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In the schemes, we designate only one particular stereoisomer of the Birch-reduction products for the sake of clarity. In practice, however, the Birch reaction occurs without a particular diastereoselectivity; see ref 1, p 1010.
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20
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9244223527
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According to the photoionization mass spectra acquired in Orsay, the unlabeled sample of 3 showed an increased content of methyl benzoate, which we assign to autoxidation during transportation from the Berlin laboratory where the compounds were prepared.
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9244230542
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In ref 21, the barrier is given with even larger accuracy, 0.35 ± 0.01 eV.
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26
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9244220059
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To a first approximation, secondary KIEs are neglected.
-
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39
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9244233779
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+ ions clearly reveal structure 2 but cannot address the question of a delayed hydrogen-ring walk.
-
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40
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-
9244225084
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note
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+].
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43
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9244240728
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+)).
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44
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