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Volumn 35, Issue 2, 1996, Pages 303-312

Photoinduced Electron and Energy Transfer in Rigidly Bridged Ru(II)-Rh(III) Binuclear Complexes

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Indexed keywords


EID: 0000612267     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950745j     Document Type: Article
Times cited : (109)

References (82)
  • 6
    • 0001748542 scopus 로고
    • Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam
    • Wasielewski, M. R. In Photoinduced Electron Transfer, Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Part A, p 161.
    • (1988) Photoinduced Electron Transfer , pp. 161
    • Wasielewski, M.R.1
  • 57
    • 2742613324 scopus 로고
    • Rorabacher, D. B., Endicott, J. F., Eds.; ACS Symposium Series 198; American Chemical Society: Washington, DC, and references therein
    • Creutz, C.; Keller, A. D.; Schwartz, H. A.; Sutin, N.; Zipp, A. P. In Mechanistic Aspects of Inorganic Reactions; Rorabacher, D. B., Endicott, J. F., Eds.; ACS Symposium Series 198; American Chemical Society: Washington, DC, 1982; p 385 and references therein.
    • (1982) Mechanistic Aspects of Inorganic Reactions , pp. 385
    • Creutz, C.1    Keller, A.D.2    Schwartz, H.A.3    Sutin, N.4    Zipp, A.P.5
  • 60
    • 2742530777 scopus 로고    scopus 로고
    • note
    • In fluid solution at 150 K, wavelength effects on the emission and excitation spectra disappear for Ru-Ru. For Ru-Rh, on the other hand, accurate emission/excitation experiments are precluded by the quenching process.
  • 61
    • 85088542243 scopus 로고    scopus 로고
    • note
    • 53
  • 64
    • 2742559322 scopus 로고    scopus 로고
    • note
    • In picosecond laser flash photolysis, formation of the LC triplet state of Rh(III) polypyridine complexes is complete in τ < 30 ps (M. T. Indelli and N. Serpone, unpublished results).
  • 65
    • 85088542448 scopus 로고    scopus 로고
    • note
    • -1.
  • 70
    • 2742518741 scopus 로고    scopus 로고
    • note
    • o values should be regarded as indicative figures.
  • 71
    • 85088543418 scopus 로고    scopus 로고
    • note
    • 72 in the two-sphere model, each molecular component can be modeled by a "representative sphere", with an effective radius obtainable from CPK models. For both molecular components of our Ru(II)-Rh(III) dyads (identified as (ttpy)M(tpy) fragments), this procedure gives a value of 5.1 Å for the radii of the representative spheres.
  • 73
    • 2742571397 scopus 로고    scopus 로고
    • This assumption is in line with the observed irreversibility of the Rh(III) reduction
    • This assumption is in line with the observed irreversibility of the Rh(III) reduction.
  • 75
    • 85088542638 scopus 로고    scopus 로고
    • note
    • 77
  • 80
    • 2742576857 scopus 로고    scopus 로고
    • note
    • 39
  • 82
    • 2742545120 scopus 로고
    • Helms, A.; Heiler, D.; McLendon, G. J. Am. Chem. Soc. 1991, 113, 4325; 1992, 114, 6227.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 6227


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.