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This calculation is performed using the exact hard spheres scattering (EHSS) model
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Because of the upper limit of quadrupole mass spectrometer range equal to ∼4000 amu
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The collision integrals of all species are inversely correlated with buffer gas temperature. In calculations, this can be crudely accounted for via a temperature-dependent He collision radius
-
The collision integrals of all species are inversely correlated with buffer gas temperature. In calculations, this can be crudely accounted for via a temperature-dependent He collision radius 5859. When evaluating the cross sections for spheres at 78 and 378 K, we have adjusted R so that the values for the smallest (Formula presented) clusters, the mobilities of which are only weakly sensitive to geometry 2223, would match those found at 305 K. This has produced (Formula presented) at 78 K and 1.09 Å at 378 K (assuming the bulk density of β-tin).
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65
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For larger clusters, the values at 305 K appear to be slightly higher. It is not clear at this juncture if this carries any structural information. It might be due to a marginal thermal annealing
-
For larger clusters, the values at 305 K appear to be slightly higher. It is not clear at this juncture if this carries any structural information. It might be due to a marginal thermal annealing.
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