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In fluid solution at 150 K, wavelength effects on the emission and excitation spectra disappear for Ru-Ru. For Ru-Rh, on the other hand, accurate emission/excitation experiments are precluded by the quenching process.
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61
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85088542243
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note
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53
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62
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0001362750
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Frink, M E., Sprouse, S. D.; Goodwin, H. A., Watts, R. J.; Ford, P. C. Inorg. Chem. 1988, 27, 1283.
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Frink, M.E.1
Sprouse, S.D.2
Goodwin, H.A.3
Watts, R.J.4
Ford, P.C.5
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63
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0002489695
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Kirk, A. D.; Hoggard, P. E.; Porter, G. B.; Rockley, M. G.; Windsor, M. W. Chem. Phys. Lett. 1976, 37, 199.
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Kirk, A.D.1
Hoggard, P.E.2
Porter, G.B.3
Rockley, M.G.4
Windsor, M.W.5
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64
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2742559322
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note
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In picosecond laser flash photolysis, formation of the LC triplet state of Rh(III) polypyridine complexes is complete in τ < 30 ps (M. T. Indelli and N. Serpone, unpublished results).
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65
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85088542448
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note
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-1.
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69
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0021133071
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Miller, J. R.; Beitz, J. V.; Huddlestone, R. K. J. Am. Chem. Soc. 1984, 106, 5057.
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Miller, J.R.1
Beitz, J.V.2
Huddlestone, R.K.3
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70
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2742518741
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note
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o values should be regarded as indicative figures.
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-
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71
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85088543418
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note
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72 in the two-sphere model, each molecular component can be modeled by a "representative sphere", with an effective radius obtainable from CPK models. For both molecular components of our Ru(II)-Rh(III) dyads (identified as (ttpy)M(tpy) fragments), this procedure gives a value of 5.1 Å for the radii of the representative spheres.
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72
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33845373449
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Brunschwig, B. S.; Ehrenson, S.; Sutin, N. J. Phys. Chem. 1986, 90, 3657.
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Brunschwig, B.S.1
Ehrenson, S.2
Sutin, N.3
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73
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2742571397
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This assumption is in line with the observed irreversibility of the Rh(III) reduction
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This assumption is in line with the observed irreversibility of the Rh(III) reduction.
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75
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85088542638
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note
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77
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76
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0000013088
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Glauser, R.; Hauser, U.; Herren, F.; Ludi, A.; Roder, P ; Schmidt, E.; Siegenthaler, H.; Wenk, F. J. Am Chem. Soc. 1973, 95, 8457.
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Glauser, R.1
Hauser, U.2
Herren, F.3
Ludi, A.4
Roder, P.5
Schmidt, E.6
Siegenthaler, H.7
Wenk, F.8
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78
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0001106707
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Balzani, V.; Bolletta, F.; Scandola, F. J. Am. Chem. Soc. 1980, 102, 2152.
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Balzani, V.1
Bolletta, F.2
Scandola, F.3
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79
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0000310215
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Murtaza, Z.; Zipp, A. P.; Worl, L. A.; Graff, D.; Jones, W. E.; Bates, W. D.; Meyer, T. J. J. Am. Chem. Soc. 1991, 113, 5113
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Murtaza, Z.1
Zipp, A.P.2
Worl, L.A.3
Graff, D.4
Jones, W.E.5
Bates, W.D.6
Meyer, T.J.7
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80
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2742576857
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note
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39
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81
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1542617895
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Helms, A.; Heiler, D.; McLendon, G. J. Am. Chem. Soc. 1991, 113, 4325; 1992, 114, 6227.
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Helms, A.1
Heiler, D.2
McLendon, G.3
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2742545120
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Helms, A.; Heiler, D.; McLendon, G. J. Am. Chem. Soc. 1991, 113, 4325; 1992, 114, 6227.
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