Radical cation of dibenzothiophene fully annelated with bicyclo[2.2.2]octene units: X-ray crystal structure and electronic properties

Organic Letters

Volumn 6, Issue 23, 2004, Pages 4179-4182

  Yamazaki, Daisuke ^a   Nishinaga, Tohru ^a   Komatsu, Koichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BICYCLO COMPOUND; DIBENZOTHIOPHENE DERIVATIVE;

ARTICLE; CHEMICAL INTERACTION; ELECTRONICS; OXIDATION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 9444251061     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0483605     Document Type: Article

References (21)

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3. For a review, see: Nishinaga, T.; Komatsu, K. Org. Biomol. Chem. Submitted.
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12. 2 = 0.0903 (I > 2σ(I)), and GOF = 1.000.
13. Schaffrin, R. M.; Trotter, J. J. Chem. Soc. A. 1970, 1561-1565.
14. 2 = 0.0882 (I > 2σ(I)), and GOF = 1.002.
15. + by subtracting 0.04 V: Gagné, R. R.; Allison, J. L.; Gall, R. S.; Koval, C. A. J. Am. Chem. Soc. 1977, 99, 7170-7178.
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17. 2 = 0.0504 (I > 2σ(I)), and GOF = 0.908.
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19. This tendency is also observed for C1-C2 bond.
20. 2 = 0.0530 (I > 2σ(I)), and GOF = 0.858.
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