Mobilities of carbon cluster ions: Critical importance of the molecular attractive potential

Journal of Chemical Physics

Volumn 108, Issue 6, 1998, Pages 2416-2423

  Shvartsburg, Alexandre A ^a   Schatz, George C ^a   Jarrold, Martin F ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0006463761     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.475625     Document Type: Article

References (76)

1. D. F. Hagen, Anal. Chem. 51, 871 (1979).
2. R. H. St. Louis and H. H. Hill, Crit. Rev. Anal. Chem. 21, 321 (1990).
3. G. von Helden, M. T. Hsu, P. R. Kemper, and M. T. Bowers, J. Chem. Phys. 95, 3835 (1991).
4. G. von Helden, P. R. Kemper, N. G. Gotts, and M. T. Bowers, Science 259, 1300 (1993).
5. G. vin Helden, M. T. Hsu, N. G. Gotts, P. R. Kemper, and M. T. Bowers, Chem. Phys. Lett. 204, 15 (1993).
6. G. von Helden, M. T. Hsu, N. G. Gotts, and M. T. Bowers, J. Phys. Chem. 97, 8182 (1993).
7. G. von Helden, N. G. Gotts, W. E. Palke, M. T. Bowers, Int. J. Mass Spectrom. Ion Processes 138, 33 (1994).
8. N. G. Gotts, G. von Helden, and M. T. Bowers, Int. J. Mass Spectrom. Ion Processes 149/150, 217 (1995).
9. J. M. Hunter, J. L. Fye, and M. F. Jarrold, J. Chem. Phys. 99, 1785 (1993).
10. J. M. Hunter, J. L. Fye, and M. F. Jarrold, Science 260, 784 (1993).
11. J. M. Hunter, J. L. Fye, E. J. Roskamp, and M. F. Jarrold, J. Phys. Chem. 98, 1810 (1994).
12. J. M. Hunter, J. L. Fye, and M.F. Jarrold, J. Phys. Chem. 97, 3460 (1993).
13. K. B. Shelimov, J. M. Hunter, and M. F. Jarrold, Int. J. Mass Spectrom. Ion. Processes 138, 17 (1994).
14. J. M. Hunter, J. L. Fye, N. M. Boivin, and M. F. Jarrold, J. Phys. Chem. 98, 7440 (1994).
15. D. E. Clemmer, J. M. Hunter, K. B. Shelimov, and M. F. Jarrold, Nature (London) 372, 248 (1994).
16. D. E. Clemmer and M. F. Jarrold, J. Ann. Chem. Soc. 117, 8841 (1995).
17. K. B. Shelinov, D. E. Clemmer, and M. F. Jarroid, J. Phys. Chem. 99, 11376 (1995).
18. K. B. Shelimov and M. F. Jarrold, J. Phys. Chem. 99, 17677 (1995).
19. K. B. Shelimov, D. E. Clemmer, and M. F. Jarrold, J. Chem. Soc. Dalton Trans. 5, 567 (1996).
20. G. von Helden, N. G. Gotts, P. Maitre, and M. T. Bowers, Chem. Phys. Lett. 227, 601 (1994).
21. J. L. Fye and M. F. Jarrold, J. Phys. Chem. A 101, 1836 (1997).
22. G. von Helden, E. Porter, N. G. Gotts, and M. T. Bowers, J. Phys. Chem. 99, 7707 (1995).
23. S. Lee, N. G. Gotts, G. von Helden, and M. T. Bowers, Science 267, 999 (1995).
24. S. Lee, N. G. Gotts, G. von Helden, and M. T. Bowers, J. Phys. Chem. A 101, 2096 (1997).
25. G. Von Helden, T. Wyttenbach, and M. T. Bowers, Science 267, 1483 (1995).
26. Ph. Dugourd, R. R. Hudgins, D. E. Clemmer, and M. F. Jarrold, Rev. Sci. Instrum. 68, 1122 (1997).
27. D. L. Strout, L. D. Book, J. M. Millam, C. Xu, and G. E. Scuseria, J. Phys. Chem. 98, 8622 (1994).
28. D. L. Strout and G. E. Scaseria, J. Phys. Chem. 100, 6492 (1994).
29. L. D. Book, C. Xu, and G. E. Scuseria, Chem. Phys. Lett. 222, 281 (1994).
30. M. Krishanamarthy, J. A. de Gouw, V. M. Bierbaum, and S. R. Leone, J. Phys. Chem. 100, 14908 (1986): M. Krishnamarthy, J. A. de Gouw, L. N. Ding. V. M. Bierbaum, and S. R. Leone, J. Chem. Phys. 106, 530 (1997).
31. M. Krishanamarthy, J. A. de Gouw, V. M. Bierbaum, and S. R. Leone, J. Phys. Chem. 100, 14908 (1986): M. Krishnamarthy, J. A. de Gouw, L. N. Ding. V. M. Bierbaum, and S. R. Leone, J. Chem. Phys. 106, 530 (1997).
32. S. J. Valentine, J. G. Anderson, A. D. Ellington, and D. E. Clemmer, J. Phys. Chem. B 101, 3891 (1997); C. S. Houglund, Y. Liu, A. D. Ellington, M. Pagel, and D. E. Clemmer, J. Am. Chem. Soc. 119, 9051 (1997).
33. S. J. Valentine, J. G. Anderson, A. D. Ellington, and D. E. Clemmer, J. Phys. Chem. B 101, 3891 (1997); C. S. Houglund, Y. Liu, A. D. Ellington, M. Pagel, and D. E. Clemmer, J. Am. Chem. Soc. 119, 9051 (1997).
34. E. Mack, Jr., J. Am. Chem. Soc. 47, 2468 (1925).
35. M. F. Mesleh, J. M. Hunter, A. A. Shvartsburg, G. C. Schutz, and M. F. Jarrold, J. Phys. Chem. 100, 16082 (1996); J. Phys. Chem. A 101, 968 (1997).
36. M. F. Mesleh, J. M. Hunter, A. A. Shvartsburg, G. C. Schutz, and M. F. Jarrold, J. Phys. Chem. 100, 16082 (1996); J. Phys. Chem. A 101, 968 (1997).
37. A. A. Shvartsburg, R. R. Hudgins, Ph. Dugourd, and M. F. Jarrold, J Phys. Chem. A 101, 1684 (1997).
38. 60 (neutral)-He scattering cross sections by A. Ruiz, J. Breton, and J. M. Gomez Llorente, Chem. Phys. Lett. 270, 121 (1997).
39. J. Breton, J. Gonzalez-Platas, and C. Girardet, J. Chem. Phys. 99, 4036 (1993).
40. M. F. Jarrold, J. Phys. Chem. 99, 11 (1995).
41. E. A. Mason and E. W. McDaniel, Transport Properties of Ions in Gases (Wiley, New York, 1988).
42. (1,1) term are below 0.01% for all clusters. The higher-order terms are negligible here because we operate in the Rayleigh limit, (Ref. 38) where the ions are much more heavier than the buffer gas atmos.
43. For fullerenes (Refs. 33 and 34) this correction to the temperatuer scale is negligible (<1 K). The correction, however, rapidly increases with increasing drift velocity (which is inversely proportional to the collision intergral) and may exceed 10 K for the smallest clusters studied here.
44. L. A. Vichland and A. S. Dickinson, Chem. Phys. 193, 255 (1995).
45. L. A. Vichland, A. S. Dickinson, and R. G. Maclagan, Chem. Phys. 211, 1 (1996); W. K. Liu and A. S. Dickinson, Mol. Phys. 88, 161 (1996).
46. L. A. Vichland, A. S. Dickinson, and R. G. Maclagan, Chem. Phys. 211, 1 (1996); W. K. Liu and A. S. Dickinson, Mol. Phys. 88, 161 (1996).
47. S. N. Lin, G. W. Griffin, E. C. Horning, and E. E. Wentworth, J. Chem. Phys. 60, 4994 (1974).
48. A. A. Shvartsburg and M. F. Jarrold, Chem. Phys. Lett. 86, 261 (1996). Equations (2), (4), and (5) are correct as written here. The same formulas presented in the above reference are in error by a factor of two [Eqs. (2) and (4)] and 2/π [Eq. (5)].
49. We have acquired the data for n=7-10, 16, 18, 22, 24, 28, 30, 34, 36, 40, and 46.
50. J. M. L. Martin and P. R. Taylor, J. Phys. Chem. 100, 6047 (1996).
51. J. M. L. Martin, J. El-Yazal, and J. P. Francoes, Chem. Phys. Lett. 252, 9 (1996).
52. J. Hutter and H. P. Luthi, J. Chem. Phys. 101, 2213 (1994).
53. J. Hutter, H. P. Luthi, and F. Diederich, J. Am. Chem. Soc. 116, 750 (1994).
54. T. F. Giesen, A. Van Orden, H. J. Hwang, R. S. Fellers, R. A. Provencal, and R. J. Saykally, Science 265, 756 (1994).
55. H. J. Hwang, A. Van Orden, K. Tanaka, E. W. Kuo, J. R. Heath, and R. J. Saykally. Mol. Phys. 79, 769 (1993).
56. D. A. Plattner and K. N. Houk, J. Am. Chem. Soc. 117, 4405 (1995).
57. K. Raghavachari, D. L. Strout, G. K. Odom, G. E. Scuseria, J. A. Pople, B. G. Johnson, and P. M. W. Gill, Chem. Phys. Lett. 214, 357 (1993).
58. K. Raghavachari, B. Zhang, J. A. Pople, B. G. Johnson, and P. M. W. Gill, Chem. Phys. Lett. 220, 385 (1994).
59. J. M. Martin, J. P. Francois, R. Gijbels, and J. Almlof. Chem. Phys. Lett. 187, 367 (1991).
60. J. M. L. Martin, J. El-Yazal, and J. P. Francois, Chem. Phys. Lett. 248, 345 (1996).
61. J. M. L. Martin, J. El-Yazal, and J. P. Francois, Chem. Phys. Lett. 255, 7 (1996).
62. J. D. Watts and R. J. Bartlett, Chem. Phys. Lett. 190, 19 (1992).
63. Martin et al. (Ref. 47) found that the lowest energy isomers for small neutral carbon rings are not circular, but feature strongly alternating bond angles. The calculated mobilities of these prometries (n=7-18) are slightly (within 1.5%) below those of our model structures.
64. K. B. Shelimov (private communications).
65. 50 fullerence with the experimental structure, has been applied to all MNDO geometries for carbon clusters in our preceding work (Refs. 33 and 34).
66. D. L. Strout, R. L. Murry, C. Xu, W. C. Eckhoff, G. K. Odom, and G. E. Scuseria, Chem. Phys. Lett. 214, 576 (1993).
67. Measurement is from J. M. Hunter and M. F. Jarrodl (unpublished results).
68. G. B. Adams, O. F. Sankey, J. B. Page, M. O'Keeffe, and D. A. Drabold, Science 256, 1792 (1992).
69. D. Bakowies and W. Thiel, J. Am. Chem. Soc. 113, 3704 (1991).
70. G. E. Scuseria, in Buckminsterfullerenes, edited by W. E. Billups and M. A. Clufolini (VCH Weinheim, 1993), p 103.
71. J. M. Hunter and M. F. Jarrold, J. Am. Chem. Soc. 117, 10317 (1995).
72. J. R. Heath and R. J. Saykally, J. Chem. Phys. 94, 1724 (1991).
73. A. Van Orden, H. J. Hwang, E. W. Kuo, and R. J. Saykally, J. Chem. Phys. 98, 6678 (1993).
74. Ph. Dugourd, R. R. Hudgins, J. M. Tenenbaum, and M. F. Jarrold (to be published).
75. h structure is under 0.3%, which is within the experimental error margin.
76. h structure is under 0.3%, which is within the experimental error margin.