Reactivity of a thiolate-bridged dinuclear ruthenium complex with nitrogenous molecules: Spectroscopic identification of a labile dinitrogen complex

European Journal of Inorganic Chemistry

Volumn , Issue 21, 2004, Pages 4291-4299

  Sellmann, Dieter ^a   Prakash, Raju ^a   Heinemann, Frank W ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

N ligands; Nitrogen fixation; Nitrogenases; Ruthenium; S ligands

Indexed keywords

AMMONIA; IRRADIATION; LIGANDS; MOLECULES; RUTHENIUM; RUTHENIUM COMPOUNDS;

DINITROGEN COMPLEXES; DINUCLEAR RUTHENIUM COMPLEXES; DIRUTHENIUM COMPLEX; N LIGANDS; N-LIGANDS; NITROGENASE; PYRIDINE-2; S LIGANDS; SPECTROSCOPIC IDENTIFICATION; THIOLATES;

NITROGEN FIXATION;

2,6 BIS[(3,5 DI TERT BUTYL 2 SULFANYLPHENYL)THIOMETHYL]PYRIDINE; CARBONYL DERIVATIVE; METAL COMPLEX; NITROGEN DERIVATIVE; PYRIDINE DERIVATIVE; RUTHENIUM COMPLEX; SULFIDE; SULFUR DERIVATIVE; THIOLACID; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON; GEOMETRY; HYPERBARISM; METAL BINDING; OXIDATION; REACTION ANALYSIS; REDUCTION; ROOM TEMPERATURE; SPECTROSCOPY; STRUCTURE ANALYSIS; ULTRAVIOLET RADIATION;

EID: 9244259626     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400375     Document Type: Article

References (46)

1. [1a] J. B. Howard, D. C. Rees, Chem. Rev. 1996, 96, 2965-2982.
2. [1b] B. K. Burgess, D. J. Lowe, Chem. Rev. 1996, 96, 2983-3011.
3. [1c] R. R. Eady, Chem. Rev. 1996, 96, 3013-3030.
4. [1d] R. N. F. Thorneley, D. J. Lowe, J. Biol. Inorg. Chem. 1996, 1, 576-580.
5. [1e] D. C. Rees, J. B. Howard, Curr. Opin. Chem. Biol. 2000, 4, 559-566.
6. [1f] O. Einsle, F. A. Tezcan, S. L. A. Andrade, B. Schmid, M. Yoshida, J. B. Howard, D. C. Rees, Science 2002, 297, 1696-1700.
7. [2a] H. Deng, R. Hofmann, Angew. Chem. 1993, 105, 1125-1128; Angew. Chem. Int. Ed. Engl. 1993, 32, 1062-1065.
8. [2a] H. Deng, R. Hofmann, Angew. Chem. 1993, 105, 1125-1128; Angew. Chem. Int. Ed. Engl. 1993, 32, 1062-1065.
9. [2b] M. D. Fryzuk, S. A. Johnson, Coord. Chem. Rev. 2000, 200-202, 379-409.
10. [2c] D. Sellmann, A. Fürsattel, J. Sutter, Coord. Chem. Rev. 2000, 200-202, 545-561.
11. [3a] R. A. Henderson, C. J. Leigh, C. J. Pickett. Adv. Inorg. Chem. Radiochem. 1983, 27, 197-292.
12. [3b] M. Hidai, Y. Mizobe, Chem. Rev. 1995, 95, 1115-1133.
13. [3c] D. V. Yandulov, R. R. Schrock, Science 2003, 301, 76-78.
14. [3d] B. A. MacKay, M. D. Fryzuk, Chem. Rev. 2004, 104, 385-401.
15. [4a] Y. Yoshida, T. Adachi, M. Kamanica, T. Ueda, J. Am. Chem. Soc. 1988, 110, 4872-4873.
16. [4b] R. H. Morris, J. M. Rassner, J. F. Sawyer, M. Shiralian, J. Am. Chem. Soc. 1984, 106, 3683-3684.
17. [4c] J. Chatt, R. H. Crabtree, J. R. Dilworth, R. L. Richards, J. Chem. Soc., Dalton Trans. 1974, 2358-2362.
18. [4d] J. R. Dilworth, J. Hu, R. H. Thompson, D. L. Hughes, J. Chem. Soc., Chem. Commun. 1992, 551-553; and references cited therein.
19. [4e] M. B. O'Regan, A. H. Liu, W. C. Finck, R. R. Schrock, J. Am. Chem. Soc. 1990, 112, 4331-4338.
20. [5a] D. Sellmann, B. Hautsch, A. Rösler, F. W. Heinemann, Angew. Chem. 2001, 113, 1551-1555; Angew. Chem. Int. Ed. 2001, 40, 1505-1508.
21. [5a] D. Sellmann, B. Hautsch, A. Rösler, F. W. Heinemann, Angew. Chem. 2001, 113, 1551-1555; Angew. Chem. Int. Ed. 2001, 40, 1505-1508.
22. [5b] D. Sellmann, A. Hille, F. W. Heinemann, M. Moll, A. Rösler, J. Sutter, G. Brehm, M. Reiher, B. A. Hess, S. Schneider, Inorg. Chim. Acta 2003, 348, 194-198.
23. [6a] D. Sellmann, J. Utz, N. Blum, F. W. Heinemann, Coord. Chem. Rev. 1999, 190-192, 607-627.
24. [6b] D. Sellmann, J. Sutter. Prog. Inorg. Chem. 2003, 52, 585-681.
25. D. Sellmann, R. Prakash, F. W. Heinemann, M. Moll, M. Klimowicz, Angew. Chem. 2004, 116, 1913-1916; Angew. Chem. Int. Ed. 2004, 43, 1877-1880.
26. D. Sellmann, R. Prakash, F. W. Heinemann, M. Moll, M. Klimowicz, Angew. Chem. 2004, 116, 1913-1916; Angew. Chem. Int. Ed. 2004, 43, 1877-1880.
27. [8a] D. Sellmann, J. Utz, F. W. Heinemann, Inorg. Chem. 1999, 38, 5314-5322.
28. [8b] D. Sellmann, D. Häußinger, T. Gottschalk-Gaudig, F. W. Heinemann, Z. Naturforsch., Teil B 2000, 55, 723-729.
29. [8c] D. Sellmann, T. Gottschalk-Gaudig, F. W. Heinemann, Inorg. Chem. 1998, 37, 3982-3988.
30. D. Sellmann, T. Gottschalk-Gaudig, D. Häußinger, F. W. Heinemann, B. A. Hess, Chem. Eur. J. 2001, 7, 2099-2103.
31. D. Sellmann, K. Engl, F. W. Heinemann, Eur. J. Inorg. Chem. 2000, 423-429.
32. Recent Advances in Hydride Chemistry (Eds.: M. Peruzzini, R. Poli), Elsevier, Amsterdam, 2001, and references cited therein.
33. [12a] S. D. Pell, J. N. Armor, J. Am. Chem. Soc. 1972, 94, 686-687.
34. [12b] S. D. Pell, J. N. Armor, J. Am. Chem. Soc. 1973, 95, 7625-7633.
35. J. D. Buhr, H. Taube, Inorg. Chem. 1980, 19, 2425-2434.
36. [14a] H. M. Koepp, H. Wendt, H. Strehlow, Z. Elektrochem. 1960, 64, 483-491.
37. [14b] G. Gritzner, J. Kuta, Pure Appl. Chem. 1984, 55, 461-466.
38. A. J. Bard, L. R. Faulkner, Electrochemical Methods, Fundamentals and Applications, Wiley, New York, 1980.
39. [16a] D. Sellmann, R. Prakash, F. W. Heinemann, Eur. J. Inorg. Chem. 2004, 1847-1858.
40. [16b] D. Sellmann, R. Prakash, F. Geipel, F. W. Heinemann, Eur. J. Inorg. Chem. 2002, 2138-2346.
41. [17a] R. H. Blessing, Acta Crystallogr., Sect. A 1995, 51, 33-38.
42. [17b] SADABS, Bruker AXS, Inc., Madison, WI, USA, 2002.
43. [18a] SHELXTL NT 5.1, Bruker AXS, Inc., Madison, WI, USA, 1998.
44. [18b] SHELXTL NT 6.12, Bruker AXS, Inc., Madison, WI. USA, 2002.
45. F. D. Flack, Acta Crystallogr., Sect. A 1983, 39, 876-881.
46. 2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: + 44-1223-336-033; E-mail: deposit@ccdc.cam.ac.uk].