Synthesis of persulfate containing poly (N-vinyl-2-pyrrolidone) (PVP) hydrogels in aqueous solutions by γ-induced radiation

Radiation Physics and Chemistry

Volumn 72, Issue 6, 2005, Pages 703-710

  Kaplan Can, Hatice ^a  

^a HACETTEPE UNIVERSITY   (Turkey)

Author keywords

Irradiation; Crosslinking; Degradation; DSC; FTIR; Gelation dose; Hydrogels; Poly(N vinyl 2 pyrrolidone); TGA

Indexed keywords

CROSSLINKING; DIFFERENTIAL SCANNING CALORIMETRY; FOURIER TRANSFORMS; GAMMA RAYS; NEGATIVE IONS; ORGANIC POLYMERS; SOLUTIONS; SYNTHESIS (CHEMICAL); THERMOANALYSIS; THERMOGRAVIMETRIC ANALYSIS;

CHAIN SCISSION; PERSULFATE ANIONS;

HYDROGELS;

ANION; COBALT 60; POLYMER; POVIDONE; SULFATE;

AQUEOUS SOLUTION; ARTICLE; CONCENTRATION RESPONSE; CROSS LINKING; DEGRADATION; DIFFERENTIAL SCANNING CALORIMETRY; FOURIER TRANSFORMATION; GAMMA RADIATION; GELATION; HYDROGEL; MATHEMATICAL ANALYSIS; RADIATION DOSE; RADIATION RESPONSE; STRUCTURE ANALYSIS; SYNTHESIS; THERMAL ANALYSIS; THERMOGRAVIMETRY;

EID: 9644299898     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2004.04.028     Document Type: Article

References (28)

1. Abad L.V., Relleve L.S., Aranilla C.T., Dela Rosa A.M. Properties of radiation synthesized PVP-kappa carrageenan hydrogel blends. Radiat. Phys. Chem. 68:2003;901-908
2. Anderson C.C., Rodriguez F., Thurston D.A. Crosslinking aqueous poly(vinylpyrrolidone) solutions by persulfate. J. Appl. Polym. Sci. 23:1979;2453-2462
3. Bharali J.D., Shaoo S.K., Mozumdar S., Maitra A. Cross-linked polyvinylpyrrolidone nanoparticles. a potential carrier for hydrophilic drugs J. Colloid Inter. Sci. 258:2003;415-423
4. Chapiro A., Legris C. Gel formation in the radiolysis of poly(N-vinylpyrrolidone). Radiat. Phys. Chem. 28(2):1986;143-144
5. Charlesby A., Alexander P. Energy transfer in macromolecules exposed to ionizing radiations. J. Polym. Sci. 23:1955;355-375
6. Chirila T.V., Rakoczy P.E., Garrett K.L., Lou X., Costanble I.J. The use of synthetic polymers for delivery of therapeutic antisense oligodeoxynucleotides. Biomaterials. 23:2002;321-342
7. Darwis D., Hilmy N., Hardiningsih L., Erlina T. Poly(N-vinylpyrrolidone) hydrogels. 1. Radiation polymerization and crosslinking of N-vinylpyrrolidone Radiat. Phys. Chem. 42(4-6):1993;907-910
8. Güner A., Ataman M. Effects of inorganic salts on the properties of aqueous PVP solutions. Colloid. Polym. Sci. 272:1994;175-180
9. Hilmy N., Darwis D., Hardiningsih L. Poly(N-vinylpyrrolidone) hydrogels. 2. Hydrogel composites as wound dressing for tropical environment Radiat. Phys. Chem. 42:1993;911-914
10. Hoffman A.S. Hydrogels for biomedical applications. Adv. Drug Delivery Rev. 54:2002;3-12
11. Kang J.S., Kim K.Y., Lee Y.M. Preparation of PVP immobilized microporous chlorinated polyvinyl chloride membranes on fabric and their hydraulic permeation behavior. J. Membr. Sci. 214:2003;311-321
12. 8 hydrogels in water. J. Appl. Polym. Sci. 78:2000;994-1000
13. 8 hydrogels in urea solutions. Adv. Polym. Chem. 19:2000;210
14. 8 hydrogels. Radiat. Phys. Chem. 68:2003;811-818
15. 8 hydrogels. In α-lactose solutions. Adv. Polym. Tech. 22:2003;252-259
16. Kiran E., Rodriguez F. Effects of gamma radiation on aqueous polymer solutions - a comparative study. J. Macromol. Sci. Phys. B7(2):1973;209-224
17. Lopergolo L.C., Lugao A.B., Catalani L.H. Direct uv photocrosslinking of poly(N-vinyl-2-pyrrolidone) (PVP) to produce hydrogels. Polymer. 44:2003;6217-6222
18. Lugao A.B., Rogero S.O., Malmonge S.M. Rheological behaviour of irradiated wound dressing poly(vinyl pyrrolidone) hydrogels. Radiat. Phys. Chem. 63:2002;543-546
19. Mazi H., Kibarer G., Güner A. Degradation kinetics of poly(N-vinyl-2-pyrrolidone) by persulfate anion in aqueous solution. Iran Polym. J. 10:2001;277-282
20. Rosiak J.M. Gel/sol analysis of irradiated polymers. Radiat. Phys. Chem. 51:1998;13-17
21. Rosiak J.M., Olejniczak J., Pekala W. Fast reactions of irradiated polymers. I. crosslinking and degradation of polyvinylpyrrolidone Radiat. Phys. Chem. 32:1988;691-747
22. Rosiak J.M., Ulanski P. Synthesis of hydrogels by irradiation of polymers in aqueous solution. Radiat. Phys. Chem. 55:1999;139-151
23. Rosiak J.M., Olejniczak J., Charlesby A. Gel/dose curves for polymers undergoing simultaneous crosslinking and scission. Radiat. Phys. Chem. 38:1991;113-118
24. Rosiak J.M., Ulanski P., Pajewski L.A., Yoshii F., Makuuchi K. Radiation formation of hydrogels for biomedical purposes. Some remarks and comments. Radiat. Phys. Chem. 46:1995;161-168
25. Rzaev Z.M.O., Guner A., Kaplan Can H., Asici A. Reactions of some anhydride-containing copolymers with γ-aminopropyltriethoxysilane. Polymer. 42:2001;5599-5606
26. Senaglos E., Thomas R. Persulfate-initiated reactions of N-vinylpyrrolidone. J. Polym. Sci., Symp. Ser. 55:1979;241-247
27. Tenhu H., Sundholm F., Bjorkten Studies of crosslinked poly(N-vinylpyrrolidone) by calorimetry and by NMR. J. Macromol. Chem. 18:1984;2011
28. Vasir J.K., Tambwekar K., Garg S. Bioadhesive microspheres as a controlled drug delivery system. Int. J. Pharm. 255:2003;13-32