Destruction of Aqueous-Phase Carbon Tetrachloride in an Electrochemical Reactor with a Porous Cathode

Industrial and Engineering Chemistry Research

Volumn 43, Issue 4, 2004, Pages 913-923

  He, Jiahan ^a   Sáez, A Eduardo ^a   Ela, Wendell P ^a   Betterton, Eric A ^b   Arnold, Robert G ^a  

^a University of Arizona   (United States)

^b UNIVERSITY OF ARIZONA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATHODES; CHEMICAL REACTORS; COPPER; ELECTRIC CONDUCTIVITY; HYDROGEN; POROUS MATERIALS;

CONDUCTIVE SOLUTIONS; ELECTROCHEMICAL REACTORS;

ELECTROCHEMISTRY;

CARBON TETRACHLORIDE;

REACTOR;

ARTICLE; CONTINUOUS FLOW REACTOR; ELECTRIC CONDUCTIVITY; ELECTROCHEMISTRY; EQUILIBRIUM CONSTANT; MATHEMATICAL MODEL; MOLECULAR EVOLUTION; PARAMETER; PHASE TRANSITION; POROSITY; SIMULATION;

EID: 1042289812     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030591c     Document Type: Article

References (24)

1. Vogel, T. M.; Criddle, C. S.; McCarty, P. L. Transformation of halogenated aliphatic compounds. Environ. Sci. Technol. 1987 21, 722.
2. Bouwer, E. J.; Wright, J. P. Transformations of trace halogenated aliphatics; in anoxic biofilm columns. J. Contam. Hydrol. 1988, 2, 155.
3. Assaf-anid, N.; Hayes, K. F.; Vogel, T. M. Reductive dechlorination of carbon tetrachloride by cobalamin(II) in the presence of dithiothreitol. Environ. Sci. Technol. 1994, 28, 246.
4. Chiu, P. C.; Reinhard, M. Metallocoenzyme-mediated reductive transformation of carbon tetrachloride in titanium(III) citrate aqueous solution. Environ. Sci. Technol. 1995, 29, 595.
5. Chiu, P. C.; Reinhard, M. Transformation of carbon tetrachloride by reduced vitamin B12 in aqueous cysteine solution. Environ. Sci. Technol. 1996, 30, 1882.
6. Gillham, R. W.; O'Hannesin, S. F. Enhanced degradation of halogenated aliphatics by zerovalent iron. Ground Water 1994, 32, 958.
7. Johnson, T. L.; Scherer, M. M.; Tratnyek, P. G. Kinetics of halogenated organic compound degradation by iron metal. Environ. Sci. Technol. 1996, 30, 2634.
8. Matheson, L. J.; Trantnyek, P. G. Reductive dehalogenation of chlorinated methanes by iron metal. Environ. Sci. Technol. 1994, 28, 2045.
9. Orth, S. W.; Gillham, R. W. Dechlorination of trichloroethene in aqueous solution using Fe(O). Environ. Sci. Technol. 1996, 30, 66.
10. 4 - effects of cathode material and potential on kinetics, selectivity, and product stoichiometry. Environ. Eng. Sci. 1999, 16, 1.
11. Scherer, M. M.; Westall, J. C.; Ziomek-Moroz, M.; Tratnyek, P. G. Kinetics of carbon tetrachloride reduction at an oxide-free iron electrode. Environ. Sci. Technol. 1997, 31, 2385.
12. Criddle, C. S.; McCarty, P. L. Electrolytic model system for reductive dehalogenation in aqueous environment. Environ. Sci. Technol. 1991, 25, 973.
13. Cheng, I. F.; Fernando, Q.; Korte, N. Electrochemical dechlorination of 4-chlorophenol to phenol. Environ. Sci. Technol. 1997, 31, 1074.
14. Li, T.; Farrell, J. Reductive dechlorination of trichloroethene and carbon tetrachloride using iron and palladized-iron cathodes. Environ. Sci. Technol. 2000, 34, 173.
15. Lambert, F. L.; Hasslinger, B. L.; Franz, R. N. The total reduction of carbon tetrachloride at the glassy carbon electrode. J. Electrochem. Soc. 1975, 122, 737.
16. Chen, G.; Betterton, E. A.; Arnold, R. G. Electrolytic oxidation of trichloroethylene using a ceramic anode. J. Appl. Electrochem. 1999, 29, 961.
17. Nagaoka, T.; Yamashita, J.; Takase, M.; Ogura, K. Composite electrodes consisting of metal and oxidized carbon particles for complete degradation of trichlorethylene in acetonitrile. J. Electrochem. Soc. 1994, 141, 1522.
18. Calmidi, V. V.; Mahajan, R. L. Forced convection in high porosity metal foams. J. Heat Transfer 2000, 122, 557.
19. Lu, T. J.; Stone, H. A.; Ashby, M. F. Heat transfer in open-cell metal foams. Acta Mater. 1998, 46, 3619.
20. Liu, Z. J.; Betteron, E. A.; Arnold, R. G. Electrolytic reduction of low molecular weight chlorinated aliphatic compounds: structural and thermodynamic effects on process kinetics. Environ. Sci. Technol. 2000, 34, 804.
21. Pickett, D. J. Electrochemical Reactor Design; Elsevier Scientific Publishing Company: Amsterdam, The Netherlands, 1979.
22. Doherty, T.; Sunderland, J. G.; Roberts, E. P. L.; Pickett, D. J. An improved model of potential and current distribution within a flow-through porous electrode. Electrochim. Acta 1996, 41, 519.
23. Freeze, R. A.; Cherry, J. A. Groundwater; Prentice Hall Inc.: Englewood Cliffs, NJ, 1979.
24. LaGrega, M. D.; Buckingham, P. L.; Evans, J. C. Hazardous Waste Management; McGraw-Hill: New York, 1994.