Design of Long-Lived Ru(II) Terpyridine MLCT States. Tricyano Terpyridine Complexes

Inorganic Chemistry

Volumn 37, Issue 23, 1998, Pages 6084-6089

  Indelli, Maria Teresa ^a   Bignozzi, Carlo Alberto ^a   Scandola, Franco ^a   Collin, Jean Paul ^a,b  

^a UNIVERSITY OF FERRARA   (Italy)

^b UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000002275     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980060u     Document Type: Article

References (40)

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33. 23 consistent with the assignment of the transition as a bpy-centered one.
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36. The equilibrium assumption is just arbitrary. That of constant MC energy would be, strictly speaking, incorrect as the strong second-sphere interactions with the solvent will certainly affect to some extent the ligand field strength of cyanide. It is used here simply to mean that the solvent dependence is probably much less pronounced for MC than for MLCT energies.
37. In principle, the assignment of the right-hand branch of Figure 4a to a termally activated decay regime could be checked by temperature-dependent lifetime measurements. In practice, however, the emissions in this solvent range are too weak and short-lived to yield reliable activation energy values.
38. 2O). Thus, the order indicated is appropriate regardless of the solvent.
39. 38
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