retrieved free of charge from our FTP server (http://www.aip.org/epaps/epaps.html) or from ftp.aip.org in the directory /epaps/. For further information: e-mail: paps@aip.org or fax: 516-576-2223.
    • See AIP Document No. E-PAPS: E-JCPSA6-109-018835 for a complete listing of transition frequencies and intensities of the acetylenic CH and OH stretch spectra. E-PAPS document files may be retrieved free of charge from our FTP server (http://www.aip.org/epaps/epaps.html) or from ftp.aip.org in the directory /epaps/. For further information: e-mail: paps@aip.org or fax: 516-576-2223.
  • 25
    • 22244485954 scopus 로고    scopus 로고
    • Several separate microwave searches have been performed to identify transitions from a second conformer (expected to be the trans conformation). These measurements have used Stark cell spectrometers [Refs. 21, 22, and (private communication)], a FTMW spectrometer (Ref. 22), and the EROS. No transitions that can be assigned to a second conformation have been found
    • Several separate microwave searches have been performed to identify transitions from a second conformer (expected to be the trans conformation). These measurements have used Stark cell spectrometers [Refs. 21, 22, and J. C. Pearson (private communication)], a FTMW spectrometer (Ref. 22), and the EROS. No transitions that can be assigned to a second conformation have been found.
    • Pearson, J.C.1
  • 26
    • 22244451614 scopus 로고    scopus 로고
    • Many of the molecules previously studied by high-resolution molecular-beam spectroscopy do not meet the single bright-state criterion. In particular, the high barrier to methyl group internal rotation produces an overlapping spectrum of the noninteracting A and E symmetry states (Ref. 10)
    • Many of the molecules previously studied by high-resolution molecular-beam spectroscopy do not meet the single bright-state criterion. In particular, the high barrier to methyl group internal rotation produces an overlapping spectrum of the noninteracting A and E symmetry states (Ref. 10).
  • 32
    • 33645724878 scopus 로고
    • A lengthening of the effective Golden Rule decay rate by this type of level structure has been discussed previously;
    • A lengthening of the effective Golden Rule decay rate by this type of level structure has been discussed previously; G. A. Voth, J. Chem. Phys. 88, 5547 (1988).
    • (1988) J. Chem. Phys. , vol.88 , pp. 5547
    • Voth, G.A.1
  • 41
    • 0001600990 scopus 로고
    • More detailed modeling of the effects of Coriolis interactions are possible using the methods developed by Perry;
    • More detailed modeling of the effects of Coriolis interactions are possible using the methods developed by Perry; D. S. Perry, J. Chem. Phys. 98, 6665 (1993), and Ref. 15.
    • (1993) J. Chem. Phys. , vol.98 , pp. 6665
    • Perry, D.S.1
  • 44
    • 22244471622 scopus 로고    scopus 로고
    • In the prolate symmetric top limit, the K=0 states would only experience perpendicular Coriolis interactions. The rotational dependence of the perpendicular Coriolis interaction is used in the simulation (for the case where K=0)
    • In the prolate symmetric top limit, the K=0 states would only experience perpendicular Coriolis interactions. The rotational dependence of the perpendicular Coriolis interaction is used in the simulation (for the case where K=0);


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.