Phosphine oxides as efficient neutral coordinate-organocatalysts for stereoselective allylation of N-acylhydrazones

Organic and Biomolecular Chemistry

Volumn 2, Issue 4, 2004, Pages 446-448

  Ogawa, Chikako ^a   Konishi, Hideyuki ^a   Sugiura, Masaharu ^a   Kobayashi, Shu ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; CARBON; HYDROGEN PEROXIDE; KETONES; OXIDATION; PHOSPHORUS COMPOUNDS; SILANES; SOLUBILITY; STEREOCHEMISTRY;

ORGANOCATALYSTS; STEREOSELECTIVE ALLYLATION;

CATALYSTS;

EID: 1342344956     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b315037b     Document Type: Article

References (25)

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25. PS-phosphine oxide 2 is not soluble but swollen in dichloromethane. After the reaction, 2 was recovered quantitatively by simple filtration and washing (water, methanol, diethyl ether, tetrahydrofuran, and dichloromethane). It might be possible that one or two phosphine oxide components in 2 activate allyltrichlorosilane in the transition state, though the latter might be less prominent in the polymer matrix.