Reductive dehalogenation of aqueous-phase chlorinated hydrocarbons in an electrochemical reactor

Industrial and Engineering Chemistry Research

Volumn 43, Issue 25, 2004, Pages 7965-7974

  He, Jiahan ^a   Ela, Wendell P ^a   Betterton, Eric A ^b   Arnold, Robert G ^a   Sáez, A Eduardo ^a  

^a University of Arizona   (United States)

^b UNIVERSITY OF ARIZONA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATHODES; CHEMICAL REACTORS; COMPUTER SIMULATION; DECHLORINATION; ELECTROCHEMISTRY; MASS TRANSFER; MATHEMATICAL MODELS; POROUS MATERIALS; REDUCTION;

EQUILIBRIUM POTENTIAL; LIQUID-PHASE ELECTROCHEMICAL REACTORS; REDUCTIVE DEHALOGENATION; RESIDENCE TIME;

CARBON TETRACHLORIDE;

CARBON; CARBON TETRACHLORIDE; COPPER; HYDROCARBON; HYDROGEN; WATER;

CHLORINATED HYDROCARBON; DECHLORINATION; ELECTROCHEMICAL PROCESS;

AQUEOUS SOLUTION; ARTICLE; CHLORINATION; CONDUCTANCE; DEHALOGENATION; ELECTROCHEMICAL ANALYSIS; ELECTRODE; EQUIPMENT DESIGN; LIQUID; MATHEMATICAL MODEL; PERFORMANCE; REACTOR; REDUCTION;

EID: 9744265623     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie049568x     Document Type: Article

References (17)

1. Vogel, T. M.; Griddle, C. S.; McCarty, P. L. Transformation of Halogenated Aliphatic Compounds. Environ. Sci. Technol. 1987, 21, 722.
2. Bouwer, E. J.; Wright, J. P. Transformations of Trace Halogenated Aliphatics in Anoxic Biofilm Columns. J. Contam. Hydrol. 1988, 2, 155.
3. Gusmao, A. D.; de Campos, T. M. P.; Nobre, M. D. M.; Vargas, B. D. Laboratory Tests for Reactive Barrier Design. J. Hazard. Mater. 2004, 110, 105.
4. 4-Effects of Cathode Material and Potential on Kinetics, Selectivity, and Product Stoichiometry. Environ. Eng. Sci. 1999, 16, 1.
5. Scherer, M. M.; Westall, J. C.; Ziomek-Moroz, M.; Tratnyek, P. G. Kinetics of Carbon Tetrachloride Reduction at an Oxide-Free Iron Electrode. Environ. Sci. Technol. 1997, 31, 2385.
6. Criddle, C. S.; McCarty, P. L. Electrolytic Model System for Reductive Dehalogenation in Aqueous Environment. Environ. Sci. Technol. 1991, 25, 973.
7. Cheng, I. F.; Fernando, Q.; Korte, N. Electrochemical Dechlorination of 4-Chlorophenol to Phenol. Environ. Sci. Technol. 1997, 31, 1074.
8. Li, T.; Farrell, J. Reductive Dechlorination of Trichloroethene and Carbon Tetrachloride Using Iron and Palladized-Iron Cathodes. Environ. Sci. Technol. 2000, 34, 173.
9. Lambert, F. L.; Hasslinger, B. L.; Franz, R. N. The Total Reduction of Carbon Tetrachloride at the Glassy Carbon Electrode. J. Electrochem. Soc. 1975, 122, 737.
10. Chen, G.; Betterton, E. A.; Arnold, R. G. Electrolytic Oxidation of Trichloroethylene Using a Ceramic Anode. J. Appl. Electrochem. 1989, 29, 961.
11. Nagaoka, T.; Yamashita, J.; Takase, M.; Ogura, K. Composite Electrodes Consisting of Metal and Oxidized Carbon Particles for Complete Degradation of Trichlorethylene in Acetonitrile. J. Electrochem. Soc. 1994, 141, 1522.
12. He, J.; Saez, E. A.; Ela, W. P.; Betterton, E. A.; Arnold, R. G. Destruction of Aqueous Phase Carbon Tetrachloride in an Electrochemical Reactor with a Porous Cathode. Ind. Eng. Chem. Res. 2004, 43, 913.
13. Calmidi, V. V.; Mahajan, R. L. Forced Convection in High Porosity Metal Foams. J. Heat Transfer 2000, 122, 557.
14. Lu, T. J.; Stone, H. A.; Ashby, M. F. Heat Transfer in Open-Cell Metal Foams. Acta Mater. 1998, 46, 3619.
15. Liu, Z. J.; Betteron, E. A.; Arnold; R. G. Electrolytic Reduction of Low Molecular Weight Chlorinated Aliphatic Compounds: Structural and Thermodynamic Effects on Process Kinetics. Environ. Sci. Technol. 2000, 34, 804.
16. Pickett, D. J. Electrochemical Reactor Design; Elsevier Scientific: Amsterdam, The Netherlands, 1979.
17. Doherty, T.; Sunderland, J. G.; Roberts, E. P. L.; Pickett, D. J. An Improved Model of Potential and Current Distribution within a Flow-Through Porous Electrode. Electrochim. Acta 1996, 41, 519.