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3843050462
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note
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Molecular weights and polydispersities (GPC), however, were found to cover much narrower ranges, characteristic of each zirconocene, indicating that the variations in yield within a single set of reaction conditions (i.e., particular zirconocene with or without hydrogen) were due to variations in the amounts of actually active catalyst, and not to changes in the character of the reaction.
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24
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3843129868
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unpublished results
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(b) Forlini, F., unpublished results.
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Forlini, F.1
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31
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3843061471
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note
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10 Therefore, it may be that under our conditions the main factor governing the relative activities of V us VI, is simply an inverse relationship between activity and numbers of secondary insertions (Table 2). These same arguments may also explain the similar reversal of the relative activities of the pair of catalysts III and IV, on going from high monomer concentrations (refs 12 and 13) to our conditions of low concentration (Tables 1 and 2).
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33
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0030204302
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3843050463
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note
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9
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35
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3843094074
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2 and monomer for Zr-1,2 and Zr-2,1 sites, and therefore the amount by which this reckoning underestimates the Zr-1,2 sites, would vary from one metallocene to another.
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-
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38
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3843049341
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note
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The curves in Figure 1 were corrected for the rapid flow of propene into the reactor during equilibration of propene in solution in toluene (first 3-4 min) by subtracting from them the curve recorded for dissolution of propene in the absence of catalyst, under otherwise identical conditions.
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39
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