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Volumn 18, Issue 25, 1999, Pages 5264-5275

Propene polymerization with the isospecific, highly regiospecific rac-Me2C(3-t-Bu-1-Ind)2ZrCl2/MAO catalyst. 1. Influence of hydrogen on initiation and propagation: Experimental detection and theoretical investigation of 2,1 propene insertion into the Zr-H bond

Author keywords

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Indexed keywords


EID: 0000081472     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990488g     Document Type: Article
Times cited : (42)

References (83)
  • 38
    • 3743124680 scopus 로고    scopus 로고
    • PCT WO 98/43989
    • 2 ligand gave quite comparable results; for details, see: Resconi, L.; Balboni, D.; Dang, V. A.; Yu, L. C. PCT WO 98/43989. Resconi, L.; Balboni, D.; Baruzzi, G.; Fiori, C.; Guidotti, S. Submitted to Organometallics.
    • Resconi, L.1    Balboni, D.2    Dang, V.A.3    Yu, L.C.4
  • 46
    • 3743087841 scopus 로고    scopus 로고
    • note
    • 2 the angle between the mean planes of the five-membered rings is about 50°, for all the bridged ligands this value is more than 70°. Evidently, repulsive steric interactions in the unbridged catalysts disfavor the more electronically stable Zr(isopropyl) species.
  • 65
    • 0003744120 scopus 로고    scopus 로고
    • Vrije Universiteit Amsterdam: Amsterdam, The Netherlands
    • ADF 2.3.0; Vrije Universiteit Amsterdam: Amsterdam, The Netherlands, 1996.
    • (1996) ADF 2.3.0
  • 70
    • 0003990093 scopus 로고
    • Department of Theoretical Chemistry, Free University: Amsterdam, The Netherlands
    • Krijn, J.; Baerends, E. J. Fit Functions in the HFS Method; Department of Theoretical Chemistry, Free University: Amsterdam, The Netherlands, 1984.
    • (1984) Fit Functions in the HFS Method
    • Krijn, J.1    Baerends, E.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.